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High-toughness epoxy resin grouting material for rapid repair of concrete structure joint

A concrete structure, epoxy resin technology, applied in the direction of epoxy resin glue, adhesive type, adhesive, etc., can solve the problems of high viscosity of liquid nitrile rubber, affecting material properties, degumming, etc., to achieve good wet bond strength , Long working time and good stability

Inactive Publication Date: 2020-03-24
BEIJING MUNICIPAL ENG RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the extremely short curing period is achieved by gradually accumulating heat through gradual polymerization to promote the addition polymerization reaction. The fast reactivity of the epoxy adhesive in this system is significantly affected by temperature. When the temperature is low and the gradual polymerization speed slows down, the hardening time of the material will decrease. Significantly extended, it is difficult to meet the requirements of uninterrupted traffic repair and reinforcement of plate girder hinge joints
Moreover, the epoxy adhesive is only toughened by introducing liquid fixation rubber, and the toughening effect is limited. The liquid nitrile rubber itself has a high viscosity, so it should not be mixed too much. The material is prone to degumming under long-term complex fatigue loads. question
At the same time, non-active diluents are used in the viscosity reduction measures, which are prone to problems such as precipitation under long-term loading, which will affect the performance of the material
In addition, thixotropy reduces the fluidity of polyurethane adhesives. When pouring glue into joints, the material poured in the front will gather, thixotropy, and flow will slow down. The gradual reaction speed will increase rapidly, and the materials will harden in a very short time, resulting in seams Blockage of the inner flow channel, which prevents full perfusion, especially in summer when the temperature is high

Method used

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  • High-toughness epoxy resin grouting material for rapid repair of concrete structure joint
  • High-toughness epoxy resin grouting material for rapid repair of concrete structure joint

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Component A:

[0026] 10 parts of bisphenol A type epoxy resin, 10 parts of hydrogenated bisphenol A type epoxy resin, 10 parts of bisphenol F type epoxy resin, 10 parts of aliphatic glycidyl ethers, 5 parts of diglycidyl adipate, 2 parts of diglycidyl phthalate, 3 parts of diglycidyl terephthalate, 4 parts of polyurethane modified epoxy resin, 5 parts of silicone modified epoxy resin, 1 part of nitrile rubber modified epoxy resin 10 parts, 10 parts of epoxy-terminated liquid nitrile rubber, 10 parts of aliphatic glycidyl ether;

[0027] Component B:

[0028] 10 parts of modified alicyclic amine, 10 parts of modified fatty amine, 5 parts of polymercaptan, 1 part of tertiary amine accelerator, 5 parts of amino-terminated liquid nitrile rubber, 5 parts of silicone defoamer, 1 part of fungicide 2 parts, 2 parts of antioxidant, 2 parts of heat stabilizer.

[0029] The volume ratio of A and B components is 1:0.4.

Embodiment 2

[0031] Component A:

[0032] 20 parts of bisphenol A type epoxy resin, 20 parts of hydrogenated bisphenol A type epoxy resin, 20 parts of bisphenol F type epoxy resin, 20 parts of aliphatic glycidyl ethers, 10 parts of diglycidyl adipate, 10 parts of diglycidyl phthalate, 10 parts of diglycidyl terephthalate, 30 parts of polyurethane modified epoxy resin, 30 parts of silicone modified epoxy resin, 10 parts of nitrile rubber modified epoxy resin 30 parts, 30 parts of epoxy-terminated liquid nitrile rubber, 40 parts of aliphatic glycidyl ether;

[0033] Component B:

[0034] 60 parts of modified alicyclic amine, 60 parts of modified fatty amine, 15 parts of polymercaptan, 5 parts of tertiary amine accelerator, 25 parts of amino-terminated liquid nitrile rubber, 15 parts of silicone defoamer, 5 parts of antifungal agent 5 parts, 5 parts of antioxidant, 5 parts of heat stabilizer.

[0035] The volume ratio of A and B components is 1:1.

Embodiment 3

[0037] 60 parts of bisphenol F-type epoxy resin, 20 parts of diglycidyl adipate, 40 parts of polyurethane modified epoxy resin, 20 parts of epoxy-terminated liquid nitrile rubber, and 25 parts of aliphatic glycidyl ether;

[0038] Component B:

[0039] 70 parts of modified alicyclic amine, 10 parts of polythiol, 3 parts of tertiary amine accelerator, 15 parts of amino-terminated liquid nitrile rubber, 10 parts of silicone defoamer, and 10 parts of heat stabilizer.

[0040] The volume ratio of A and B components is 1:0.7.

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Abstract

The invention relates to a high-toughness epoxy resin grouting material for rapid repair of a concrete structure joint. The high-toughness epoxy resin grouting material is composed of the following raw materials: a component A and a component B, wherein the component A comprises: glycidyl ether epoxy resin, glycidyl ether epoxy resin, softened modified epoxy resin, epoxy-terminated liquid nitrilebutadiene rubber and a reactive diluent; and the component B comprises: a modified amine curing agent, polymercaptan, a tertiary amine accelerator, amino-terminated liquid nitrile butadiene rubber, anorganic silicon defoamer and an anti-aging agent, and the mass ratio of the component A to the component B is 1:0.2-1. The epoxy resin grouting material has low viscosity, is convenient for groutingconstruction, has good applicability to a humid basal plane, and has fast hardening speed, high early mechanical strength and bonding strength, excellent flexibility, and excellent damp-heat aging resistance and fatigue resistance, and can achieve rapid repair and reinforcement on a concrete structure joint without affecting normal traffic.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to a high-toughness epoxy resin grouting material used for rapid repair of concrete structure joints. Background technique [0002] Plate girders have the advantages of simple structure, quick installation, and low cost, so they are widely used in small-span bridges in my country. For the simply supported hinged plate girder structure, the hinge joint is the medium to realize the lateral connection between the plate girders. Once the hinge joint is damaged, the lateral distribution of the bridge and the overall mechanical performance will be seriously affected, resulting in excessive deflection of the plate girder, Cracking of the bottom of the slab and damage to the pavement of the bridge deck; in addition, the seepage of rainwater will cause corrosion of steel bars in the slab girder, corrosion of concrete, and reduction of strength, which pose serious hidden dangers ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J109/02C08G59/50C08G59/56C08G59/66
CPCC08G59/5006C08G59/5026C08G59/56C08G59/66C08L2201/08C08L2205/025C08L2205/035C09J163/00C08L63/00C08L9/02
Inventor 姚嘉靳昊易忠来李化建黄发礼王振谢永江温浩温家馨刘澈刘铭轩王光明陶水忠汤博洋司金艳王丽萍王灏董建
Owner BEIJING MUNICIPAL ENG RES INST
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