Three-dimensional patterned porous graphene black body and preparation method and application thereof

A porous graphene, three-dimensional pattern technology, applied in graphene, chemical instruments and methods, carbon compounds, etc., can solve the problem of blackbody-like nano-micro structure that cannot form three-dimensional three-dimensional, difficult to achieve laser nano-micro structure fine processing, polymerization. The price of imide materials is high, and the effect of enhancing absorption and light-thermal conversion utilization, convenient storage and transportation, and no catalyst is required.

Active Publication Date: 2022-01-14
SHANGHAI INST OF OPTICS & FINE MECHANICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this patent has the following disadvantages: 1) the price of polyimide material is high and the variety is single; 2) it is difficult to realize the fine processing of the nano-microstructure of the material by laser, and it is impossible to form a three-dimensional black body-like nano-microstructure
At present, this technology mainly relies on nanomaterials that are relatively expensive and have complex preparation processes. Therefore, nanomaterials that are cheap and easy to obtain, have excellent light absorption properties, and a well-developed pore structure, and their low-cost and high-efficiency preparation methods are an inevitable demand.

Method used

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  • Three-dimensional patterned porous graphene black body and preparation method and application thereof
  • Three-dimensional patterned porous graphene black body and preparation method and application thereof
  • Three-dimensional patterned porous graphene black body and preparation method and application thereof

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Embodiment 1

[0039] The commercial lasers used in the present invention can be nanosecond lasers, picosecond lasers, femtosecond lasers, etc., carbon materials include but are not limited to shaped biomass porous carbon, carbon sponge, foam, gel, film, etc., wherein the biomass is porous Carbon is a carbon material prepared from biomass, such as plant stalks, fruit shells, etc., including but not limited to porous carbon, mesoporous carbon, coal, and activated carbon.

[0040] A method for preparing a three-dimensional patterned porous graphene-like black body prepared by a short-pulse laser-induced processing method, the specific steps are as follows:

[0041] (1) Using laser processing technology to induce porous graphene-like black bodies: process the formed carbon material into a disc shape with a diameter of 30 mm, and then use a fixing device to fix it on the substrate. The fixing device here includes but is not limited to tape, Clamping tooling, etc.; flat substrates include but are...

Embodiment 2

[0045] Such as Figure 6 As shown, the application of a hydrophilic porous graphene-like black body prepared by laser processing method in seawater desalination, specifically, a container with a dome with a diameter of 8 cm is used as a fresh water collection device; the hydrophilic fiber Cloth and other hydrophilic materials are coated on the surface of cylindrical heat-insulating foam, and placed in a circular plastic beaker with a diameter of 5 cm that is filled with water to be treated; the hydrophilic porous graphene-like blackbody material prepared by the present invention is processed into a diameter 5 cm round, making it in decryption contact with the hydrophilic fiber cloth; under the sunlight, the porous graphene-like black body absorbs light and converts the light into heat to heat and evaporate the water absorbed by the hydrophilic fiber cloth at the bottom, separating Thermal foam plays the role of heat management, so as to realize seawater desalination, sewage tr...

Embodiment 3

[0048] Such as Figure 7 As shown, the application of a three-dimensional patterned porous graphene-like black body prepared by short-pulse laser processing method in photothermal catalysis and photoelectrocatalytic degradation of organic matter, specifically, a laser-induced three-dimensional pattern with a size of 1*1 cm The graphene-like black body material is used as the working electrode and placed in a circular plastic beaker with a diameter of 5 cm to be treated with organic wastewater; a two-electrode system is used, with graphite as the counter electrode, and the light is enhanced to electrochemically catalyze the degradation of organic matter.

[0049] The principle of the invention is to use laser to induce graphitization transformation of carbon materials, and induce the formation of graphene-like black bodies under laser irradiation. During the whole process, part of the carbon is gasified to form a large number of porous structures. The graphene-like black body w...

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Abstract

The invention discloses a short-pulse or ultra-short-pulse laser direct gasification method. The construction of a three-dimensional patterned multilevel structure of a carbonaceous material is realized, and a carbonaceous black-body-like material is prepared and applied to the fields of wide-spectrum light absorption, super-capacitors, nano-catalysis and the like. The invention relates to the technical field of solar energy or spectral absorption and utilization, battery energy, environmental management and the like. The carbonaceous material mainly comprises formed biomass carbon, carbonaceous sponge, gel, a film and the like. According to the patterned and three-dimensional structure, the surface of the carbonaceous material can be locally machined in a short-pulse laser nanometer gasification mode according to the design requirement, local direct gasification of the carbonaceous material is achieved, and meanwhile, amorphous carbon is converted into a black-body-like graphene structure with a three-dimensional shape. According to the invention, the amorphous carbonaceous material can realize crystal transformation, the amorphous carbonaceous material has the characteristics of high conductivity, high surface roughness, strong optical absorption, high specific surface area and the like, and the spectral absorption and transformation capability and the energy utilization efficiency can be remarkably improved.

Description

technical field [0001] The invention belongs to the technical field of material preparation, and in particular relates to a three-dimensional patterned porous graphene-like black body prepared by a short-pulse laser processing method, a preparation method and an application thereof. Background technique [0002] Graphene is a new type of two-dimensional layered material composed of single-layer carbon atom lattice arrangement. New materials, especially three-dimensional graphene-like blackbody materials, have broad application prospects in many fields such as optoelectronics, composite materials, energy storage, energy capture, thermal management, and catalysis. [0003] So far, various graphene preparation methods such as mechanical exfoliation, ultrasonic exfoliation, chemical synthesis, chemical vapor deposition, and graphite oxide reduction have been developed. However, these preparation methods can only produce graphene with a small size. , it is impossible to obtain p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/184C01B32/194
CPCC01B32/184C01B32/194Y02P20/133
Inventor 吴卫平刘丰华顾云娇王瓒胡一谷
Owner SHANGHAI INST OF OPTICS & FINE MECHANICS CHINESE ACAD OF SCI
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