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Method for increasing performance of modification layer on surface of material and application thereof

A surface modification layer and performance technology, applied in the field of surface modification of materials, can solve the problems of weak weather resistance and wear resistance, not yet suitable for practical use, poor bonding force, etc., to achieve dense film layer and improve bonding force and wear resistance, enhance the effect of bonding force

Active Publication Date: 2015-09-09
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] However, the single zinc-chromium film formed by zinc-chromium film coating technology has poor bonding force with the substrate, and its weather resistance and wear resistance are also weaker than traditional coatings.
In addition, there are few reports on the application of zinc-chromium film coating technology in the anti-corrosion application of NdFeB magnets, and it has not yet been adapted to practical application.

Method used

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  • Method for increasing performance of modification layer on surface of material and application thereof
  • Method for increasing performance of modification layer on surface of material and application thereof
  • Method for increasing performance of modification layer on surface of material and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0094] (1) Nd, B, Co, Cu, Al, Zr, Fe raw materials according to the mole percentage of Nd 25.8%, B 0.98%, Co1%, Cu 0.27%, Al 0.18%, Zr 0.4%, Febal ratio, the total alloy The mass is 5kg, put into the vacuum induction melting furnace at the same time, through the process of charging - vacuuming - preheating - argon filling - high power smelting - low power stirring - casting and other processes, the smelted alloy liquid (copper roller adopts cooling water Cooling, the rotating speed is about 35-50 rpm) to make a well-crystallized sheet with a thickness of about 0.3-0.4mm, and select an alloy quick-setting sheet with a smooth performance, uniform thickness, and bright white color to prepare powder for use.

[0095] (2) Put the selected quick-setting tablets into the special hydrogen crushing furnace, and carry out coarse crushing through positive and negative pressure detection-hydrogen absorption-heating-vacuum dehydrogenation-cooling-out of the furnace, etc. In nitrogen-protec...

Embodiment 2

[0109] Steps (1)~(5) are identical with steps (1)~(5) in embodiment 1;

[0110] The difference is as follows:

[0111] (6) Use gasoline and a NaOH solution with a concentration of 2mol / L to remove the oil stains on the surface of the small cylinder successively, and then place it in a sandblasting machine for surface derusting and descaling treatment (the diameter of the steel shot is: 0.1~ 0.3mm, sandblasting time: 20 minutes). Afterwards, the surface of the small cylinder is polished on a cylindrical grinder (polishing time: 30 minutes), and finally the polished small cylinder is placed in a mixture of absolute ethanol and acetone, and the surface of the magnet is further decontaminated under the action of ultrasonic waves Processing (ultrasonic frequency: 100 Hz, cleaning time: 10 minutes), take out the small cylinder and let it dry naturally at room temperature for later use.

[0112] (7) While cleaning the surface of the magnet, get sodium silicate and add zinc silicate...

Embodiment 3

[0118] Steps (1)~(5) are identical with steps (1)~(5) in embodiment 2;

[0119] (6) Use gasoline and NaOH solution with a concentration of 2% to remove the oil stains on the surface of the small cylinder after slicing, and then place it in the sandblasting machine for surface derusting and descaling treatment (the diameter of the steel shot is: 0.1 to 0.3 mm, sandblasting time: 30 minutes). Afterwards, the surface of the small cylinder is polished on a cylindrical grinder (polishing time: 40 minutes), and finally the polished small cylinder is placed in a mixture of absolute ethanol and acetone, and the surface of the magnet is further decontaminated under the action of ultrasonic waves Processing (ultrasonic frequency: 100 Hz, cleaning time: 20 minutes), take out the small cylinder and let it dry naturally at room temperature for later use.

[0120] (7) While cleaning the surface of the magnet, get sodium water glass and add zinc silicate to fully mix (zinc silicate accounts...

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Abstract

The invention discloses a method for increasing performance of a modification layer on surface of a material and an application thereof. The method comprises the following steps: coating inorganic zinc-rich silica sol on a surface to be processed of the material to form a priming coat, coating zinc chromium coating liquid on the priming coat to form a zinc chromium membrane; wherein the inorganic zinc-rich silica sol comprises a soluble alkali metal silicate material, inorganic gel and ultrafine zinc dust, and the zinc chromium coating liquid comprises sheet shape zinc dust, aluminium powder, chromic anhydride, boric acid and a surfactant. The method is capable of effectively increasing the performance of the modification layer on surface of the material, has the advantages of simple process, easy regulation and control, low cost, no pollution, safety and environmental protection, and is especially adapted to protection processing on neodymium iron boron permanent magnet obtained from various brands and various preparation methods, has wide application prospect on the magnetic material protection aspect, and the comprehensive properties of the modification layer on surface of the material is excellent.

Description

technical field [0001] The invention relates to a material surface treatment technology, in particular to a method for improving the comprehensive performance of a rare earth permanent magnet material, such as a surface protection layer of an NdFeB magnet, and belongs to the technical field of material surface modification. Background technique [0002] NdFeB permanent magnet materials have been widely used in voice coil motors, magnetic resonance imaging, general motors, generators, sensors, instruments and other fields due to their excellent magnetic properties. However, the poor corrosion resistance of NdFeB itself has seriously affected its application, so the research on the corrosion resistance of NdFeB is of great significance. Although many protection methods for NdFeB magnets have been developed at present, sintered NdFeB magnets have a large number of pores, and acid and plating solutions are easy to remain, resulting in long-term corrosion of magnets and coatings....

Claims

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Application Information

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IPC IPC(8): C23C22/76C23C22/82C09D1/00
CPCC09D1/00C09D5/10C23C24/00C23C28/00
Inventor 周巧英郭帅闫阿儒李东
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI