Highly reflective microcrystalline/amorphous materials, and methods for making and using the same
a microcrystalline/amorphous material, high-reflective technology, applied in the direction of spectral modifiers, inorganic chemistry, textiles and paper, etc., can solve the problems of increasing energy demand, air pollution, heat-trapping greenhouse gas emissions of power plants, increasing energy demand, etc., to increase the albedo of a surface and mitigate urban heat island effects
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example 4
Precipitated Pigment Example 4
[0176]Reaction 9 was precipitated by dissolving 67.23 g CuCl2 into 1 L of water and 84.01 g NaHCO3 into another liter of water. Then NaHCO3 solution was poured into CaCl2—CuCl2 solution with magnetic stirring and kept for 1 hour. The green precipitates were Buchner-filtered and the filtered slurry was initially dried using paper towels and then dried overnight under ambient condition.
[0177]These resulted in variously colored carbonate precipitates. Reaction 6 was light red, and Reaction 7 was rose / red. Reaction 8 produced a blue / green product and Reaction 9 produced a green product.
2. Manufacture of Albedo Enhancing Materials from Precipitate
a. Ceramic Samples
[0178]Precipitated powders were pressed to densify and observe reactions that may take place during the powder pressing process. Coupons were composed of 6-11 grams of powders (depending on volume of respective powders) and hydrated with 10 wt. % of a liquid phase to aid and / or promote any potentia...
example 1
Curing Example 1
[0189]As an example, sample 69, which originally consisted of ACC, transformed into calcite when cured in 1M Na2CO3 solution, while it transformed to aragonite in seawater. FTIR spectra comparing the original S69 and S69 cured in 1M Na2CO3 clearly indicated the formation of calcite by appearance of representative calcite peak at 713 cm−1 after 4 days.
example 2
Curing Example 2
[0190]As a comparison, S69 cured in seawater shows a completely different result, as peaks specific to aragonite at 853, 713, and 700 cm−1 continues to grow for 7 days. A possible reason for the diverging result is that high pH in Na2CO3 solution stabilizes the metastable ACC and amorphous vaterite precursor / anhydrous amorphous carbonate to calcite, and different kinds of cations and organic compounds induced transformation into aragonite in seawater as they inhibit calcite formation. For instance, past studies show evidence that the presence of Mg2+, Fe2+, and dissolved organic carbons (DOCs) inhibit calcite formation. The two resulting cured samples were intensely hardened, due to formation of calcite and aragonite.
[0191]As mentioned in previous section, amorphous vaterite precursor / anhydrous amorphous carbonate and ACCs are metastable phases of calcium carbonate that are prone to transformation into more stable polymorphs as calcite or aragonite depending on react...
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