Fireproof flame-retardant polyurethane external wall thermal-insulation system material
A technology for thermal insulation and fire resistance of external walls, which is applied in the fields of fireproof coatings, heat preservation, and fire prevention. To achieve the effect of excellent fire and flame retardant properties
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Embodiment 1
[0021] Preparation of phosphorus-containing flame-retardant polyether polyol: heat and dissolve 0.2mol tetrabromobisphenol A, 0.5mol pentaerythritol, and 0.3mol sucrose, slowly add 0.3mol polyphosphoric acid at 100°C, react for 5 hours, and then drop 10mol epoxy Chloropropane is added dropwise to carry out ring-opening etherification reaction to obtain a flame-retardant polyether polyol containing 5 wt% of phosphorus and 10 wt% of bromine.
[0022] Preparation of amino heterocyclic polyether: add 1mol toluene diamine and 0.1mol melamine to the reaction flask, add 0.3g potassium hydroxide, heat and dissolve at 60°C, then pass in 3mol propylene oxide and 3mol ethylene oxide, react for 5h , to obtain a heterocyclic amino polyether polyol with a functionality of 4, a hydroxyl value of 420 mgKOH / g, and a viscosity of 1000 cp.
[0023] Bromination of polyphenyl polymethyl isocyanate: add bromine with a concentration of 8wt% dropwise to polyphenyl polymethyl isocyanate at room temper...
Embodiment 2
[0027] Phosphorus-containing flame-retardant polyether polyol 80g, heterocyclic amino polyether polyol 20g, silicone foam stabilizer 2g, catalyst dimethylethanolamine 2g, catalyst dibutyltin dilaurate 1g, flame retardant methylphosphoric acid di Mix 50 g of methyl ester and 20 g of fluorodichloroethane as a foaming agent to obtain component A; mix and foam brominated polyphenylpolymethyl isocyanate between component A and component B in a weight ratio of 1:1, and the isocyanate The index is 1.05. The obtained flame retardant polyurethane rigid foam material had an oxygen index of 31, a smoke density of 53, and a compressive strength of 0.5 MPa.
[0028] The moisture-proof primer, flame retardant polyurethane rigid foam material, interface agent, anti-crack mortar, fireproof paint and finishing paint are brushed on the wall from the inside to the outside to form the external wall insulation material.
Embodiment 3
[0030] Phosphorus-containing flame-retardant polyether polyol 50g, heterocyclic amino polyether polyol 50g, silicone foam stabilizer 2g, catalyst dimethylethanolamine 2g, catalyst dibutyltin dilaurate 1g, flame retardant tri(2) phosphate -Chloroethyl) ester 20g and foaming agent fluorodichloroethane 40g are mixed to obtain A component; A component and B component brominated polyphenyl polymethyl isocyanate are mixed in a weight ratio of 1:1 Foaming, isocyanate index 1.10. The obtained flame retardant polyurethane rigid foam material had an oxygen index of 29, a smoke density of 79, and a compressive strength of 0.7 MPa.
[0031] The moisture-proof primer, flame retardant polyurethane rigid foam material, interface agent, anti-crack mortar, fireproof paint and finishing paint are brushed on the wall from the inside to the outside to form the external wall insulation material.
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