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Slow-release long-acting fishing net antifouling coating

An antifouling coating and slow-release technology, applied in antifouling/underwater coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve the problems of affecting the performance of fishing nets, difficult to promote and use, and poor practicability, etc., to achieve Effects of improving thixotropy and adhesion, improving strength and surface finish, and enhancing stain resistance

Inactive Publication Date: 2018-12-07
CHAOHU XIANGYU FISHING GEAR
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the process of fishery development, fishing nets are an indispensable part of fishery production. Among them, fishing nets produced by traditional knotting methods have been widely used in fishery fishing. Fishing nets usually produced by knotting methods include pull nets, sticky nets and other types of fishing nets. After the fishing net is used, it is easy to attach a large amount of dirt to its surface, which affects the performance of the fishing net. Although many cleaning devices have been developed, it is difficult to popularize them due to poor practicability. In order to improve this situation, the raw material polyethylene is usually added. The surface is coated with antifouling coatings to improve its antifouling performance and mechanical strength. The existing antifouling coatings are usually self-polishing antifouling coatings. The antifouling agent is mainly cuprous oxide, and the content of cuprous oxide can usually be It can reach about 50%. The anti-fouling effect is mainly achieved by the exudation of cuprous oxide. Copper ions will accumulate in marine organisms, and the toxicity is lower than that of tributyltin. Although the environmental protection requirements of the composite retaining wall, there are more serious human Environmental hazards. Copper-free antifouling coatings have been studied as a new hot spot. Although the existing antifouling coatings avoid the use of metal raw materials, their antifouling effects need to be further improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A slow-release and long-acting antifouling coating for fishing nets, comprising the following raw materials in parts by weight: 62 parts of mixed resin, 180 parts of slow-release antifouling agent, 4 parts of medium-chain fatty acid triglycerides, 14 parts of nano-calcium carbonate, γ-ammonia 2 parts of propyltriethoxysilane, 1.2 parts of nitrogenous organic base, 0.4 parts of lignocellulose;

[0017] The preparation method of the slow-release antifouling agent is: by weight, 1.5 parts of guanidine nitrate, 5 parts of carbon nanotube-metakaolin base polymer, 1.5 parts of thiabendazole, 0.5 parts of umbrella-shaped siloxane dispersant, Mix 0.65 parts of hydroxycarboxylic acid aqueous solution with a mass concentration of 2.5 mol / L and 65 parts of cyclodextrin, stir and react at a temperature of 650°C for 25 minutes, and then stand at a temperature of 12°C for 2.5 hours, namely have to;

[0018] The preparation method of the carbon nanotube-metakaolin base polymer is as ...

Embodiment 2

[0023] A slow-release and long-acting antifouling coating for fishing nets, comprising the following raw materials in parts by weight: 60 parts of mixed resin, 20 parts of slow-release antifouling agent, 3 parts of medium-chain fatty acid triglycerides, 16 parts of nano calcium carbonate, γ-ammonia 1 part of propyltriethoxysilane, 1.6 parts of nitrogen-containing organic base, 0.2 part of lignocellulose;

[0024] The preparation method of the slow-release antifouling agent is: by weight, 2 parts of guanidine nitrate, 4 parts of carbon nanotube-metakaolin base polymer, 2 parts of thiabendazole, 0.8 parts of umbrella-shaped siloxane dispersant, Mix 0.5 parts of hydroxycarboxylic acid aqueous solution with a mass concentration of 2.8 mol / L and 70 parts of cyclodextrin, stir and react at a temperature of 60°C for 20 minutes, and then stand at a temperature of 15°C for 3 hours, that is have to;

[0025] The preparation method of the carbon nanotube-metakaolin base polymer is as fo...

Embodiment 3

[0030] A slow-release and long-lasting antifouling coating for fishing nets, comprising the following raw materials in parts by weight: 65 parts of mixed resin, 16 parts of slow-release antifouling agent, 5 parts of medium-chain fatty acid triglycerides, 12 parts of nano-calcium carbonate, γ-ammonia 3 parts of propyltriethoxysilane, 0.8 part of nitrogen-containing organic base, 0.6 part of lignocellulose;

[0031] The preparation method of the slow-release antifouling agent is: by weight, 1 part of guanidine nitrate, 6 parts of carbon nanotube-metakaolin base polymer, 1 part of thiabendazole, 0.2 part of umbrella-shaped siloxane dispersant, Mix 0.8 parts of hydroxycarboxylic acid aqueous solution with a mass concentration of 2.2 mol / L and 60 parts of cyclodextrin, stir and react at a temperature of 70°C for 30 minutes, and then stand at a temperature of 10°C for 2 hours, that is have to;

[0032] The preparation method of the carbon nanotube-metakaolin base polymer is as foll...

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Abstract

The invention belongs to the technical field of antifouling coatings for fishing nets, and particularly relates to a slow-release long-acting fishing net antifouling coating comprising the following raw materials by weight: 60-65 parts of mixed resin, 16-20 parts of a slow-release antifouling agent, 3-5 parts of medium chain fatty acid triglyceride, 12-16 parts of nano calcium carbonate, 1-3 partsof gamma-aminopropyltriethoxysilane, 0.8-1.6 parts of a nitrogen-containing organic base, and 0.2-0.6 part of lignocellulose. The surface energy of a coating film of the antifouling coating is less than 20 mJ / m<2>, the coating film of the antifouling coating has a large contact angle with seawater to play an antifouling effect, wherein thiabendazole can increase the antibacterial property of a slow-release antifouling agent, cyclodextrin can prolong the action time, by rational proportioning of raw materials of the antifouling coating, the slow-release long-acting fishing net antifouling coating can effectively adhere to the surface of a fishing net to form a structurally-stable film layer which is not affected by seawater temperature and impact, the anti-corrosion and anti-fouling effectof the fishing net can be improved, meanwhile use of a copper-containing antifouling agent is avoided, and the slow-release long-acting fishing net antifouling coating is suitable for promotion.

Description

technical field [0001] The invention belongs to the technical field of antifouling coatings for fishing nets, in particular to a slow-release and long-acting antifouling coating for fishing nets. Background technique [0002] In the process of fishery development, fishing nets are an indispensable part of fishery production. Among them, fishing nets produced by traditional knotting methods have been widely used in fishery fishing. Usually, fishing nets produced by knotting methods include pull nets, sticky nets and other types of fishing nets. After the fishing net is used, it is easy to attach a large amount of dirt to its surface, which will affect the performance of the fishing net. Although many cleaning devices have been developed, they are difficult to popularize due to poor practicability. In order to improve this situation, the raw material polyethylene is usually added. The surface is coated with antifouling coatings to improve its antifouling performance and mechan...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D163/10C09D5/16C09D7/61C09D7/63C09D7/65
CPCC08K2003/265C08K2201/011C08L2205/035C09D5/14C09D5/1625C09D5/1662C09D5/1687C09D175/04C08L63/10C08L97/02C08K13/02C08K3/26C08K3/041C08K3/346C08K5/31C08K5/46
Inventor 胡文龙
Owner CHAOHU XIANGYU FISHING GEAR
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