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Laminated pipe material for high-rise drainage and manufacturing method thereof

A laminated pipe and high-rise technology, applied in the field of laminated pipes for high-rise drainage and its preparation, can solve the problems of poor thermal stability of PVC resin, harsh processing conditions, poor low temperature resistance, etc., to overcome melt fracture, shorten Effect of plasticizing time and improving compatibility

Active Publication Date: 2018-11-23
HUZHOU JINJIE IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, due to the disadvantages of PVC resin itself, such as poor thermal stability, poor low temperature resistance, poor fluidity and insufficient toughness, it is necessary to add various additives to improve its performance.
Therefore, domestic and foreign countries have successively developed high-impact PVC pipes, mainly using elastomers for toughening, and the most widely used is chlorinated polyethylene (CPE). This method can improve the toughness of PVC pipes, but the amount of CPE added Larger, due to the network toughening mechanism of CPE, the processing conditions are relatively harsh, and it is difficult to achieve a rigid-tough balance
Although this kind of pipe has been promoted to a certain extent, its impact resistance at low temperature (-10°C) is still poor. At the same time, the existing pipe has high density, short pressure resistance time, and high production cost.

Method used

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  • Laminated pipe material for high-rise drainage and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0069] A laminated pipe for high-rise drainage, which consists of the following components in terms of mass fraction:

[0070] 60 parts of polyvinyl chloride resin;

[0071] 2 parts of organotin stabilizer;

[0072] 1 part stearic acid;

[0073] 2 parts of modified ACR;

[0074] 2 parts of titanium dioxide;

[0075] 2 parts of modified nano calcium carbonate;

[0076] Brightener 0.5;

[0077] 0.5 parts of MBS resin;

[0078] Among them, the organic tin stabilizer can be one of maleate, mercaptide, and mercaptan fatty acid salt; the polyvinyl chloride resin model is ethylene hair SG-5 resin;

[0079] The preparation of MBS resin in the raw material comprises the following steps:

[0080] Add soft water, emulsifier, and monomer into the reaction kettle and stir, then add potassium persulfate or ammonium persulfate initiator to initiate the reaction. The reaction occurs at a temperature of 90°C and a stirring speed of 200r / min. After the reaction is completed, the temperat...

Embodiment 2

[0093] A laminated pipe for high-rise drainage, which consists of the following components in terms of mass fraction:

[0094] 70 parts of polyvinyl chloride resin;

[0095] 3 parts of stabilizer;

[0096] 3 parts stearic acid;

[0097] 5 copies of modified ACR;

[0098] 5 parts of titanium dioxide;

[0099] 6 parts of modified nano calcium carbonate;

[0100] Brightener 0.8;

[0101] 1.3 parts of MBS resin;

[0102] Wherein the organotin stabilizer can be one of tribasic lead sulfate, dibasic lead phosphite, and lead stearate;

[0103] The preparation of described MBS resin comprises the following steps:

[0104] Add soft water, emulsifier, and monomer into the reaction kettle, stir, and then add potassium persulfate or ammonium persulfate initiator to initiate the reaction. The reaction occurs at a temperature of 110°C and a stirring speed of 250r / min. After the reaction is completed, the temperature is lowered to obtain MBS. The intermediate emulsion is then spray-d...

Embodiment 3

[0117] A laminated pipe for high-rise drainage, which consists of the following components in terms of mass fraction:

[0118] 80 parts of polyvinyl chloride resin;

[0119] 5 parts of stabilizer;

[0120] 5 parts of stearic acid;

[0121] 8 parts of modified ACR;

[0122] 8 parts of titanium dioxide;

[0123] 6 parts of modified nano calcium carbonate;

[0124] Brightener 1;

[0125] 2 parts of MBS resin;

[0126] The preparation of described MBS resin comprises the following steps:

[0127] Add soft water, emulsifier, and monomer into the reaction kettle and stir, and then add potassium persulfate or ammonium persulfate initiator to initiate the reaction. The reaction occurs at a temperature of 120°C and a stirring speed of 300r / min. After the reaction is completed, the temperature is lowered to obtain MBS. The intermediate emulsion is then spray-dried to obtain the finished product MBS resin powder; the emulsifier is sodium allyloxy hydroxypropyl sulfonate; the monom...

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PUM

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Abstract

The invention belongs to the technical field of plastic tubular products, and in particular, relates to a laminated tubular product for high-rise water drainage and a manufacturing method thereof. The laminated tubular product is composed of the following components: polyvinyl chloride resin, a stabilizer, stearic acid, modified ACR, titanium dioxide, modified nano calcium carbonate and the like; preparation of the modified ACR comprises the following steps: (1) seed emulsion preparation: with butyl acrylate and styrene as monomers, adding a lauryl sodium sulfate emulsifier and a potassium persulfate initiator, stirring and heating to prepare a seed emulsion; (2) inner core preparation: continuing to add the potassium persulfate initiator and the butyl acrylate and styrene monomers, and introducing tetrafluoroethylene gas, to prepare an inner core; and (3) outer shell preparation: continuing to add the lauryl sodium sulfate emulsifier and the potassium persulfate initiator, adding methyl methacrylate, and adding modified nano SiO2, to prepare an outer shell; and (4) carrying out spray drying, to prepare the modified ACR. The vinyl chloride tube has the advantages of good impact resistance and good pressure resistance.

Description

technical field [0001] The invention belongs to the technical field of plastic pipes, and in particular relates to a laminated pipe for high-rise drainage and a preparation method thereof. Background technique [0002] In the water supply system, plastic pipes have the characteristics of non-corrosion, good hygienic performance, and easy installation. They have been vigorously promoted in our country, and it is the general trend to replace traditional galvanized iron pipes. Plastic water supply pipes mainly include: PVC, polyethylene (PE), polypropylene (PP), etc. Compared with other polyolefin pipes, PVC pipes have high strength, good flame retardancy, high ring stiffness, and excellent weather resistance Performance, low price and other advantages, have been widely used. [0003] However, due to the disadvantages of PVC resin itself, such as poor thermal stability, poor low temperature resistance, poor fluidity and insufficient toughness, various additives are added to im...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08L51/04C08L51/00C08K9/06C08K3/36C08K9/10C08K3/26C08F220/18C08F212/08C08F214/26C08F265/06C08F220/14B29C61/08
CPCB29C61/08C08F220/18C08F220/1804C08F265/06C08K2201/011C08L27/06C08L2203/18C08L2205/03C08L2207/53C08L51/04C08L51/003C08K9/06C08K3/36C08K9/10C08K2003/265C08F220/14C08F212/08C08F214/265
Inventor 沈宇龙
Owner HUZHOU JINJIE IND CO LTD
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