Corrosion-resistant coating material for navigation marks and preparation method of material

A corrosion-resistant and coating technology, applied in the field of coatings, can solve the problems of limited adhesion to the dense substrate of the coating, unsatisfactory effect, limited water and oil repellency, water resistance and corrosion resistance of the coating, and achieve surface adsorption. Strong strength, strong adhesion and good water resistance

Active Publication Date: 2019-05-31
苏州锦航工程技术服务有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Chinese patent application CN106398402A discloses an anti-corrosion marine coating, the coating components include 3-11 parts of polymerized o-p-toluidine, 15-23 parts of organic bentonite, 3.5-5.6 parts of aldehyde and ketone resin, 1.8 parts of polychlorotrifluoroethylene -3.2 parts, 5-14 parts of hydrogenated nitrile rubber, 12-18 parts of dienyl imide, 4.8-6.5 parts of alkyl succinic acid imide, 4-10 parts of glass microspheres; the coating of the invention Limited water and oil repellency, water repellency and corrosion resistance
[0006] Chinese patent application CN105238157A discloses an anti-corrosion marine coating and its preparation method. In this invention, chlorinated rubber and furan resin are miscible, and nano-calcium titanate and other additives coated and modified by coupling agent are added. The components are evenly dispersed, forming a highly polar C-Cl bond, which improves the corrosion resistance of the coating, but the compactness of the coating and the adhesion to the substrate are limited. The coating is only suitable for metal substrates, other substrates then the effect is not ideal

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  • Corrosion-resistant coating material for navigation marks and preparation method of material
  • Corrosion-resistant coating material for navigation marks and preparation method of material

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Embodiment 1

[0035] A kind of corrosion-resistant paint for navigation mark, its raw material comprises by weight: 32 parts of epoxy resin, 14 parts of polyester, 3 parts of coordination type titanate coupling agent, 15 parts of graphene, 10 parts of zinc powder, 35 parts of siloxane oligomer, 12 parts of antimicrobial agent tetrachloroisophthalonitrile, graphene is a micro-sheet powder structure with a thickness of 3 μm and a diameter of 6 μm, and zinc powder is a scaly structure with an average diameter of 2 μm .

[0036] Wherein, the preparation steps of siloxane oligomer are as follows:

[0037] (1) Manganese oxide is added to the aqueous solution containing glacial acetic acid, and then silica sol is added to prepare a mixed aqueous solution;

[0038] (2) Weigh and mix methyltrimethoxysilane and isopropanol according to the mass percentage of 1:1 to prepare a silanol solution;

[0039] (3) Under the condition of slow stirring, add the silanol solution prepared in step (2) to the mix...

Embodiment 2

[0046]A kind of corrosion-resistant coating for navigation mark, its raw material comprises by weight: 24 parts of epoxy resin, 22 parts of polyester, 1 part of titanate coupling agent, 6 parts of graphene, 20 parts of zinc powder, siloxane 45 parts of oligomers, 4 parts of antimicrobial agent diiodomethyl-p-tolylsulfone, graphene has a micro-sheet powder structure with a thickness of 8 μm and a diameter of 9 μm, and zinc powder has a scale-like structure with an average diameter of 9 μm.

[0047] Wherein, the preparation steps of siloxane oligomer are as follows:

[0048] (1) Calcium oxide is added to the aqueous solution containing acetic acid, and then silica sol is added to prepare a mixed aqueous solution;

[0049] (2) Weigh and mix methyltrimethoxysilane and isopropanol according to the mass percentage of 1:1 to prepare a silanol solution;

[0050] (3) Under the condition of slow stirring, add the silanol solution prepared in step (2) to the mixed aqueous solution prepa...

Embodiment 3

[0057] A kind of anti-corrosion coating for navigation mark, its raw material comprises by weight: 25 parts of epoxy resin, 20 parts of polyester, 2 parts of coordination type titanate coupling agent, 12 parts of graphene oxide, 12 parts of zinc powder , 38 parts of siloxane oligomer, 6 parts of antimicrobial agent phthalimide, graphene oxide is a micro-sheet powder structure with a thickness of 4 μm and a diameter of 7 μm, zinc powder is a spherical structure with an average diameter of 2 μm .

[0058] Wherein, the preparation steps of siloxane oligomer are as follows:

[0059] (1) Zinc oxide is added to the aqueous solution containing propionic acid, and then silica sol is added to prepare a mixed aqueous solution;

[0060] (2) Mix methyltrimethoxysilane and phenylsilane in proportion, and then mix them with isopropanol to prepare a silanol solution, wherein the mass percentage of methyltrimethoxysilane and phenylsilane is 70:30, and methyltrimethoxysilane The mass percent...

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Abstract

The invention relates to a corrosion-resistant coating material for navigation marks and a preparation method of the material. The raw materials of the coating material comprise the following components in parts by weight: 24-32 parts of epoxy resin, 14-22 parts of polyester, 1-3 parts of titanate coupling agents, 6-15 parts of graphene, 10-20 parts of zinc powder, 35-45 parts of siloxane oligomers and 4-12 parts of antimicrobial agents. The preparation method is simple to operate, and graphene and zinc powder are evenly dispersed in a mixture; the coating material solves the problems that a coating film of the coating material for the navigation marks is not dense enough, the waterproof and permeability resistance is poor, the anticorrosion performance is poor, and the adhesion force is poor in the prior art; and through the synergistic effect of all components, the corrosion resistance, the friction resistance, the water resistance, the weather resistance and the impact resistance ofthe coating are improved in the seawater environment , and meanwhile, the service life of the navigation marks is prolonged.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a corrosion-resistant coating used for navigation aids and a preparation method thereof. Background technique [0002] The marine environment is a complex corrosive environment. In this environment, seawater itself is a strong corrosive medium. At the same time, waves, waves, tides, and currents produce low-frequency reciprocating stress and impact on the navigation mark. Corrosion is extremely serious in the high-temperature marine environment. Corrosion not only reduces the structural strength of the buoy, shortens the service life, but also attaches marine organisms to its surface. Marine microorganisms, attached organisms and their metabolites all have a direct impact on the corrosion process. or indirect acceleration. [0003] Existing coatings are still difficult to deal with the problems of seawater corrosion, sudden changes in marine climate, and marine organisms. At pr...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D167/00C09D183/04C09D5/10C09D7/61C09D5/16
Inventor 石阳威黄祥张建维傅大卫王娟王蕾杜媛安齐美骏季磊孙银根蔡政
Owner 苏州锦航工程技术服务有限公司
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