The producing method of the rare earth based flat plate denitrification catalyst
A denitration catalyst, flat-plate technology, applied in chemical instruments and methods, heterogeneous catalyst chemical elements, physical/chemical process catalysts, etc. Industrial application difficulties and other problems, to achieve the effect of good sulfur resistance, strong surface adsorption energy, and low cost
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Embodiment 1
[0030] (1) Weigh 17.75g of tetra-n-butyl titanate and 1.44g of tetraethyl orthosilicate dissolved in 15g of absolute ethanol, weigh 0.57g of ammonium molybdate and dissolve in citric acid solution with a mass concentration of 0.1% at 20°C , mix the two evenly, add acetic acid solution with a mass concentration of 0.5% to adjust the pH to 2, and keep the temperature at 60°C for 0.5h;
[0031] (2) Weigh 1000g anatase TiO 2 (Wuxi Tuoboda Titanium Dioxide Products Co., Ltd., model TBD-A107, specific surface area 85.1 m 2 / g), adding the stable sol in step (1) to TiO 2 medium, mix evenly, bake at 350°C for 5 hours, and grind to 200 mesh;
[0032] (3) Weigh 1.80g of tantalum pentachloride, 14.01g of cerium nitrate pentahydrate, and 8.86g of lanthanum nitrate, dissolve them in a sulfamic acid solution with a mass concentration of 10%, and mix well;
[0033] (4) Slowly add the stable solution in step (3) to step (2), stir evenly and slowly add ammonia solution with a mass concentra...
Embodiment 2
[0038] (1) Weigh 14.09g of ethyl titanate, 62.30g of orthosilicate methyl ester and dissolve in 30g of absolute ethanol, weigh 1.52g of molybdenum nitrate and dissolve in 50°C deionized water, mix the two evenly and add mass concentration Adjust the pH to 6 for the 10% sulfamic acid solution, and keep it warm at 30°C for 24h;
[0039] (2) Weigh 1000g anatase TiO 2 , adding the stable sol in step (1) to TiO 2 medium, mix evenly, roast at 650°C for 1 hour, and grind to 400 mesh;
[0040] (3) Weigh 29.66g of tantalum ethoxide, 10.20g of cerium oxalate, and 156.45g of lanthanum acetate, dissolve them in an acetic acid solution with a mass concentration of 0.5% and mix well;
[0041] (4) Slowly add the stable solution in step (3) to step (2), stir evenly and slowly add ammonia solution with a mass concentration of 25% to a pH of 8;
[0042] (5) Add 60 g of 100 nm zirconium dioxide, 20 g of aminocellulose, and 8 g of polyethylene wax to the preliminary catalyst paste obtained in ...
Embodiment 3
[0046] (1) Weigh 1.10g of tetraisobutyl titanate and 6.02g of methyl orthosilicate dissolved in 5g of absolute ethanol, weigh 4.51g of molybdenum chloride and dissolve in 60°C deionized water, mix the two evenly Add methanesulfonic acid solution with a mass concentration of 5% to adjust the pH to 5, and keep it at 40°C for 2h;
[0047] (2) Weigh 1000g anatase TiO 2 , adding the stable sol in step (1) to TiO 2 medium, mix evenly, bake at 500°C for 3 hours, and grind to 1000 mesh;
[0048] (3) Weigh 115.80g of tantalum chloride, 19.10g of cerium carbonate, and 32.26g of lanthanum chloride, dissolve them in a citric acid solution with a mass concentration of 5%, and mix well;
[0049] (4) Slowly add the stable solution in step (3) to step (2), stir evenly and slowly add ammonia solution with a mass concentration of 20% to pH 7;
[0050] (5) Add 1 g of 80 nm ferric oxide, 5 g of ammonium polyacrylate, and 10 g of paraffin to the preliminary catalyst paste obtained in step (4), ...
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