Green phase bright yellow inorganic nanometer pigment and preparation method thereof

An inorganic nano and inorganic pigment technology, applied in the field of inorganic pigments, can solve the problems such as the decrease of yellow chromaticity value and affect the color rendering effect of pigments, and achieve the effect of uniform size and good dispersion.

Active Publication Date: 2017-07-14
JINGDEZHEN CERAMIC INSTITUTE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Bi 2 MoO 6 and Bi 2 WO 6 Although the introduction of the pigment can make the pigment present a stable green-shade yellow (a* value is about -5),

Method used

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  • Green phase bright yellow inorganic nanometer pigment and preparation method thereof
  • Green phase bright yellow inorganic nanometer pigment and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0022] Example 1 Bi 0.88 Zn 0.08 Nd 0.04 V 0.9 Al 0.1 O 4-δ Pigment preparation

[0023] According to theory, 0.25mol / L Bi can be synthesized 0.88 Zn 0.08 Nd 0.04 V 0.9 Al 0.1 O 4-δ Prepare the solution.

[0024] First, according to the formula composition, the bismuth nitrate pentahydrate (Bi(NO 3 ) 3 ·5H 2 O), ammonium metavanadate (NH 4 VO 3 ), zinc nitrate hexahydrate (Zn(NO 3 ) 2 ·6H 2 O), neodymium nitrate (Nd(NO 3 ) 3 ) And aluminum nitrate nonahydrate (Al(NO 3 ) 3 ·9H 2 O) Add to pure water, stir and heat to 80°C continuously, then add diethylenetriaminepentaacetic acid as complexing agent, and obtain a mixed solution after fully dissolving each component. The molar ratio of complexing agent to total metal ion It is: complexing agent: metal ion=2.5:2. While continuing to stir, add sodium dodecylbenzene sulfonate as a dispersant. The amount of dispersant is 0.35% (relative to the mass percentage concentration of the added water). After the dispersant is fully dissolved, 10%...

Example Embodiment

[0025] Example 2 Bi 0.9 Zn 0.1 V 0.88 Al 0.06 Mo 0.06 O 4-δ Pigment preparation

[0026] According to theory, 0.4mol / L Bi can be synthesized 0.9 Zn 0.1 V 0.88 Al 0.06 Mo 0.06 O 4-δ Prepare the solution.

[0027] First, according to the formula composition, the bismuth oxide (Bi 2 O 3 ), vanadium pentoxide (V 2 O 5 ), zinc oxide (ZnO), aluminum oxide (Al 2 O 3 ) And ammonium molybdate tetrahydrate, etc. were added to pure water, stirred and heated to 90 ℃, and then added diethylene triamine pentaacetic acid as a complexing agent, the components were fully dissolved to obtain a mixed solution, in which the complexing agent and metal The molar ratio of the total amount of ions is: complexing agent: metal ion=4:2. While continuing to stir, add sodium dodecylbenzene sulfonate as a dispersant, and the amount of dispersant is 0.2% (relative to the mass percentage concentration of the added water). After the dispersant is fully dissolved, 10% ammonia water is added dropwise to adjust the ...

Example Embodiment

[0028] Example 3 Bi 0.92 La 0.08 V 0.9 Ta 0.1 O 4-δ Pigment preparation

[0029] According to theory, 0.5mol / L Bi can be synthesized 0.92 La 0.08 V 0.9 Ta 0.1 O 4-δ Prepare the solution.

[0030] First, according to the formula composition, the bismuth nitrate pentahydrate (Bi(NO 3 ) 3 ·5H 2 O), ammonium metavanadate (NH 4 VO 3 ), lanthanum nitrate hexahydrate (La(NO 3 ) 2 ·6H 2 O) Add tantalum oxalate to pure water, stir and heat to 80°C, then add ethylenediaminetetraacetic acid as a complexing agent. After the components are fully dissolved, a mixed solution is obtained. The total amount of complexing agent and metal ions is The molar ratio is: complexing agent: metal ion=3:2. While continuing to stir, add sodium lauryl sulfate as a dispersant, and the amount of dispersant is 0.3% (relative to the mass percentage concentration of the added water). After the dispersant is fully dissolved, 10% ammonia water is added dropwise to adjust the pH of the solution to 9, and the uniform p...

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Abstract

The invention discloses a green phase bright yellow inorganic nanometer pigment and a preparation method thereof. According to the present invention, by combing a complexation method and uniform precipitation, a small amount of metal ions are used to dope and Bi and V in BiVO4 are simultaneously substituted to prepare a yellow pigment so as to easily inhibit the conversion of the crystal phase structure of the pigment into the tetragonal phase and obtain the pure the monoclinic scheelite type crystal phase pigment, and by co-doping ions at different lattice positions, the electron structure of the crystal formed by the pigment can be effectively regulated, such that the reflectivity of the crystal on the yellow light and the absorption of the crystal on the blue light can be improved, and the pigment has the bright green phase yellow tone, wherein the L* value, the a* value and the b* value respectively are 90-92, -3 to -6 and 90-92.5; and the yellow inorganic pigment with characteristics of environmental protection, no toxicity, good stability and high performance has good application prospects in the fields of coating materials, plastics, ink and the like, and can replace toxic yellow organic pigments.

Description

technical field [0001] The invention belongs to the field of inorganic pigments, in particular to a green phase bright yellow inorganic nano pigment and a preparation method thereof. Background technique [0002] As an important inorganic composite oxide pigment, bismuth vanadate (BiVO 4 ) yellow pigment is expected to replace the traditional lead chrome yellow, cadmium yellow and zinc chrome yellow and other yellow pigments containing lead, chromium and cadmium toxic heavy metals due to its strong weather resistance, green environmental protection and non-toxicity. , strong tinting strength, long service life and unique infrared reflection, etc., are widely used in coatings, plastics, cosmetics and ink industries. Especially the BiVO which exhibits a green phase 4 The yellow pigment has the characteristics of bright and vivid, eye-catching, high tone and strong hiding power. Its color rendering effect is close to the high-performance yellow organic pigment of the same app...

Claims

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Application Information

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IPC IPC(8): C01G31/00C09C1/00C09C3/06B82Y40/00B82Y30/00
CPCB82Y30/00B82Y40/00C01G31/00C01P2002/72C01P2004/03C01P2004/62C01P2006/62C01P2006/63C01P2006/64C09C1/0006C09C3/06
Inventor 张小珍汪永清江瑜华常启兵白明敏
Owner JINGDEZHEN CERAMIC INSTITUTE
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