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The producing method of the rare earth based flat plate denitrification catalyst

A denitration catalyst, flat-plate technology, applied in chemical instruments and methods, heterogeneous catalyst chemical elements, physical/chemical process catalysts, etc. Industrial application difficulties and other problems, to achieve the effect of good sulfur resistance, strong surface adsorption energy, and low cost

Active Publication Date: 2017-01-04
DATANG NANJING ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of these catalysts include complex preparation process and difficulty in industrial application, or the catalyst has poor wear resistance, sulfur resistance, water resistance, or solid poisons such as alkali metals and alkaline earth metals, or the temperature window of the catalyst. Narrow is difficult to meet industrial applications, and there are few patents on rare earth substrate catalysts

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] (1) Weigh 17.75g of tetra-n-butyl titanate and 1.44g of tetraethyl orthosilicate dissolved in 15g of absolute ethanol, weigh 0.57g of ammonium molybdate and dissolve in citric acid solution with a mass concentration of 0.1% at 20°C , mix the two evenly, add acetic acid solution with a mass concentration of 0.5% to adjust the pH to 2, and keep the temperature at 60°C for 0.5h;

[0031] (2) Weigh 1000g anatase TiO 2 (Wuxi Tuoboda Titanium Dioxide Products Co., Ltd., model TBD-A107, specific surface area 85.1 m 2 / g), adding the stable sol in step (1) to TiO 2 medium, mix evenly, bake at 350°C for 5 hours, and grind to 200 mesh;

[0032] (3) Weigh 1.80g of tantalum pentachloride, 14.01g of cerium nitrate pentahydrate, and 8.86g of lanthanum nitrate, dissolve them in a sulfamic acid solution with a mass concentration of 10%, and mix well;

[0033] (4) Slowly add the stable solution in step (3) to step (2), stir evenly and slowly add ammonia solution with a mass concentra...

Embodiment 2

[0038] (1) Weigh 14.09g of ethyl titanate, 62.30g of orthosilicate methyl ester and dissolve in 30g of absolute ethanol, weigh 1.52g of molybdenum nitrate and dissolve in 50°C deionized water, mix the two evenly and add mass concentration Adjust the pH to 6 for the 10% sulfamic acid solution, and keep it warm at 30°C for 24h;

[0039] (2) Weigh 1000g anatase TiO 2 , adding the stable sol in step (1) to TiO 2 medium, mix evenly, roast at 650°C for 1 hour, and grind to 400 mesh;

[0040] (3) Weigh 29.66g of tantalum ethoxide, 10.20g of cerium oxalate, and 156.45g of lanthanum acetate, dissolve them in an acetic acid solution with a mass concentration of 0.5% and mix well;

[0041] (4) Slowly add the stable solution in step (3) to step (2), stir evenly and slowly add ammonia solution with a mass concentration of 25% to a pH of 8;

[0042] (5) Add 60 g of 100 nm zirconium dioxide, 20 g of aminocellulose, and 8 g of polyethylene wax to the preliminary catalyst paste obtained in ...

Embodiment 3

[0046] (1) Weigh 1.10g of tetraisobutyl titanate and 6.02g of methyl orthosilicate dissolved in 5g of absolute ethanol, weigh 4.51g of molybdenum chloride and dissolve in 60°C deionized water, mix the two evenly Add methanesulfonic acid solution with a mass concentration of 5% to adjust the pH to 5, and keep it at 40°C for 2h;

[0047] (2) Weigh 1000g anatase TiO 2 , adding the stable sol in step (1) to TiO 2 medium, mix evenly, bake at 500°C for 3 hours, and grind to 1000 mesh;

[0048] (3) Weigh 115.80g of tantalum chloride, 19.10g of cerium carbonate, and 32.26g of lanthanum chloride, dissolve them in a citric acid solution with a mass concentration of 5%, and mix well;

[0049] (4) Slowly add the stable solution in step (3) to step (2), stir evenly and slowly add ammonia solution with a mass concentration of 20% to pH 7;

[0050] (5) Add 1 g of 80 nm ferric oxide, 5 g of ammonium polyacrylate, and 10 g of paraffin to the preliminary catalyst paste obtained in step (4), ...

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Abstract

The invention discloses a producing method of the rare earth based flat plate denitrification catalyst which applies the anatase titanium dioxide powder as the first carrier, the titanium silicon molybdenum compound oxides as the active components, one or more of the nanometer oxides of tungsten, cobalt, nickel, zirconium iron as the assistant catalyst. What's more, add the binder and lubricant and then form the pastes of the denitrification catalyst. The pastes of the catalyst needs to be decayed, coated, dried, cut and calcined to make the flat plate denitrification catalyst. The rare earth denitrification catalyst produced in this method has a good stability of high temperature and frame. The anti-wear and anti-seismic functions are quite excellent. it also has features like wider temperature windows, higher denitrification efficiency and simple recycling and processing of waste catalyst. The processing is simple and low-cost so it can meet the requirements of the industrial application and will be adapted to the denitrification of all the fixed and moving sources.

Description

technical field [0001] The invention relates to a rare earth-based flat-plate denitrification catalyst and a preparation method thereof, belonging to the fields of environmental protection catalytic materials and air pollution control. Background technique [0002] The ultra-clean emission of nitrogen oxides from coal-fired power plants has been fully rolled out, and remarkable results have been achieved with the joint efforts of all sectors of society. At present, the most widely used denitrification technology in coal-fired power plants is selective catalytic reduction (SCR), the core of which is catalyst, mostly vanadium-titanium series. where V 2 o 5 It is a highly toxic substance, slightly soluble in water, which will damage the human respiratory system and skin, cause kidney damage, visual impairment, etc., and the vanadium-titanium system catalyst will produce pollution during production and use. The waste vanadium-titanium catalyst belongs to Hazardous solid waste...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/28B01J23/30B01J23/887B01J23/888B01D53/86B01D53/56
CPCB01D53/8631B01J23/002B01J23/28B01J23/30B01J23/8877B01J23/8885B01J2523/00B01J2523/3706B01J2523/3712B01J2523/41B01J2523/47B01J2523/48B01J2523/57B01J2523/68B01J2523/69B01J2523/842B01J2523/847
Inventor 纵宇浩王虎陈志平黄力李倩王晓伟孙丹
Owner DATANG NANJING ENVIRONMENTAL PROTECTION TECH
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