This invention relates to a group of benzyl amine derivatives and their preparation method, as well as their application as chemical herbicide in agriculture. In their general structural formula at right, D or E = H, halogens, C1~C4 alkyl, C1~C4 alkoxy, C1~C4 halogenated alkyl and C1~C4 halogenated alkyloxyl; R1, which can be placed on either of positions on benzene ring from 3 to 6, is = H, halogens, nitro, C1~C4 alkyl, C1~C4 alkyloxyl; R2 and R3=C1~C4 alkyl, C1~C4 halogenoalkyl, -CH2COOCH3, aryl-substituted C1~C4 alkyl, phenyl, R5-(or R6)-substituted phenyl or naphthyl and heterocyclic radical ( including pyridyl, thienyl, thiazyl and pyrimidinyl); or R2 , R3 and N combine to form circular amidogen, n= 0-2; R5 (or R6) is among H, halogens, nitro, hydroxyl, methyl, ethyl, teriarybutyl, chloromethyl, methoxyl, trifluoromethyl, trifluromethoxyl, ethoxyl, cyano and phenoxyl.