Magnesia partly stabilized zircite floamed ceramic filter

A technology for stabilizing zirconia and foamed ceramics, applied in filtration and separation, ceramic products, chemical instruments and methods, etc., can solve the problems of large sintering shrinkage, low product strength, low bulk density, etc. Production time, effect of uniform microstructure

Inactive Publication Date: 2009-07-22
WUXI ZHUOXIN CERAMIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the preparation technology of zirconia-based foam ceramics has the following two difficulties: first, during the firing process of zirconia products, due to the martensitic phase transformation and the particularity of the foam ceramic structure, the blanking method is to use ceramic The slurry is formed by coating and hanging on the three-dimensional network foam plastic, and the bulk density of the powder is low. Compared with the pressure-formed zirconia ceramics, the sintering mass transfer process and solid solution reaction have other characteristics, and the sintering shrinkage is larger, so the part is stable. It is very difficult to develop zirconia foam ceramics, ...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] will have been cut into 150×2.5mm polyurethane foam with pore diameter of 10PPI is immersed in sodium hydroxide aqueous solution with a mass concentration of 20% and a temperature of 40°C for 2 hours, then the polyurethane foam is taken out, rinsed repeatedly with clean water, and placed in Dry in an oven at 80°C for 24 hours. Dissolve 6 grams of polyvinyl butyral in 200 grams of absolute ethanol, then add 40 grams of magnesium oxide with an average particle diameter of 1 micron, and 960 grams of fused zirconia with an average particle diameter of 40 microns, and mix in a ball mill into slurry. Dip the dried polyurethane foam into the ethanol slurry of magnesia-zirconia, then squeeze the excess slurry out of the polyurethane foam on a squeezer, and then dry the polyurethane foam naturally in the air. Afterwards, the polyurethane foam whose surface has been covered with a dry ceramic layer is immersed in the ethanol slurry of magnesium oxide-zirconia for the second ti...

Embodiment 2

[0016] will have been cut into The polyurethane foam with a pore size of 10PPI is immersed in a sodium hydroxide aqueous solution with a mass concentration of 15% and a temperature of 50°C for 3 hours, then the polyurethane foam is taken out, rinsed repeatedly with clean water, and placed in a refrigerator with a temperature of 80°C. Dry in the oven for 24 hours. Dissolve 8 grams of polyvinyl butyral in 200 grams of absolute ethanol, then add 70 grams of magnesium oxide with an average particle diameter of 1 micron, and 930 grams of fused zirconia with an average particle diameter of 40 microns, and mix in a ball mill into slurry. Dip the dried polyurethane foam into the ethanol slurry of magnesia-zirconia, then squeeze the excess slurry out of the polyurethane foam on a squeezer, and then dry the polyurethane foam naturally in the air. Afterwards, the polyurethane foam whose surface has been covered with a dry ceramic layer is immersed in the ethanol slurry of magnesium ox...

Embodiment 3

[0018] will have been cut into 150×2.5mm polyurethane foam with a pore size of 10PPI is immersed in an aqueous sodium hydroxide solution with a mass concentration of 10% and a temperature of 60°C for 4 hours, then the polyurethane foam is taken out, rinsed repeatedly with clean water, and placed in Dry in an oven at 80°C for 24 hours. Dissolve 10 grams of polyvinyl butyral in 200 grams of absolute ethanol, then add 100 grams of magnesium oxide with an average particle diameter of 1 micron, and 900 grams of chemical zirconia with an average particle diameter of 40 microns, and mix them in a ball mill to form slurry. Dip the dried polyurethane foam into the ethanol slurry of magnesia-zirconia, then squeeze the excess slurry out of the polyurethane foam on a squeezer, and then dry the polyurethane foam naturally in the air. Afterwards, the polyurethane foam whose surface has been covered with a dry ceramic layer is immersed in the ethanol slurry of magnesium oxide-zirconia for...

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PUM

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Abstract

The invention belongs to a ceramic foam filter used in the casting industry. The invention proposes a technique which employs an organic solvent as a dispersing medium, a polymer material being capable of being dissolved into the organic solvent as a caking agent, and magnesia and monoclinic phase zirconia as the main materials to prepare a magnesia partially-stable zirconia ceramic foam filter. Absolute ethyl alcohol is preferably selected as the organic solvent for the consideration of environment protection. But the organic solvent covered by the invention also comprises the organic solvents capable of dissolving macromolecular caking agent like methanol, acetone, cyclohexanone, isobutyl alcohol, benzene, toluene, and the like. PVB is mainly selected as the macromolecular caking agent. The invention has the advantages of quick drying speed of a foamed ceramics biscuit, and saving the production time; moreover, the ceramic grains are piled compactly in the biscuit; the sintered foamed ceramic has uniform clearance and high high-temperature intensity, thus being capable of completely meeting the filtering on molten steel and high temperature alloy fused masses.

Description

technical field [0001] The invention belongs to a foam ceramic filter used in the foundry industry, in particular to a magnesia partially stabilized zirconia foam ceramic filter for filtering and purifying molten steel and superalloy melt with excellent thermal shock resistance and high temperature strength. Background technique [0002] In the production of castings, the use of foam ceramic filter metal liquid filtration technology, through three filtration and purification mechanisms of mechanical interception, rectification scum and deep adsorption, can effectively reduce or eliminate non-metallic inclusions and purify liquid alloys, thereby improving the quality of alloys. Improve the yield, improve the internal quality, working performance and machining performance of castings. [0003] For alloys with lower smelting temperature, such as copper, aluminum and magnesium, because the high temperature performance of the filter material is not high, ceramic foam filters made...

Claims

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Application Information

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IPC IPC(8): C04B35/48C04B38/00B01D39/20
Inventor 杨琪胡健倪新梅
Owner WUXI ZHUOXIN CERAMIC TECH
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