Polishing solution for sapphire substrate

A sapphire substrate and polishing liquid technology, which is applied to polishing compositions containing abrasives, etc., can solve the problem of uncontrollable surface roughness of sapphire substrate materials, scratched polishing liquid dispersion stability, and poor polishing efficiency of polishing slurry. and other problems, to achieve the effect of not polluting the environment and corroding equipment, good polishing effect and low cost

Active Publication Date: 2013-12-18
HUNAN HAOZHI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, the Chinese patent (application number 03141638.1) "Optical Sapphire Crystal Substrate Grinding Process" mainly includes rough grinding, fine grinding and polishing. Although it can effectively reduce the surface roughness of sapphire, the diamond abrasive used in it is During the polishing process, it is easy to damage the surface layer of the material, causing deep scratches and the dispersion stability of the polishing liquid is poor
Polishing sapphire with silica sol can achieve a very low surface roughness Ra<0.5 nm, but the polishing rate is too slow; such as the Chinese patent (application number 201010215841.6) "slightly alkaline sapphire polishing solution and its preparation method", the invention is Suspend nano-silica sol particles with a particle size of 3-300nm in water first, then add a complexing agent into the suspension, then add a surfactant, and finally adjust the pH value of the suspension to 7-9.5; the inventive method Simple, reasonable, easy to produce, and good product stability; the product can be diluted in a high proportion, the product has high polishing efficiency, strong stability, and is not easy to deposit on the polishing machine and the surface of the polished product. Its unique fluid properties are not suitable for sapphire after polishing. The surface is air-dried, which greatly reduces the burden of the subsequent cleaning process; however, the polishing efficiency of the polishing slurry is still not good
There is also a Chinese patent (application number 200610013968.3) "Control method for high removal rate of sapphire substrate", which discloses the method of using SiO with a particle size of 15-40nm 2 Abrasives, polishing fluid with a pH value of 11-13.5, under the polishing process conditions of 40-60°C temperature, 40-120rpm speed, 0.10-0.20MPa, 100-5000ml / min flow rate, the sapphire substrate material is processed on a polishing machine. Polishing for 0.2 to 3 hours; this method can achieve high-speed mass transfer under strong chemical action, thereby achieving high removal rate of polishing; Corrosion pits formed on the surface

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The specific preparation steps of this embodiment are as follows:

[0026] ①. Preparation of materials: Take 10g of ammonium persulfate, 30g of lithium chloride, 385g of deionized water, 25g of EDTA, and nano silicon (SiO 2 ) Sol (40-50nm, 40wt%) 4500g, ethylenediamine 50g, spare;

[0027] ②, preparation of polishing accelerator: After mixing the standby ammonium persulfate and lithium chloride, under room temperature, while stirring, add it to the standby deionized water, and after it is completely dissolved, it becomes a polishing accelerator solution. spare;

[0028] ③. Preparation of mixed aqueous solution: add the spare EDTA to the spare polishing accelerator solution to form a mixed aqueous solution for later use;

[0029] ④ Preparation of polishing solution: The mixed aqueous solution to be prepared is left to stand, cooled to room temperature (about 25°C), added to the nano-silica sol, stirred while adding, and the flow rate of the addition is controlled at 10...

Embodiment 2

[0034] The specific preparation steps of this embodiment are as follows:

[0035] ①. Preparation of materials: Take 20g of potassium iodate, 60g of tetramethylammonium hydroxide, 350g of deionized water, 25g of glycine, and nano silicon (SiO 2 ) Sol (40-50nm, 40wt%) 4500g, ethanolamine 45g, spare;

[0036] ②. Preparation of polishing accelerator: After mixing the spare potassium iodate and tetramethylammonium hydroxide, at room temperature, while stirring, add it to the spare deionized water. After it is completely dissolved, it becomes a polishing accelerator. agent solution, spare;

[0037] ③. Preparation of mixed aqueous solution: add the spare glycine to the spare polishing accelerator solution to form a mixed aqueous solution for future use;

[0038] ④ Preparation of polishing solution: The mixed aqueous solution to be prepared is left to stand, cooled to room temperature (about 25°C), added to the nano-silica sol, stirred while adding, and the flow rate of the addition...

Embodiment 3

[0043] The specific preparation steps of this embodiment are as follows:

[0044] ①. Preparation of materials: Take 15g of potassium persulfate, 45g of lithium chloride, 370g of deionized water, 25g of glycine, nano silicon (SiO 2 ) Sol (40-50nm, 40wt%) 4500g, ethanolamine 45g, spare;

[0045] ②. Polishing accelerator preparation: After mixing the spare potassium persulfate and lithium chloride, add it to the spare deionized water while stirring at room temperature. After completely dissolving, it becomes a polishing accelerator solution. spare;

[0046] ③. Preparation of mixed aqueous solution: add the spare glycine to the spare polishing accelerator solution to form a mixed aqueous solution for future use;

[0047] ④ Preparation of polishing solution: The mixed aqueous solution to be prepared is left to stand, cooled to room temperature (about 25°C), added to the nano-silica sol, stirred while adding, and the flow rate of the addition is controlled at 100 ml / min, fully sti...

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Abstract

The invention discloses a polishing solution for a sapphire substrate, and relates to the technical field of preparation of polishing materials. The polishing solution is prepared from the following active ingredients in percentage by weight: 90-95% of silica sol, 0.05-2% of polishing accelerator, 0.05-3% of complexing agent, 0.05-3% of pH regulator, and the balance of deionized water. The polishing solution has the characteristics of being high in removal rate, good in polishing effect, easy to clean, low in cost and the like, and is applicable to the polishing of sapphire substrate materials.

Description

Technical field: [0001] The invention relates to the technical field of preparation of polishing materials, in particular to a polishing liquid for sapphire substrates. Background technique: [0002] The main component of sapphire single crystal (Sapphire) is α-Al 2 o 3 , is a general term for corundum gemstones of other colors except ruby ​​in corundum gemstones, also known as white gemstones. With a Mohs hardness of 9, it is second only to diamond with a Mohs hardness of 10. Sapphire is still highly stable at high temperatures, with a melting point of 2030 °C. Sapphire has excellent dielectric properties, electrical properties, excellent optical transparency and mechanical properties, and is resistant to chemical corrosion and radiation. It can be used as infrared and microwave window systems, light-emitting diodes (LEDs), laser diodes (LDs), Parts manufacturing materials in high-tech fields such as light transmission windows for ultraviolet to near-infrared light, pre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09G1/02
Inventor 朱小华巩强
Owner HUNAN HAOZHI TECH
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