Formula and preparation method of carbon nanotube high-efficiency anticorrosive paint

A technology of carbon nanotubes and anti-corrosion coatings, applied in the direction of anti-corrosion coatings, fire-proof coatings, coatings, etc., can solve the problems of unfavorable storage, easy agglomeration, poor heat resistance, etc., to improve the use performance, improve the use effect, improve The effect of heat resistance

Inactive Publication Date: 2022-03-22
深圳市中科纳米科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the continuous development of science and technology in the field of coatings, research has proved that the application of nano-materials in coatings can not only improve the overall performance of coatings, but also add some new functions to coatings, such as self-cleaning, antistatic, and absorbing stealth etc., thereby improving the performance of coating products, and carbon nanotubes, as a new type of nanomaterial with great development potential, have the electrical conductivity of metal or semiconductor, extremely high mechanical strength, hydrogen storage capacity, adsorption capacity and strong microwave Characteristics such as absorption capacity are gradually applied in the field of coatings and are becoming more and more extensive. However, in the actual use of existing carbon nanotube anti-corrosion coatings, due to the large aspect ratio and specific surface area of ​​carbon nanotubes, the coatings It is easy to agglomerate between them, which not only affects the use, but also is not conducive to storage, and its own heat resistance is poor, which needs to be improved
[0003] Chinese Patent No. CN106675317A discloses a carbon nanotube modified conductive anti-corrosion coating for grounding grids, which is mainly aimed at the problem that the existing conductive coating has poor corrosion resistance, and the anti-corrosion coating with better corrosion resistance has low electrical conductivity. , using nano-carbon powder filler, epoxy resin matrix, nano-magnetic iron oxide, inert diluent, polyurethane resin, alkyd resin, polyvinyl alcohol, ethyl acetate, dispersant, acetone, methyl isobutyl ketone and triphosphate The ratio between butyl ester and other materials can realize the conductivity of carbon nanotube anticorrosive coatings, but the influence of the agglomeration of carbon nanotube anticorrosive coatings on the use of coatings is still ignored, and needs to be improved
[0004] Chinese Patent No. CN112574606A discloses a carbon nanotube anti-corrosion coating. Compared with the prior art, the invention has the advantages of environmentally friendly materials and environmentally friendly production process. The resulting paint film has excellent water resistance and anti-corrosion performance, and has high bonding strength. Alkali resistance and corrosion resistance are excellent, which greatly improves the scope of application and cost performance of the coating. Although the bonding strength of the carbon nanotube anti-corrosion coating has been improved, the problem of agglomeration and storage of the coating cannot be solved. make improvements

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  • Formula and preparation method of carbon nanotube high-efficiency anticorrosive paint
  • Formula and preparation method of carbon nanotube high-efficiency anticorrosive paint

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Effect test

Embodiment 1

[0028] see Figure 1-2 , the present invention provides a technical solution: a carbon nanotube high-efficiency anti-corrosion coating formula, its raw materials are as follows by proportion: high chlorinated polyethylene resin 44%, organic bentonite 15%, carbon nanotube 4%, organic solvent 6%, 8% silicone sol, 3% defoamer, 5% dispersant, 2% curing agent, 1% film-forming aid, 2% diluent, 3% silver powder, 3% plasticizer and 4% deionized water.

[0029] The material of the organic solvent includes but not limited to styrene, perchlorethylene, trichloroethylene, ethylene glycol ether and triethanolamine, using styrene, perchlorethylene, trichloroethylene, ethylene glycol ether and triethanolamine as the preparation The organic solvent in the process can greatly improve the compatibility between the components of the coating. The material of the defoamer is polydimethylsiloxane and dimethyl silicone oil or a mixture of two of them. The defoamer Then the defoaming effect in the w...

Embodiment 2

[0039] A carbon nanotube high-efficiency anti-corrosion coating formula, its raw materials are as follows by proportion: high chlorinated polyethylene resin 42%, organic bentonite 15%, carbon nanotube 5%, organic solvent 7%, organosilicon sol 9%, defoamer 3%, dispersant 5%, curing agent 3%, coalescent 1%, diluent 1%, silver powder 2%, plasticizer 3% and deionized water 4%.

[0040] The material of the organic solvent includes but not limited to styrene, perchlorethylene, trichloroethylene, ethylene glycol ether and triethanolamine, using styrene, perchlorethylene, trichloroethylene, ethylene glycol ether and triethanolamine as the preparation The organic solvent in the process can greatly improve the compatibility between the components of the coating. The material of the defoamer is polydimethylsiloxane and dimethyl silicone oil or a mixture of two of them. The defoamer Then the defoaming effect in the whole coating preparation process can be improved.

[0041] The material ...

Embodiment 3

[0050] A carbon nanotube high-efficiency anti-corrosion coating formula, its raw materials are as follows by proportion: high chlorinated polyethylene resin 45%, organic bentonite 15%, carbon nanotube 4%, organic solvent 6%, organosilicon sol 8%, defoamer 3%, dispersant 5%, curing agent 2%, film-forming aid 1%, diluent 1%, silver powder 2%, plasticizer 2% and deionized water 6%.

[0051] The material of the organic solvent includes but not limited to styrene, perchlorethylene, trichloroethylene, ethylene glycol ether and triethanolamine, using styrene, perchlorethylene, trichloroethylene, ethylene glycol ether and triethanolamine as the preparation The organic solvent in the process can greatly improve the compatibility between the components of the coating. The material of the defoamer is polydimethylsiloxane and dimethyl silicone oil or a mixture of two of them. The defoamer Then the defoaming effect in the whole coating preparation process can be improved.

[0052] The mat...

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Abstract

The invention relates to the technical field of anti-corrosion coatings, in particular to a formula and a preparation method of a carbon nanotube efficient anti-corrosion coating. The formula of the carbon nanotube high-efficiency anticorrosive coating consists of high chlorinated polyethylene resin, organic bentonite, carbon nanotubes, an organic solvent, organic silica sol, a defoaming agent, a dispersing agent, a curing agent, a coalescing agent, a diluent, silver powder, a plasticizer and deionized water. In the preparation process of the carbon nanotube anticorrosive paint, the diluent, the silver powder and the plasticizer are added, so that the viscosity and the rheological property of the paint can be adjusted, the Van der Waals force among anticorrosive paint molecules can be properly weakened, and the condition of agglomeration among the paint in the storage process can be avoided; meanwhile, the heat resistance of the whole carbon nanotube anticorrosive paint in the using process can be improved, the overall using performance of the paint is further improved, and the using effect of the whole paint is further improved through the coalescing agent.

Description

technical field [0001] The invention relates to the technical field of anti-corrosion coatings, in particular to a carbon nanotube high-efficiency anti-corrosion coating formulation and a preparation method thereof. Background technique [0002] With the continuous development of science and technology in the field of coatings, research has proved that the application of nano-materials in coatings can not only improve the overall performance of coatings, but also add some new functions to coatings, such as self-cleaning, antistatic, and absorbing stealth etc., thereby improving the performance of coating products, and carbon nanotubes, as a new type of nanomaterial with great development potential, have the electrical conductivity of metal or semiconductor, extremely high mechanical strength, hydrogen storage capacity, adsorption capacity and strong microwave Characteristics such as absorption capacity are gradually applied in the field of coatings and are becoming more and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D123/28C09D5/10C09D7/61C09D7/20C09D7/63
CPCC09D123/286C09D5/10C09D7/61C09D7/20C09D7/63C09D5/18C08K2003/0806C08K3/346C08K3/041C08K3/08C08K5/06C08K5/12C08K5/523
Inventor 李蕾蕾吴功松
Owner 深圳市中科纳米科技有限公司
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