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A kind of preparation method of environment-friendly bamboo charcoal board for decoration

A bamboo charcoal, environmentally friendly technology, applied in applications, home appliances, flat products, etc., can solve the problems of uneven density of bamboo charcoal boards, high cost of bamboo charcoal boards, uneven dispersion of bamboo charcoal powder, etc., to improve tensile strength and elastic modulus. , High production efficiency and uniform performance

Active Publication Date: 2021-12-07
湖南竹海炭生源生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] What the present invention proposes is a kind of preparation method of environment-friendly bamboo charcoal board for decoration, and its purpose is to solve the problems such as high cost of existing bamboo charcoal board, uneven dispersion of bamboo charcoal powder in resin and lead to uneven density of bamboo charcoal board, etc., proposes a A kind of preparation method of decorative bamboo charcoal board, with biomass nanocellulose as dispersant and stabilizer, bamboo charcoal powder is uniformly dispersed in aqueous solution, forms dispersed and stable bamboo charcoal powder / nanometer cellulose suspension, forms after freeze-drying Sheet-shaped bamboo charcoal powder airgel, then impregnated the airgel with phenolic resin, dried at low temperature and hot-pressed into bamboo charcoal sheet

Method used

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Examples

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preparation example Construction

[0020] A kind of preparation method of environment-friendly bamboo charcoal board for decoration, specifically comprises the following steps:

[0021] (1) The prepared or purchased bamboo charcoal has a moisture content of 10% to 14%, a fixed carbon content of 85% to 88%, an ash content of 2% to 4%, and a specific surface area of ​​300 to 600m 2 / g; volatile matter 6%~8%; air-dry density ≥ 0.800g / cm3. Then the bamboo charcoal is crushed into 300-1000-mesh bamboo charcoal powder (with a particle size within the range of 10-50 μm).

[0022] (2) Using biomass nanocellulose as a dispersant, the diameter of the nanocellulose is between 10 and 100, and dissolving the nanocellulose in deionized water to form a nanocellulose solution of a certain concentration;

[0023] Using 80-100 mesh bamboo powder as raw material, use 15-25% chlorous acid solution and sodium hydroxide solution to remove lignin and hemicellulose, then use TEMPO oxidation method to weigh 0.01g TEMPO and 0.1g NaBr s...

Embodiment 1

[0030] According to the water content of 10%, the fixed carbon content is 85% to 88%, the ash content is 2% to 4%, and the specific surface area is 400m 2 / g, volatile matter 6% to 8%; if the air-dry density is 0.800g / cm3, it is required to purchase bamboo charcoal, then dry the bamboo charcoal until it is absolutely dry, and then crush it into 500-mesh bamboo charcoal powder.

[0031] Using 100 mesh bamboo powder as raw material, use 25% chlorous acid solution and sodium hydroxide solution to remove lignin and hemicellulose, then use TEMPO oxidation method to weigh 0.01g TEMPO and 0.1gNaBr to dissolve in 100mL deionized Add 1g of α-cellulose to the water and continue to stir until it is completely dissolved, then slowly drop in 8mmol of sodium hypochlorite, and adjust the pH to about 10 with dilute hydrochloric acid and NaOH solution respectively, add 5ml of absolute ethanol to terminate the reaction after 4 hours of reaction, and use Wash with ionic water until neutral. Tak...

Embodiment 2

[0036] According to the moisture content of 10%, the fixed carbon content is 85% to 88%, the ash content is 2% to 4%, and the specific surface area is 500m 2 / g, volatile matter 6% to 8%; if the air-dry density is 0.80g / cm3, it is required to purchase bamboo charcoal, then dry the bamboo charcoal until it is absolutely dry, and then crush it into 800-mesh bamboo charcoal powder.

[0037] Using 100 mesh bamboo powder as raw material, use 25% chlorous acid solution and sodium hydroxide solution to remove lignin and hemicellulose, then use TEMPO oxidation method to weigh 0.01g TEMPO and 0.1gNaBr to dissolve in 100mL deionized Add 1g of α-cellulose to the water and continue to stir until it is completely dissolved, then slowly drop in 8mmol of sodium hypochlorite, and adjust the pH to about 10 with dilute hydrochloric acid and NaOH solution respectively, add 5ml of absolute ethanol to terminate the reaction after 4 hours of reaction, and use Wash with ionic water until neutral. T...

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Abstract

The invention relates to a preparation method of an environmentally friendly bamboo charcoal board for decoration. Biomass nano-cellulose is used as a dispersant, and bamboo charcoal powder is uniformly dispersed in an aqueous solution to form a uniformly dispersed and stable bamboo charcoal powder / nano-cellulose mixed solution, which is freeze-dried Then, the bamboo charcoal powder block material is formed, and the bamboo charcoal powder block material is pulverized into granules, and then impregnated with phenolic resin, dried at low temperature, and hot-pressed into bamboo charcoal plates of different densities. The bamboo charcoal board produced by this method has the characteristics of uniform density and stable mechanical properties. The addition of nanocellulose can improve the flexural strength and elastic modulus of bamboo charcoal board, and solve the problems of high brittleness and unsatisfactory mechanical properties of bamboo charcoal board. At the same time, the raw materials used in the present invention are simple in composition, and the used biomass nanocellulose can be completely degraded, thereby truly achieving the purpose of environmental protection. Moreover, the production equipment of the present invention can be produced by using a conventional multi-layer wood-based panel hot press, and has the characteristics of high production efficiency and large output.

Description

technical field [0001] The invention relates to a method for preparing an environment-friendly bamboo charcoal board for decoration, and belongs to the technical field of bamboo wood-based board processing. Background technique [0002] At present, wood / bamboo wood-based panels are mainly used for construction and interior decoration, which are made by passing wood / bamboo unit materials through phenolic / urea-formaldehyde resins or other resins under high temperature / high pressure loads. The prepared panels have natural The texture of wood or bamboo has certain aesthetics while satisfying the strength. However, the dimensional stability of this type of board is not ideal, especially when it is used as an outdoor building decoration material, it is prone to deformation, cracking, mildew, decay, discoloration and other problems during the continuous exposure to sunlight and soaking in rain. [0003] Bamboo charcoal is a carbon material formed by pyrolysis of bamboo at high tem...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B27N3/02B27N3/08B27N3/18
CPCB27N3/02B27N3/08B27N3/18
Inventor 郝明亮黄超
Owner 湖南竹海炭生源生物科技有限公司