The invention discloses an acrylic vacuum coating paint and a coating process thereof. The acrylic vacuum coating paint comprises a vacuum coating primer and a vacuum coating finish paint. The vacuum coating primer comprises high-hydroxyl-value low-viscosity acrylic resin, multi-element thixotropic hydroxyl-containing acrylic resin, a diluent, an adhesion promoter, a leveling agent, a drier, an oily nano color concentrate and an aliphatic or alicyclic polyisocyanate curing agent. The vacuum coating finish paint comprises low-hydroxyl-value acrylic resin, a diluent, an adhesion promoter, a leveling agent, an antifoaming agent, an ultraviolet absorber, a drier, an oily nano color concentrate and an aliphatic or alicyclic polyisocyanate curing agent. The acrylic vacuum coating paint has the advantages of high weather resistance, favorable acid/alkali resistance, favorable water resistance, favorable sag resistance, excellent mirror surface effect and favorable stability, has excellent decorative and protective actions on acrylic, and can satisfy the requirements for acrylic vacuum coating products in outdoor, bathroom and other places.