Biological biodegradable self-control slow-releasing fertilizer and preparation method thereof

A slow-release fertilizer and biological technology, applied in fertilizer mixtures, nitrogen fertilizers, fertilization devices, etc., can solve the problems of poor nutrient controlled release performance, unfavorable food crops promotion and application, unfavorable handling, etc., and achieve good controlled release performance and degradability. The effect of expanding the scope of applicable crops and improving nitrogen use efficiency

Active Publication Date: 2007-09-19
格瑞昊尔斯生物科技(山东)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Inorganic coated fertilizers mainly use phosphate rock powder, calcium magnesium phosphate fertilizer, talcum powder, gypsum powder, fly ash, organic or inorganic bonding materials as coating materials in China (see Chinese patents 02126743.x, 03106547.3, 200410024201.1, 200610045310.0 etc.), although these inorganic coated fertilizers are cheap and simple to make, they have poor nutrient controlled release performance and low nitrogen use efficiency, and one-time application will easily cause crops to have defertilization phenomenon in the later stage; foreign countries mainly use TV.A comPany, USA Developed sulfur-coated urea (SCU) (US3295950) as a representative, although its price is not high, but the problem is that ① it is difficult to strictly control the release rate of its nutrients, because the sulfur coating is brittle and will The rupture of the membrane shell will cause all the nutrients in the membrane to be released suddenly, also known as "destructive release", which will often cause damage to the root system of the crop; ②After a large amount of sulfur shells are decomposed by microorganisms in the soil, it is easy to cause soil acidification; ③Sulfur coating Urea also has the problem that the sulfur coating is easy to oxidiz

Method used

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  • Biological biodegradable self-control slow-releasing fertilizer and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0048] (1) Preparation of water-soluble polymer coating material emulsion: cellulose in weight ratio: oxidized starch: polyvinyl alcohol: polyurethane prepolymer: epoxy resin E44: epoxy resin curing agent T593: crosslinking Agent N-methylolacrylamide: emulsifier Tween 80: initiator potassium persulfate: deionized water is 35:2:6:8:9:3:2:0.15:0.002:51 (unit: gram) Weigh each component of the water-soluble high molecular polymer respectively, then mix cellulose (hydroxymethyl cellulose: nitrocellulose: the mixing weight ratio between carboxymethyl cellulose is 1: 1: 1), Oxidized starch, polyvinyl alcohol (average degree of polymerization 1700-1800, molecular weight 84000-89000 Daltons), polyurethane prepolymer, epoxy resin E44, epoxy resin curing agent T593, N-methylolacrylamide Put it into a container filled with Tween 80 and deionized water, and shear and emulsify at 8000r / min for 0.5h at 25°C to obtain an emulsion; / ml solution as an initiator; adjust the pH value of the emu...

Embodiment 2

[0054] (1) Preparation of water-soluble polymer coating material emulsion: cellulose in weight ratio: oxidized starch: polyvinyl alcohol: polyurethane prepolymer: epoxy resin E44: epoxy resin curing agent T593: crosslinking Agent N-methylolacrylamide: emulsifier Tween 80: initiator potassium persulfate: deionized water is 28: 1.5: 5: 6: 14: 2.5: 1.5: 0.12: 0.0015: 50 (unit: gram) Weigh each component of the water-soluble polymer respectively, then cellulose (the mixing weight ratio between hydroxymethyl cellulose: carboxymethyl cellulose is 1: 1), oxidized starch, polyvinyl alcohol (the average degree of polymerization is 550-650, and the molecular weight is 27000-32000 Daltons), polyurethane prepolymer, epoxy resin E44, epoxy resin curing agent T593, N-methylolacrylamide poured into Tween 80 and deionized water container, at 24 ° C, shear emulsification at 9000r / mim speed for 0.6h to obtain an emulsion; at the same time, use the reserved deionized water to make potassium pers...

Embodiment 3

[0060] Pour 75g hydroxymethylcellulose, 75g nitrocellulose, 5g oxidized starch, 20g polyvinyl alcohol, 25g polyurethane prepolymer, 30g epoxy resin (E44), 10g T593, 5g N-methylolacrylamide into the container In a 1000ml beaker with 0.5g Tween 80 and 250ml deionized water, high-speed shear emulsification at room temperature for 0.5h, while using 5ml deionized water to make a solution of 0.005g potassium persulfate as an initiator. Use a pH adjuster to adjust the pH of the emulsion to 7.5, take 1 / 10 and 1 / 5 of the initiator solution of the above emulsion and add it to a four-necked bottle or a reaction kettle, blow nitrogen, raise the temperature to 75°C, and after 20 minutes, add the remaining The emulsion (mixed with 4 / 5 initiator solution) is added dropwise within 2 hours, and the reaction is continued for 3 hours to end the reaction to obtain a water-soluble high polymer coating material emulsion with cellulose as the main component.

[0061]Add urea or compound fertilizer g...

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Abstract

The invention discloses a biodegradable self-controlling slow-release fertilizer which is produced by uniformly coating a layer of controlled-release layer of water soluble macromolecule polymer at the surface of the urea or complex fertilizer grain. The weight ratio of the complex fertilizer grain to macromolecule polymer is 0.3-0.4:9.7-9.6. The macromolecule polymer is produced in proportion of fibrin, oxidized starch, polyvinyl alcohol, polyurethane prepolyme, epoxide resin, epoxide resin solidified agent, cross linker, emolsifier, ignition primer, deionized water. The invention adopts glue and latex crosslinking with a biodegradable material to improve the controlled-release capability of the fertilizer and conquer the ''white pollution'', increase the usage ratio of nitrogen of 20-35%, and satisfy the crop need in a whole growth period.

Description

technical field [0001] The invention relates to a self-controlled slow-release fertilizer and a preparation method thereof, in particular to a biodegradable self-control slow-release fertilizer which sprays a layer of water-soluble high polymer material on the surface of urea or compound fertilizer particles as a controlled-release layer and its preparation method. Background technique [0002] Chemical fertilizers are commonly and widely used as conventional fertilizers in crop planting, and they are easy to apply and have outstanding effects. However, there are many problems in the use of chemical fertilizers. One of the most prominent problems is the low nitrogen use efficiency and the resulting The economic loss and environmental pollution caused by the large-scale application of nitrogen fertilizer. How to greatly improve the nitrogen use efficiency of chemical nitrogen fertilizers and give full play to the role of chemical fertilizers is one of the most prominent prob...

Claims

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Application Information

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IPC IPC(8): C05G3/00C05C9/00
CPCY02P60/21
Inventor 林海涛刘兆辉江丽华张文君郑福丽王梅宋效宗刘海燕
Owner 格瑞昊尔斯生物科技(山东)有限公司
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