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Degradable film and preparation method thereof

A technology for degrading film and film blowing machine is applied in the field of degradable composite film and its preparation, which can solve the problems affecting the mechanical properties of film materials, the compatibility needs to be further improved, and the application field is limited, so as to improve product competitiveness and reduce Preparation cost and effect of broadening application fields

Inactive Publication Date: 2016-04-27
六安载丰新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Chinese patent 200910109765.8 discloses an antistatic degradable film material and its preparation method. The film is prepared by using low-density polyethylene, linear low-density polyethylene, starch-based degradable plastic raw materials and antistatic masterbatch, and the finished product has good antistatic effect , with excellent mechanical properties, but this film material is only partially degraded, which still has a certain impact on the environment
Chinese patent 201019050017.7 introduces a method for preparing a biodegradable film that prevents damage to the soil structure. Starch, polyvinyl alcohol, PHB and other auxiliary materials are extruded and granulated and then blown into a film. The process is simple and easy to operate, but each material The compatibility between them needs to be further improved, which will affect the mechanical properties of thin film materials and limit their application fields.

Method used

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  • Degradable film and preparation method thereof
  • Degradable film and preparation method thereof
  • Degradable film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Dry polybutylene terephthalate / adipate, thermoplastic starch, PHA resin and fillers, wherein the drying of polybutylene terephthalate / adipate, thermoplastic starch and polyvinyl alcohol The temperature is 60°C, the filler drying temperature is 90°C, and the time is 12h;

[0027] (2) Weigh 90 parts of polybutylene terephthalate / adipate, 10 parts of thermoplastic starch, 1 part of PHA resin, 0.2 part of compatibilizer acrylic acid, 0.2 part of antioxidant 264 and 1 part of filler talcum powder, Mix evenly in a high mixer, mixing time 3min;

[0028] (3) Add the mixed material into a twin-screw extruder for melt blending, then strand and pelletize to obtain blended pellets, and the extrusion temperature is 100° C.;

[0029] (4) Extrude step (3) blended granules and 0.2 parts of lubricant methylene bis stearamide through a single-screw extruder, and blow molding at a film blowing machine to obtain a degradable film, wherein the feeding of the film blowing machine The t...

Embodiment 2

[0032] (1) Dry polybutylene terephthalate / adipate, thermoplastic starch, PHA resin and fillers, wherein the drying of polybutylene terephthalate / adipate, thermoplastic starch and polyvinyl alcohol The temperature is 70°C, the filler drying temperature is 100°C, and the time is 10h;

[0033] (2) Weigh 70 parts of polybutylene terephthalate / adipate, 20 parts of thermoplastic starch, 10 parts of PHA resin, 1 part of compatibilizer maleic anhydride, 0.9 parts of antioxidant 1010 and 10 parts of filler carbonic acid Barium, mixed evenly in a high mixer, mixing time 5min;

[0034] (3) Add the mixed material into a twin-screw extruder for melt blending, then strand and pelletize to obtain blended pellets, and the extrusion temperature is 120° C.;

[0035] (4) Extrude the blended granules of step (3) and 1 part of lubricant erucamide through a single-screw extruder, and blow them in a blown film machine to obtain a degradable film, wherein the feed temperature of the blown film machi...

Embodiment 3

[0038] (1) Dry polybutylene terephthalate / adipate, thermoplastic starch, PHA resin and fillers, wherein the drying of polybutylene terephthalate / adipate, thermoplastic starch and polyvinyl alcohol The temperature is 80°C, the filler drying temperature is 110°C, and the drying time is 8h;

[0039] (2) Weigh 50 parts of polybutylene terephthalate / adipate, 30 parts of thermoplastic starch, 20 parts of PHA resin, 3 parts of compatibilizer maleic anhydride grafted ethylene octene copolymer, 2 parts of antioxidant Agent 168 and 20 parts of filler calcium carbonate, mixed uniformly in a high mixer, mixing time 7min;

[0040] (3) Add the mixed material into a twin-screw extruder for melt blending, then strand and pelletize to obtain blended pellets, and the extrusion temperature is 150° C.;

[0041] (4) Extrude and blow the blended granules in step (3) and 2 parts of lubricant sodium stearate through a single-screw extruder to obtain a degradable film. The tempering section temperat...

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Abstract

The invention relates to a degradable film and a preparation method thereof. The method comprises the following steps: 1) drying PBT / adipate terephthalate, thermoplastic starch, PHA resin and a filling material; 2) weighing PBT / adipate terephthalate, the thermoplastic starch, the PHA resin, a compatibilizer, an and the filling material in proportion, uniformly mixing the components in a high mixing machine for 3-10 minutes; 3) adding a mixture in a double screw extruder for melt blending, bracing the mixture, and pelletizing the mixture to obtain blending particles, wherein the extrusion temperature is 100-170 DEG C; and 4) extruding the blending particles in the step 3) and a lubricant through a single screw extruder, then performing blow molding by a film blowing machine to obtain the degradable film. Compared with the prior art, the prepared degradable film is adapted to different climate condition at different places, is degraded after a certain time, cannot generate secondary pollution, and has important practical meaning for environment treatment.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and relates to a degradable composite film and a preparation method thereof. Background technique [0002] Petrochemical plastic products have already penetrated into various fields of human life. While bringing convenience to people, they inevitably bring about problems such as energy consumption and environmental pollution. At present, the "white pollution" caused by the extensive use of plastic products has brought serious harm to the ecological environment, such as the reduction of production in many fertile fields, land desertification, and river blockage. As an environmentally friendly material, degradable plastics have become the focus of research and development in the world today, and their development has alleviated environmental conflicts and resource constraints to a certain extent. Application prospect. [0003] Polybutylene terephthalate / adipate (PBAT) is a ternary copol...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L67/04C08L3/02C08K13/02C08K5/09C08K3/34C08K5/20C08K3/26C08K3/36
Inventor 严莉莉
Owner 六安载丰新材料有限公司
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