Automobile interior decorative part and preparation method thereof
A technology for automobile interior parts and epoxy resin, which is applied in the field of automobile manufacturing, can solve the problems of polluted environment, increased brittleness of composite resin, decreased impact resistance, etc., and achieves improved flame retardant and smoke suppression performance, excellent flame retardant performance, The effect of high strength flame retardant properties
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[0029] Simultaneously, in the present invention also provides a kind of preparation method according to flame-retardant type composite resin of the present invention, comprises the following steps:
[0030] (1) Mix the chlorine source, epoxy resin and catalyst uniformly in the first part of the organic solvent, and then heat and reflux at 80-120° C. for 1-8 hours to obtain the mixed system 1;
[0031](2) Add polyether polyol and the first part of the chain extender to the mixed system 1, and then react at 60-80°C for 0.5-5h to obtain the mixed system 2;
[0032] (3) Add isocyanate, reinforcing fiber, the second part of chain extender, surfactant and the second part of organic solvent to the mixed system 2, react at 80-100°C for 2-6 hours, add curing agent, after curing and forming , to obtain a flame-retardant composite resin.
[0033] According to the present invention, preferably, the weight ratio of the first part of organic solvent to the second part of organic solvent is...
Embodiment 1
[0045] (1) Composite resin preparation:
[0046] Mix 12g of phosphorus pentachloride, 100g of novolac epoxy resin and 10g of triethylbenzyl ammonium chloride in 100g of dimethyl sulfoxide, and then heat and reflux at 100°C for 6h to obtain a mixed system 1;
[0047] Add 25g of polytetrahydrofuran diol and 4g of ethylene glycol to the mixed system 1, and then react at 75°C for 2 hours to obtain the mixed system 2;
[0048] Add 30g isocyanate, 10g aluminum oxide whisker (diameter is 80nm, length is 5 μ m), 2g ethylene glycol, 5g sodium lauryl alcohol polyoxyethylene ether sulfate and 50g dimethyl sulfoxide in mixed system 2, in After reacting at 90° C. for 4 hours, 12 g of 2,4,4-trimethylhexamethylenediamine was added and cured to obtain a flame-retardant composite resin.
[0049] (2) Preparation of automotive interior parts: put polyester fabric and flame-retardant composite resin in the mold, under the conditions of clamping force 700T, injection pressure 3bar, pressure switc...
Embodiment 2
[0051] (1) Composite resin preparation:
[0052] Mix 8 g of phosphorus oxychloride, 100 g of bisphenol A epoxy resin and 10 g of triethylbenzyl ammonium bromide in 120 g of ethyl acetate, and then heat and reflux at 100 ° C for 4 hours to obtain a mixed system 1;
[0053] Add 15g of polytetrahydrofuran diol and 1.5g of 2-methyl-1,3-propanediol to the mixed system 1, and then react at 70°C for 3h to obtain the mixed system 2;
[0054] Add 18g of isocyanate, 5g of aluminum nitride whiskers (80nm in diameter, 8μm in length), 0.5g of 2-methyl-1,3-propanediol, 3g of ammonium lauryl sulfate and 30g of ethyl acetate into the mixed system 2, After reacting at 80° C. for 4 hours, 12 g of 1,14-tetradecanediamine was added and cured to obtain a flame-retardant composite resin.
[0055] (2) Preparation of automotive interior parts: put spandex fabric and flame-retardant composite resin in the mold, under the conditions of clamping force 750T, injection pressure 4bar, pressure switching 4...
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