A boiler decoking agent

A decoking agent and boiler technology, applied in fuel additives, solid fuel, petroleum industry, etc., can solve the problem of low efficiency of removing coke scale on the boiler wall, achieve the effect of reducing coal efficiency, reducing particle size, and avoiding loss

Active Publication Date: 2021-09-21
北京可林维尔化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to provide a boiler decoking agent in view of the low efficiency of the boiler wall coke removal agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0029] The preparation method of composite soot cleaning material comprises the following steps:

[0030] (1) According to the mass ratio of 1:5~8, take zinc powder and 10% acetic acid in mass concentration, and under the protection of nitrogen, wet ball milling at 300~350r / min for 12~15h to obtain ball abrasive, and take flake graphite and pulverize it in a pulverizer , pass through a 120-mesh sieve, take the sieved particles and add concentrated nitric acid according to the mass ratio of 4:1~2, stir in a water bath at 28~35°C at 300~450r / min for 20~35min, filter, take the filter residue and wash it with water until it is washed. After the liquid is neutral, move it to 65~80°C oven and dry to constant weight to obtain the dry matter, take the dried matter in a muffle furnace, and heat-treat at 800~900°C for 4~8min to obtain expanded graphite, and take the expanded graphite according to the mass ratio 4: 1~2: 15~20 Add ball abrasive and 20% ethanol solution to mix, oscillate w...

Embodiment 1

[0040] Auxiliary: Mix light calcium carbonate, borax, and zeolite at a mass ratio of 4:1:1 to obtain the auxiliary.

[0041] Mix acetone, pyridine, and water in a mass ratio of 1:2:10 to obtain a solvent.

[0042] Excipients: At 90°C, take water and mix it with zirconium oxychloride at a mass ratio of 8:1, stir at 200r / min for 30min, add glycerol twice the mass of zirconium oxychloride, and citric acid twice the mass of zirconium oxychloride , adjust the pH to 6.5 with a NaOH solution with a concentration of 0.1mol / L, and keep it warm for 4 hours to obtain the adjuvant.

[0043] Concentrated rice washing water: Take rice in water for rice washing operation at a mass ratio of 1:10 to obtain rice washing water, and add Na to the rice washing water at a mass ratio of 6:1:1 2 CO 3 , NaH 2 PO 4 Mix to obtain a mixed liquid, and vacuum evaporate at 60°C to 20% of the original volume to obtain a concentrated rice washing liquid.

[0044] Initiator: Mix ammonium persulfate and so...

Embodiment 2

[0058] Auxiliary: Mix light calcium carbonate, borax, and zeolite at a mass ratio of 4:2:1 to obtain the auxiliary.

[0059] Mix acetone, pyridine and water in a mass ratio of 4:2:10 to obtain a solvent.

[0060] Excipients: At 100°C, take water and add zirconium oxychloride in a mass ratio of 12:1 to mix, stir at 400r / min for 45min, add glycerol with 5 times the mass of zirconium oxychloride, and citric acid with 4 times the mass of zirconium oxychloride , adjust the pH to 7.5 with a NaOH solution with a concentration of 0.1mol / L, and keep it warm for 6 hours to obtain the adjuvant.

[0061] Concentrated rice washing water: Take rice in water for rice washing operation at a mass ratio of 1:15 to obtain rice washing water, and add Na to the rice washing water at a mass ratio of 8:2:1 2 CO 3 , NaH 2 PO 4 Mix to obtain a mixed liquid, and vacuum evaporate at 75°C to 35% of the original volume to obtain a concentrated rice washing liquid.

[0062] Initiator: Mix ammonium per...

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PUM

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Abstract

The invention discloses a boiler decoking agent, which belongs to the field of decoking agents. The invention uses zinc powder and flake graphite as raw materials, uses concentrated nitric acid to intercalate the flake graphite and then expands it to prepare expanded graphene, ball-mills the zinc powder into ultra-fine powder as a zinc source, and uses ethanol as a dispersant to prepare a composite material with good structure. , and interact with starch. During the preparation process, the composite material can be filled in the starch colloid pores and can be used as a cross-linking agent to cross-link the starch molecular chains, thereby making the porous starch surface denser and effectively avoiding internal deposition. Loss of ingredients during preparation and storage. The invention solves the current problem of low efficiency of boiler decoking agent in removing coke scale on the boiler wall.

Description

Technical field [0001] The invention belongs to the field of decoking agents, and specifically relates to a boiler decoking agent. Background technique [0002] Boiler decoking agent is processed from inorganic compounds according to a certain proportion. It appears as white granular or yellow powder crystals. When the agent is fed into the high-temperature furnace, a large amount of chemical smoke is generated and fully distributed throughout the furnace. The surface of the heat exchanger makes the soot on the heating surface of the boiler porous and loose, making it easy to powder and fall off. At present, it is common for chain furnace slag to be used as fuel again. Slag with high carbon content has caused huge pollution to the environment. Coking and dust accumulation during boiler operation are a major problem that plagues the boiler industry. During the use of the boiler, due to factors such as its specific use environment and the user's management level, corrosion a...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C10L9/10C10L10/04
CPCC10L9/10C10L10/04
Inventor胡丽春陈建春胡晓玉
Owner北京可林维尔化工有限公司