The invention belongs to the technical field of catalytic energy conversion, and particularly relates to a three-dimensional self-supporting multi-element
transition metal catalyst as well as a preparation method and application thereof. According to the catalyst, a
chemical plating method is adopted for in-situ deposition of a catalytic layer on a porous net-shaped foam
sponge substrate, and surface treatment technologies such as
acid etching and dipping modification are combined for optimization and modification, so that the catalyst is obtained; the preparation method specifically comprises the following steps: taking Co as a basic
metal,
doping transition metal X, and recording as Co-X; and modifying with one or two of a small amount of
platinum metals. The preparation cost and the
catalytic efficiency of the catalyst are both considered, element reactions of all steps in the catalytic process are effectively promoted through the synergistic effect of multiple elements, excellent intrinsic catalytic activity and stability are shown, efficient
hydrogen production through hydroboron
hydrolysis can be achieved, and the method is suitable for industrial production. For example, the controller can be used as a
hydrogen production starting controller in a
sodium borohydride aqueous medium hydrogen fuel
cell, realizes the supply of hydrogen anytime and anywhere, and has a wide application prospect.