The invention discloses a monatomic
cobalt coordination foamy carbon catalytic material as well as a preparation method and application thereof. The material is obtained by mixing a
cobalt precursor,
melamine, a lignosulfonate precursor and a
foaming agent and carrying out hot-pressing foaming molding, segmented
carbonization and acid
pickling. The material is a three-dimensional net-shaped foamy
carbon skeleton,
cobalt is anchored in the
carbon skeleton in a monatomic form and is coordinated with
nitrogen and
sulfur atoms in the
carbon skeleton to form an S-Co-N4 site through a
covalent bond, and atomic-scale efficient
active site construction is achieved. The material has a micro-scale pore bubble structure with coexisting open pores / closed pores, and continuous
mass transfer channels and reaction sites are provided. Pollutants and peroxymonosulfate are enriched on a mesoscale interface of a pore channel and react with monatomic sites, so that generation of active species and degradation of the pollutants are promoted. On the
macroscopic scale, the material serves as a recoverable photo-thermal
catalysis unit, the photo-thermal coupled Fenton-like process is achieved under the illumination condition, and the material is suitable for deep treatment of new pollutants in a
water body.