Main chain degradation type polyacrylic copper resin as well as preparation method and application thereof

A technology of copper polyacrylate, chain degradation, applied in coatings, biocide-containing paints, antifouling/underwater coatings, etc., can solve problems such as marine microplastic pollution, achieve thorough polishing, meet antifouling requirements, solve The effect of pollution

Active Publication Date: 2017-07-28
广东海巍新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main chain degradable polyacrylic acid copper resin can not only meet the static antifouling requirements of the ocean, but also solve the problem of marine microplastic pollution

Method used

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  • Main chain degradation type polyacrylic copper resin as well as preparation method and application thereof
  • Main chain degradation type polyacrylic copper resin as well as preparation method and application thereof
  • Main chain degradation type polyacrylic copper resin as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] (1) In a reaction vessel, add 64 parts by weight of methyl isobutyl ketone and 16 parts by weight of n-butanol, heat to 90°C under a nitrogen atmosphere, drop 25 parts by weight of acrylate stearate, 40 parts by weight of Parts of ethyl methacrylate, 15 parts by weight of 2-methylene-5-phenyl-1,3-dioxetane, 20 parts by weight of acrylic acid, 4 parts by weight of di-tert-butyl peroxide and 2 parts by weight of tetra (3-mercaptopropionic acid) mixture of quaternothritol esters, after the dropwise addition, was incubated for 4 hours to obtain an acrylate prepolymer;

[0057] (2) Add 58.2 parts by weight of copper propionate, 16.7 parts by weight of acetic acid and 100 parts by weight of xylene in the acrylate prepolymer of step (1), and react for 8 hours at 130° C. to obtain copper polyacrylate resin (green transparent resin solution).

[0058] Resin number average molecular weight M in the present embodiment n 1.0×10 4 g / mol, the copper content is 13.2%, and the acid ...

Embodiment 2

[0060] (1) In a reaction vessel, add 64 parts by weight of xylene and 16 parts by weight of propylene glycol methyl ether, heat to 95°C under a nitrogen atmosphere, and dropwise add 20 parts by weight of cyclohexyl methacrylate, 40 parts by weight of methyl Isooctyl acrylate, 10 parts by weight of hydroxyethyl acrylate, 20 parts by weight of 2-ethyl-2-oxazoline, 10 parts by weight of acrylic acid, 0.02 parts by weight of methanol and t-BuP 4 n-hexane solution (containing 0.04 parts by weight of t-BuP 4 ) formed mixture, after the dropwise addition was completed, it was incubated for 4 hours to obtain an acrylate prepolymer;

[0061] (2) Add 11.1 parts by weight of copper oxide, 20.0 parts by weight of isooctanoic acid and 60 parts by weight of xylene in the acrylate prepolymer of step (1), and react for 8 hours at 140° C. to obtain polyacrylic acid copper resin (green transparent resin solution).

[0062] Resin number average molecular weight M in the present embodiment n 1...

Embodiment 3

[0064] (1) In a reaction vessel, add 80 parts by weight of xylene, heat to 100°C under a nitrogen atmosphere, and dropwise add 10 parts by weight of polyethylene glycol methacrylate (polymerization degree is 9), 10 parts by weight of formaldehyde butyl acrylate, 10 parts by weight of 2-methoxyethyl acrylate, 40 parts by weight of acrylate, 20 parts by weight of γ-valerolactone, 10 parts by weight of methacrylic acid, 0.01 parts by weight of diethylene glycol and t-BuP 4 of n-hexane (containing 0.04 parts by weight t-BuP 4 ) formed mixture, after the dropwise addition was completed, it was incubated for 4 hours to obtain an acrylate prepolymer;

[0065] (2) Add 11.33 parts by weight of copper hydroxide, 35.1 parts by weight of abietic acid and 80 parts by weight of xylene in the acrylate prepolymer of step (1), and react for 8 hours at 140° C. to obtain copper polyacrylate resin (green transparent resin).

[0066] Resin number average molecular weight M in the present embodim...

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Abstract

The invention belongs to the technical field of marine antifouling materials and discloses a main chain degradation type polyacrylic copper resin as well as a preparation method and application thereof. The main chain degradation type polyacrylic copper resin is prepared from the following components in parts by weight: 100 parts of an acrylate prepolymer, 5-50 parts of a copper-containing compound, 0-75 parts of monocarboxylic acid and 5-150 parts of an organic solvent, wherein the acrylate prepolymer is mainly prepared from the following components: a solvent, a cyclic monomer, a vinyl monomer, a (methyl) acrylic acid and an initiator. The resin side chain copper ester bonds and main chain polyester chain segments can be hydrolyzed under seawater attach, the dependence of the traditional self-polishing material on the navigational speed is avoided, the coating surface is self-updated in static seawater due to the hydrolytic degradation effect, the anti-fouling composition can be effectively controlled to be released at a constant speed, and the anti-fouling requirements of ships at a low navigational speed, offshore production platforms and other facilities are met; and moreover, the main chain degradation type polyacrylic copper resin has excellent drag reduction effectiveness.

Description

technical field [0001] The invention belongs to the technical field of marine antifouling materials, and relates to a copper polyacrylate resin for marine antifouling coatings, in particular to a copper polyacrylate resin with degradable main chain and its preparation method and application; the resin is used for preparing Marine antifouling coatings. Background technique [0002] In recent years, limited land resources have been over-exploited, and people have gradually turned their attention and footprints to the ocean, which has also set off a wave of ocean fever. However, the serious problem of marine biofouling lies in front of people, and has been plaguing researchers all over the world. At present, the application of self-polishing marine antifouling coatings is the method with the highest commercial degree, the most mature technology and the longest service life. The main resins used for self-polishing antifouling coatings include polyacrylate silane resin, polyacr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/02C08F283/01C08F220/18C08F220/10C08F8/44C09D5/16
CPCC08F8/44C08F283/01C08F283/02C09D5/1637C08F220/1808C08F220/1812C08F220/1802
Inventor 张广照马春风潘健森
Owner 广东海巍新材料科技有限公司
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