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Low-temperature denitration and heat storage integrated catalytic type honeycomb ceramic material

A technology of honeycomb ceramics and low-temperature denitrification, which is applied in the direction of physical/chemical process catalysts, ceramic products, catalyst activation/preparation, etc. It can solve the problems of increasing the electricity cost of induced draft fans, narrow activation temperature window, and no heat storage function. Achieve the effects of improving energy utilization efficiency, improving anti-sintering ability, and superior performance

Inactive Publication Date: 2018-07-06
HUBEI SHENWU THERMAL ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The traditional vanadium-titanium denitrification catalyst has a narrow activation temperature window (320-400°C), and is susceptible to SO 2 Poisoning, low activity at low temperature, and easy to produce ammonium sulfate, which can block the catalyst hole, air preheater and downstream equipment, cause a large pressure drop in the system, increase the electricity cost of the induced draft fan and other unfavorable factors
[0007] Moreover, the existing rare earth-based catalysts do not have heat storage function, and have poor wear resistance, high low value of active temperature, low strength, and short service life; so that the scope of application is greatly limited. Therefore, we urgently need to study a new type of catalyst. Replace the above products

Method used

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  • Low-temperature denitration and heat storage integrated catalytic type honeycomb ceramic material
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  • Low-temperature denitration and heat storage integrated catalytic type honeycomb ceramic material

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Embodiment 1

[0034] The low-temperature denitrification and heat storage integrated catalytic honeycomb ceramic material mainly consists of the following components: 70 parts of nano-scale alumina, 40 parts of nano-magnesia, 35 parts of nano-titanium dioxide, 1 part of boron nitride, 50 parts of silicon dioxide powder, methyl 10 parts of methyl acrylate-butadiene-styrene terpolymer, 8 parts of glass fiber, 0.8 part of stearic acid, 0.8 part of high molecular polymer fiber, and 1 part of amino cellulose are kneaded with mud, aged and extruded Prepared by forming, drying and calcining, impregnating the catalytic slurry, drying and calcining again;

[0035] The catalytic slurry is mainly composed of the following components: weigh 5 parts of nano-scale alumina, 5 parts of ferric nitrate, 15 parts of manganese nitrate, 10 parts of mullite, 5 parts of ammonium dihydrogen phosphate, polydimethylsiloxane 2 parts of alkane, 6 parts of aluminum stearate, 3 parts of nano-neodymium oxide, 8 parts of ...

Embodiment 2

[0049] The low-temperature denitrification and heat storage integrated catalytic honeycomb ceramic material mainly consists of the following components: 75 parts of nano-scale alumina, 38 parts of nano-magnesia, 32 parts of nano-titanium dioxide, 2 parts of boron nitride, 55 parts of silicon dioxide powder, methyl 8 parts of methyl acrylate-butadiene-styrene terpolymer, 5 parts of glass fiber, 0.9 part of stearic acid, 0.9 part of high molecular polymer fiber, and 0.9 part of amino cellulose are kneaded with mud, aged and extruded Prepared by forming, drying and calcining, impregnating the catalytic slurry, drying and calcining again;

[0050] The catalytic slurry is mainly composed of the following components: 6 parts of nano-scale alumina, 8 parts of iron nitrate, 10 parts of manganese nitrate, 8 parts of mullite, 7 parts of ammonium dihydrogen phosphate, polydimethylsiloxane 1.2 parts of alkane, 8 parts of aluminum stearate, 4 parts of nano-neodymium oxide, 6 parts of ammon...

Embodiment 3

[0064] The low-temperature denitrification and heat storage integrated catalytic honeycomb ceramic material mainly consists of the following components: 80 parts of nano-scale alumina, 35 parts of nano-magnesia, 30 parts of nano-titanium dioxide, 3 parts of boron nitride, 60 parts of silicon dioxide powder, methyl 4 parts of methyl acrylate-butadiene-styrene terpolymer, 3 parts of glass fiber, 1 part of stearic acid, 1 part of polymer fiber, 0.8 part of amino cellulose, kneaded with mud, aged and extruded Prepared by forming, drying and calcining, impregnating the catalytic slurry, drying and calcining again;

[0065] The catalytic slurry is mainly composed of the following components: 8 parts of nano-scale alumina, 10 parts of iron nitrate, 5 parts of manganese nitrate, 5 parts of mullite, 10 parts of ammonium dihydrogen phosphate, polydimethylsiloxane 0.5 parts of alkane, 10 parts of aluminum stearate, 5 parts of nano-neodymium oxide, 5 parts of ammonium metatungstate, 4 par...

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Abstract

The invention discloses a low-temperature denitration and heat storage integrated catalytic type honeycomb ceramic material. The ceramic material is characterized by being mainly prepared from 70 to 80 parts of nano-scale aluminum oxide, 35 to 40 parts of nanometer magnesia, 30 to 35 parts of nano titanium dioxide, 1 to 3 parts of boron nitride, 50 to 60 parts of silicon dioxide powder, 4 to 10 parts of methyl methacrylate-butadiene-styrene terpolymer, 3 to 8 parts of glass fiber, 0.8 to 1 part of stearic acid, 0.8 to 1 part of a macromolecular polymer fiber and 0.8 to 1 part of aminocellulose. The ceramic material is prepared by kneading the components to form catalyst mud, decaying the catalyst mud, extruding and forming the catalyst mud, forming a catalyst, drying a wet green body and calcining the wet green body. According to the low-temperature denitration and heat storage integrated catalytic type honeycomb ceramic material disclosed by the invention, the catalysis efficiency ofthe catalyst is improved, and the use cost of the catalyst is reduced; by the adding of the stearic acid, forming and demolding of the catalyst are facilitated, and the finished product ratio of catalyst manufacturing is increased. The preparation steps are simple; reaction conditions under a medium-temperature environment are mild; the cost is low.

Description

technical field [0001] The invention relates to a medium-temperature catalyst, in particular to a catalytic type honeycomb ceramic material integrated with low-temperature denitrification and heat storage. Background technique [0002] In recent years, energy and its related environment have become the most concerned hotspots in countries all over the world. Due to the shortage of per capita energy resources, limited environmental capacity and fragile ecology in our country, it will greatly restrict the sustainable development of our country. Domestic GDP is growing rapidly every year, energy consumption is increasing rapidly, and the environment and ecology are deteriorating day by day. Saving energy and reducing consumption has become a major direction for solving energy problems. According to statistics, the energy consumption of the domestic industrial sector accounts for 70% of the total energy in the country. Among them, industrial furnaces are the largest energy co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/10C04B35/632C04B35/634C04B35/636C04B35/82C04B38/00B01J27/24B01J35/04B01J37/02B01J37/08B01D53/56
CPCB01D53/56C04B35/10C04B35/632C04B35/6344C04B35/6365C04B35/82C04B38/0006B01J27/24B01J37/0215B01J37/08C04B2235/3418C04B2235/386C04B2235/5212C04B2235/3206C04B2235/3232C04B2235/6567C04B2235/6562C04B2235/9607C04B2235/96B01J35/56
Inventor 吴道君李军营周守洪杨晓波陈浩
Owner HUBEI SHENWU THERMAL ENERGY TECH
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