Filamentous clay material for 3D printing and preparation method thereof
A 3D printing and clay technology, which is applied to clay products, applications, household appliances, etc., can solve the problems that hinder the development and application of 3D printing technology, limit the application of clay and its products, and complicate preparation methods of ceramic powder, so as to achieve easy molding shape Controlled, neatly arranged, evenly sized effects
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Embodiment 1
[0024] 1. Add 50 parts by weight of kaolin with a fineness of 1000 mesh, 30 parts by weight of water and ethanol in a 1:1 miscible ethanol solution, and 3 parts by weight of silicon carbide whiskers into a planetary ball mill for mixing and grinding for 0.5h, then Add 5 parts by weight of alkyl ammonium salt, emulsify with ultrasonic waves for 20 minutes, and spray dry with a spray dryer to obtain a clay mixture powder material;
[0025] 2. Put the clay mixture powder material obtained in step 1, 8 parts by weight of methyl silicone oil, and 20 parts by weight of polylactic acid into a high-speed mixer at a speed of 200r / min for 30 minutes to discharge, and extrude with a twin-screw Extrude and draw wires to make filaments with a diameter of 1.75mm and a diameter error within 5%. Collect the filaments to obtain clay 3D printing materials, and use cold air to cool them during the wire drawing process.
Embodiment 2
[0027] 1. Add 65 parts by weight of montmorillonite with a fineness of 1000, 40 parts by weight of water and ethanol in a 1:1 miscible ethanol solution, and 8 parts by weight of silicon nitride whiskers in a planetary ball mill for mixing and grinding for 1 hour, Then add 10 parts by weight of sodium alkyl phosphate, emulsify with ultrasonic waves for 30 minutes, and spray dry with a spray dryer to obtain a clay mixture powder material;
[0028] 2. Put the clay mixture powder material obtained in step 1, 12 parts by weight of sodium phthalate and 35 parts by weight of polyethylene into a high-speed mixer and mix it at a speed of 300r / min for 40 minutes to discharge the material, and extrude it with a twin-screw It is extruded out of the machine and drawn to make filaments with a diameter of 3mm and a diameter error within 5%. The filaments are collected to obtain clay 3D printing materials. During the drawing process, cold air is used for cooling.
Embodiment 3
[0030] 1. Add 50 parts by weight of kaolin with a fineness of 2000 mesh, 40 parts by weight of an ethanol solution miscible with water and ethanol at a ratio of 1:1, and 5 parts by weight of potassium titanate whiskers in a planetary ball mill for mixing and grinding for 0.5 h, Then add 5 parts by weight of fatty alcohol sodium sulfate, carry out emulsification treatment with ultrasonic waves for 30min, and use a spray dryer to carry out spray drying to obtain the clay mixture powder material;
[0031] 2. Put the clay mixture powder material obtained in step 1, 12 parts by weight of amino silicone oil, and 20 parts by weight of polypropylene into a high-speed mixer at a speed of 250r / min for 35 minutes to discharge, and use a twin-screw extruder Extrude and wire-draw to make filaments with a diameter of 1.75mm and a diameter error within 5%, collect the filaments to obtain clay 3D printing materials, and use cold air to cool during the wire-drawing process.
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Abstract
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