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Gas generator

A technology of gas generator and gas generating agent, which is applied in the field of gas generators and gas generators for automobile airbags, can solve the problems of inability to maintain well, short ignition delay period and high combustion temperature, and achieves improvement of ignition delay or fluctuation. Large, good gloss and form, the effect of improving ignition performance

Active Publication Date: 2018-06-29
HUBEI HANGPENG CHEM POWER TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this patent only uses titanate as the only shape-retaining agent, which has no obvious effect on shape retention and cannot play a good role in combustion state retention, especially for the content of basic copper nitrate greater than 40%, and the content of guanidine nitrate greater than 40%. 40% of the gas generating agent can not play a good role in maintaining the combustion form, and the gas generating agent formula is not easy to be ignited
[0015] For example, patent CN100376515C discloses a gas-generating composition, including guanidine nitrate, basic copper nitrate, auxiliary oxidant sodium nitrate, copper oxide and iron oxide, and ignition improver (aluminum sesquioxide, copper chloride, copper chromate, Potassium chromate), the gas-generating composition that adopts ignition modifier to make it easier to ignite, and the ignition delay period is short, but aluminum oxide is generally used for residue agglomeration, and has little effect on ignition improvement; copper chloride is a weak oxidant for ignition The improvement effect is not great; copper chromate and potassium chromate are strong oxidants containing copper, which can improve ignition to a certain extent, but both will increase the residue content. Copper chromate increases the insoluble residue content, and potassium chromate increases The content of dissolved residues, and the substances containing alkali metal potassium will form soluble aerosol particles after burning, which is not conducive to the agglomeration of residues
[0016] Another example is that the patent US5827996A discloses a gas generating agent for an airbag, including fuels using azoles or metal salts thereof, oxidizers, combustion catalysts, combustion control agents and slagging agents, fuels using azoles and metal salts, and slagging agents are solidified Additives for the combustion residues of gas generants, thereby facilitating the removal of residues by the filter in the airbag, but this patent is applicable to the formulation of azoles as fuel, which has a higher combustion temperature than the guanidine nitrate basic copper nitrate type formulation Too much, the shape of the tablet cannot be well maintained even if the slag forming agent is added
[0017] In addition, patent CN101952227B discloses a method for preparing a gas generating agent, adding guanidine nitrate, basic copper nitrate, auxiliary oxidants (such as potassium nitrate, strontium nitrate and sodium nitrate), burning rate regulator (potassium perchlorate), slag promoter agent (silicon dioxide, zinc oxide, ammonium oxide, aluminum oxide), tablet release aid and form retention synergistic aid B (graphite, molybdenum disulfide, tungsten disulfide, boron nitride), the granulation used in this patent The method is spray granulation, which consumes more energy than wet granulation; in addition, the slag accelerator used in this patent mainly comes from metal oxides, such as silicon dioxide, aluminum oxide, zinc oxide, and cerium oxide , metal oxides as slag accelerators can play a certain role in promoting slag agglomeration, but the effect on tablet shape maintenance is not obvious; at the same time, the patent uses tablet release aids such as: graphite, molybdenum disulfide, Tungsten disulfide, boron nitride, these additives only play the role of tableting aids, and cannot cooperate with metal oxides to promote slag agglomeration

Method used

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preparation example Construction

[0118] The present invention adopts the mode of wet granulation to prepare ignition agent composition, and specific preparation method comprises the following steps:

[0119] (1), the first material is obtained after mixing strontium nitrate, 5-aminotetrazole, potassium nitrate, mica powder, aluminum oxide, graphite and boron nitride; it can be mixed in a mixing device to obtain the first material, mixed The time is ≤20min; the mixing equipment can use a ribbon mixer.

[0120] (2), add water to the first material and carry out wet mixing to obtain the second material, wherein the amount of water added is 3% to 15% of the total mass of the first material; the wet mixing time is 2min to 15min; wet mixing equipment For kneader or mixer.

[0121] (3), passing the second material through a 10-40 mesh screen to obtain the third material;

[0122] (4), drying the third material until the water content is less than 0.5% of the total mass of the third material, and then passing throu...

Embodiment 1

[0146] The ignition agent composition comprises the following components in mass percent content:

[0147]

[0148] After these components are weighed, they are compressed into discs with a diameter of 6.4 mm and a thickness of 2.7 to 3.1 mm by wet granulation and a rotary tablet press. The specific preparation method is: mix strontium nitrate, 5-aminotetrazole (5-AT), potassium nitrate, mica powder, aluminum oxide, graphite and boron nitride through a ribbon mixer to obtain the first material; Add 10% (mass percentage content, the same below) distilled water to a material and carry out wet kneading for 12 minutes to obtain a second material, pass the second material through a 10-mesh screen to obtain a third material; dry the third material, and dry When the water content is less than 0.5% of the total mass of the third material, the fourth material is passed through a 20-mesh sieve again; the fourth material is formed by a rotary tablet press to obtain a circular sheet st...

Embodiment 2

[0154] The ignition agent composition comprises the following components in mass percent content:

[0155]

[0156]

[0157] After these components are weighed, they are compressed into discs with a diameter of 6.4 mm and a thickness of 2.7 to 3.1 mm by wet granulation and a rotary tablet press. The specific preparation method is: mix strontium nitrate, 5-aminotetrazole (5-AT), potassium nitrate, mica powder, aluminum oxide, graphite and boron nitride through a ribbon mixer to obtain the first material; Add 6% distilled water to the first material and carry out wet kneading for 10 minutes to obtain the second material, pass the second material through a 10-mesh screen to obtain the third material; dry the third material until the water content is less than the total amount of the third material 0.5% of the mass, the fourth material was obtained through a 10-mesh screen again; the fourth material was formed by a rotary tablet press to obtain a circular sheet structure.

...

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Abstract

The invention relates to a gas generator. An ignition medicament composition adopted by the gas generator is prepared from the following components by mass percent: 40%-60% of strontium nitrate, 25%-40% of 5-amino tetrazole5-AT, 1%-20% of potassium nitrate, 1%-20% of mica powder, 0.5%-10% of aluminum oxide, 0.1%-10% of graphite, and 0.1%-10% of boron nitride. The ignition medicament component prevents the tablet from sticking a mold in a tableting process, the tableted tablet can well maintain the original gloss and form, the phenomenon that the ignition medicament is delay in ignition or large in fluctuation at low temperature of -40 DEG C, the impact range of the ignition medicament worked at the temperature of -40 to +90 DEG C is wider, and the ignition is more uniform when the propellant is ignited is more uniform, the consistency is better, and the ignition performance is obviously improved. Furthermore, the propellant composition adopted by the gas generator can well maintain theform before combustion after the tablet is combusted, thereby preventing the combusted tablet from melting and sputtering to damage the airbag, and the combustion speed is improved when the low-temperature ignition performance of the composition is obviously improved.

Description

technical field [0001] The invention relates to a gas generator, in particular to a gas generator for an automobile safety airbag, and belongs to the technical field of automobile safety airbags. Background technique [0002] As we all know, with the development of highways and the improvement of automobile performance, the speed of automobiles is getting faster and faster, which makes the traffic accidents of vehicles more frequent, so the airbag system, which is an important part of automobile passive safety, is particularly important. The airbag consists of a gas generator and an air bag. A very important part of the airbag system is the gas generator, its function is to generate a sufficient volume of gas at a fast enough rate in a short time to supply the airbag. Automobile airbags are one or more inflatable devices installed in the front and rear of the car or inside the seat and the interior of the car to protect the key parts of the driver and passengers from and re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C06D5/06C06B31/04C06B23/00C06B31/00C06B21/00B60R21/264
CPCB60R21/2644C06B21/0066C06B23/00C06B31/00C06B31/04C06D5/06
Inventor 罗运强任响宁周雄张俊王晨温常琰习亮任兴仑阮家声夏强
Owner HUBEI HANGPENG CHEM POWER TECH
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