The invention discloses a catalytic
cracking gasoline adsorption dearsenification catalyst with large specific surface area, hierarchical
pore distribution and high dearsenification performance and a preparation method thereof, and the method comprises the following steps: 1) mixing
active carbon and pseudo-
boehmite in proportion,
grinding, stirring, adding a pore-enlarging agent and an acid solution, extruding into strips,
drying, and
roasting under an anaerobic condition to prepare a carbon-
alumina composite carrier; (2) adjusting the pH value of the
metal precursor solution, and impregnating the solution containing the active
metal precursor into the carrier by adopting an isovolumetric saturated impregnation method; and 3)
drying the catalyst, and
roasting in an
oxygen-free environment to obtain the finished product catalyst. The carrier with a composite pore channel structure can improve
diffusion, reaction and escape of reactant molecules in pore channels, and the reaction efficiency is improved;
metal with partially filled d tracks is selected as active metal, so that the acting force between the
arsenide and the metal can be improved, and the
arsenide is deeply removed; the pH value of the metal precursor solution is adjusted to be higher than the
isoelectric point of the metal
oxide or
hydroxide, the acting force between the metal and the carrier can be weakened, the
dispersity of the metal is improved, and finally the
arsenic removal efficiency of the catalyst is improved.