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Low-temperature curing backside silver paste for all-aluminum backfield crystalline silicon solar cells

A solar cell and all-aluminum back field technology, which is applied in circuits, electrical components, photovoltaic power generation, etc., can solve the problems of battery open-circuit voltage reduction, short-circuit current reduction, and low density of aluminum paste on the back, so as to improve open-circuit voltage and short-circuit current, improve electrical conductivity and adhesion, and improve photoelectric conversion efficiency

Active Publication Date: 2020-05-19
JIANGSU ZHENGNENG ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] On the other hand, for the conventional battery structure using common back silver paste, due to the low density of the back aluminum paste, the back silver paste cannot be effectively attached to it, so the back silver paste is directly printed on the silicon substrate, resulting in the back silver electrode area There is no aluminum back field, which becomes a non-combination area, which reduces the collection rate of the battery for minority carriers, reduces the open circuit voltage and short circuit current of the battery, and ultimately leads to a decrease in the photoelectric conversion efficiency of the battery

Method used

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  • Low-temperature curing backside silver paste for all-aluminum backfield crystalline silicon solar cells

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Weigh 10 parts of spherical silver powder with particle diameter D50 of 0.8 μm, 60 parts of flake silver powder with D50 of 4.0 μm, 20 parts of bisphenol A epoxy resin E51, reactive diluent butanediol diglycidyl ether 8.3 parts by mass. Parts, 1.18 parts of curing agent dicyandiamide, 0.02 parts of curing accelerator 2-methylimidazole, 0.5 parts of thixotropic additive fumed silica, put the above materials into a planetary mixer with rotation and revolution functions in turn and mix After uniformity, transfer the uniformly mixed material to a three-roll mill for grinding and dispersion according to a certain process to obtain a slurry with a fine and uniform appearance without coarse particles. After testing, the fineness is <10μm and the viscosity is 46Pa.S. After being further filtered through a 200-mesh screen, it was packaged and stored at -5°C for future use.

[0031] In the crystalline silicon solar cell production line, the standard raw material single crystal ba...

Embodiment 2

[0035] Take by weight D50 and be 20 parts of spherical silver powder of 2.0 μ m, D50 be 60 parts of flaky silver powder of 2.8 μ m, 14 parts of bisphenol A type epoxy resin E51, 5 parts of reactive diluent phenyl glycidyl ether, 0.77 parts of curing agent dicyandiamide, 0.03 parts of curing accelerator 2-ethyl-4-methylimidazole, 0.2 parts of thixotropic additive polyamide wax, put the above materials into a planetary mixer with rotation and revolution functions in turn After mixing evenly, transfer the evenly mixed material to a three-roll mill for grinding and dispersing according to a certain process to obtain a slurry with a fine and uniform appearance without coarse particles. After testing, the fineness is <12μm and the viscosity is 34Pa.S. After being further filtered through a 200-mesh screen, it was packaged and stored at -5°C for future use.

[0036]The above paste was made according to the process flow described in Example 1, wherein the silver paste on the back was ...

Embodiment 3

[0039] Weigh 15 parts of commercially available spherical silver powder with particle diameter D50 of 1.2 μm, 50 parts of flake silver powder with D50 of 3.2 μm, 25 parts of bisphenol A epoxy resin E44, and reactive diluent cresyl glycidyl ether 8.5 parts by mass. Parts, 1.16 parts of curing agent dicyandiamide, 0.04 parts of curing accelerator 2-phenylimidazole, 0.3 parts of thixotropic additive hydrogenated castor oil, put the above materials into a planetary mixer with rotation and revolution functions and mix evenly Finally, the uniformly mixed material is transferred to a three-roll mill for grinding and dispersion according to a certain process, and a slurry with a fine and uniform appearance without coarse particles is obtained. After testing, the fineness is <8μm and the viscosity is 49Pa.S. After being further filtered through a 200-mesh screen, it was packaged and stored at -5°C for subsequent use.

[0040] The above paste was followed by the process described in Exa...

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Abstract

The invention discloses a low-temperature curing type back sliver paste for an all-aluminum backfield crystalline silicon solar cell. The low-temperature curing type back sliver paste is composed of the following components in parts by weight: 10-20 parts of spherical silver powder, 50-60 parts of flake silver powder, 14-30 parts of bisphenol-A epoxy resin, 5-9.6 parts of active diluents, 0.77-1.18 parts of curing agent dicyandiamide, 0.02-0.04 parts of curing accelerator, and 0.2- 0.5 parts of thixotropic agent. The invention further discloses a preparation method of the silver paste and a process of manufacturing a crystalline silicon solar cell by adopting the preparation method. The crystalline silicon solar cell prepared according to the back sliver paste provided by the invention andthe manufacturing process has high photoelectric conversion efficiency, the photoelectric conversion efficiency of the crystalline silicon solar cell has about 0.4 percent of absolute value promotioncompared with a cell prepared by using the conventional slurry and preparation process, and the welding adhesion of the crystalline silicon solar cell fully meets the usage requirements for the welding adhesion of a cell panel at present.

Description

technical field [0001] The invention relates to the field of conductive silver paste for solar cells, in particular to a low-temperature curing back silver paste for all-aluminum back field crystal silicon solar cells, a preparation method and application thereof. Background technique [0002] With the excessive exploitation and consumption of fossil energy such as oil, coal, and natural gas, the energy crisis and environmental pollution caused by the greenhouse effect are becoming more and more serious, forcing human beings to seek alternative new clean energy sources. For a long time in the future, the sun will become an effective provider of clean energy for human beings. Solar power generation directly converts solar radiation into electrical energy, which is the most direct way to convert solar energy with the fewest conversion links among all clean energy sources. [0003] At present, the main solar cells are crystalline silicon solar cells, and considering the maturi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B1/22H01B13/00H01L31/0224
CPCH01B1/22H01B13/00H01L31/022441Y02E10/50
Inventor 闵玉勤张群冷青松耿心彤杨全荣
Owner JIANGSU ZHENGNENG ELECTRONICS TECH CO LTD