Polymer material containing microencapsulated rare earth metal hypophosphite, and preparation method thereof

A polymer material and rare earth metal technology, which is applied in the field of polymer materials containing microencapsulated rare earth metal hypophosphite and its preparation, and can solve the problem that halogen-containing flame retardants are harmful to the environment and the addition amount of inorganic flame retardants is high. , poor thermal stability, etc., to overcome the environmental hazards, reduce the amount of addition, and improve compatibility.

Inactive Publication Date: 2015-09-16
合肥安聚达新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to propose a polymer material containing microencapsulated rare earth metal hypophosphite and its preparation method to overcome the environmental hazards of halogen-containing flame retardants and the inorganic Disadvantages such as high addition of flame retardant, poor thermal stability, poor water resistance, etc.

Method used

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  • Polymer material containing microencapsulated rare earth metal hypophosphite, and preparation method thereof
  • Polymer material containing microencapsulated rare earth metal hypophosphite, and preparation method thereof
  • Polymer material containing microencapsulated rare earth metal hypophosphite, and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0022] Prepare materials according to each formula of proportioning 1 to proportioning 4 given in table 1 respectively, dry polybutylene terephthalate (PBT) masterbatch, glass fiber, microencapsulated lanthanum hypophosphite, Melamine cyanurate, polycarbonate, montmorillonite, maleic anhydride grafted polyolefin elastomer (POE-g-MAH), silicone powder, tetrakis[β-(3,5-di-tert-butyl-4 -Hydroxyphenyl)propionic acid]pentaerythritol ester (1010) mixed uniformly, heated to 240°C in a twin-screw extruder, melted and blended, then extruded, drawn, cooled, pelletized and dried, that is A polymer material containing microencapsulated rare earth metal hypophosphite according to the invention is obtained. Then, the sample strips for oxygen index test, vertical combustion test and tensile strength test are injection molded by the injection molding machine, and the combustion performance and mechanical performance test are carried out. The oxygen index test is carried out according to the ...

Embodiment 2

[0028] Prepare materials according to each formula of proportioning 5 to proportioning 8 given in Table 2 respectively, dry nylon 66 masterbatch, glass fiber, microencapsulated cerium hypophosphite, melamine polyphosphate, polyphenylene ether, di Silica, maleic anhydride grafted EPDM rubber (EPDM-g-MAH), ethylene bis stearic acid amide, tris (2,4-di-tert-butylphenyl) phosphite (168) mixed evenly , heated to 265 ° C in a twin-screw extruder, melted and blended, and then extruded, drawn, cooled, pelletized and dried to obtain the microencapsulated rare earth metal hypophosphite of the present invention. material. Then, the sample strips for oxygen index test, vertical combustion test and tensile strength test are injection molded by the injection molding machine, and the combustion performance and mechanical performance test are carried out. The oxygen index test is carried out according to the international standard ASTM D2863, the vertical burning test is carried out accordin...

Embodiment 3

[0034] Prepare materials according to each formula of proportioning 9 to proportioning 12 given in Table 3 respectively, dry thermoplastic polyester elastomer (TPEE), microencapsulated praseodymium hypophosphite, melem, polyphenylene sulfide, Mix mica, calcium stearate and pentaerythritol tetrakis (3-n-dodecyl thiopropionate) evenly, heat to 225°C, melt blend, then extrude, draw, cool, pelletize and bake After drying, the polymer material containing microencapsulated rare earth metal hypophosphite of the present invention is obtained. Sample bars for oxygen index test, vertical combustion test and tensile strength test were injected by injection molding machine for combustion and mechanical performance tests. The oxygen index test is carried out according to the national standard ASTM D2863, the vertical burning test is carried out according to the American standard UL 94, and the tensile strength test is carried out according to the international standard ASTM D638.

[0035]...

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Abstract

The invention discloses a polymer material containing microencapsulated rare earth metal hypophosphite, and a preparation method thereof. According to the percentages in the total mass of the composite material, 30-90% of a polymer material, 5-15% of microencapsulated rare earth metal hypophosphite, 5-10% of a nitrogen-series flame retardant, 0-30% of an enhancing agent, 0-6% of a char-forming agent, 0-2.5% of a nano-grade synergist, 0-5% of a compatibilizing agent, 0-1% of a lubricant, and 0-0.5% of an antioxidant are well mixed; the mixture is heated to a temperature of 120-265 DEG C; melt blending, extrusion, drawing, cooling, pelletizing and bake-drying are carried out, such that the polymer material provided by the invention is obtained. The polymer material provided by the invention has good flame retardant property, good mechanical performances, good water precipitation resistance and good weather resistance. With the preparation method, defects of high halogen flame retardant environmental hazard, high inorganic flame retardant addition amount, poor thermal stability, poor water resistance and the like of traditional polymer flame-retardant modification technologies are overcome. The method and the material have good application prospect.

Description

technical field [0001] The invention relates to the technical field of halogen-free flame retardancy and plastic processing application, in particular to a polymer material containing microencapsulated rare earth metal hypophosphite and a preparation method thereof. Background technique [0002] Compared with traditional materials such as cement, glass, ceramics and steel, polymer materials are latecomers, but their development speed and wide range of applications have greatly surpassed traditional materials. In recent years, polymer materials are no longer substitutes for traditional materials, but have become important materials in the fields of industry, agriculture, national defense and science and technology. Polymer materials are ubiquitous, widely permeated in all aspects of human life, and play a huge role in people's lives. However, polymer materials generally have the disadvantages of being flammable, easy to drip after burning, and producing a lot of toxic fumes....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L69/00C08L77/06C08L51/06C08L71/12C08L67/00C08L81/02C08K13/06C08K9/10C08K3/32C08K5/3492C08K7/14C08K3/34
Inventor 杨伟时虎
Owner 合肥安聚达新材料科技有限公司
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