The invention provides an inorganic full-solid-state electrochromic device with quick responsiveness and a preparation method thereof. The device comprises a substrate, a bottom protection layer, bottom conductor layers, color change layers, conduction layers, storage layers and top conductor layers, wherein the bottom protection layer, the bottom conductor layers, the color change layers, the conduction layer, the storage layers and the top conductor layers are arranged on the substrate in sequence; the inorganic full-solid-state electrochromic device is provided with multiple cavity slots, the cavity slots run through the bottom conductor layers from the top conductor layers, and each top conductor layer is divided into multiple units; each unit of each top conductor layer is independently provided with an electrode, middle electrodes are arranged on the portions, corresponding to one or more cavity slots, on the bottom conductor layers, and each unit of each top conductor layer andthe corresponding bottom conductor layer form an electric field; the top conductor layers and the bottom conductor layers have no short circuit. According to the inorganic full-solid-state electrochromic device, the electrodes are subjected to layout design, the large-area electrochromic device can be divided into multiple small-size units, the large-size device is subjected to partition control,the electric field and the voltage distribution condition of the device is improved, the whole color change response time of the device is prolonged, and the uneven color change phenomenon is avoided.