Special material for manufacturing biodegradable antibacterial breathable membrane and preparation method thereof
A technology of biodegradable material and breathable film, applied in the field of polymer/inorganic powder composite material processing, can solve the problems of environmental pollution, secondary pollution, easy to be infected by bacteria, etc., achieve good biocompatibility, reduce environmental pollution, etc. Pollution, the effect of good antibacterial effect
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Embodiment 1
[0030] Choose 50 parts of superfine heavy calcium carbonate, choose aluminate coupling agent as surface modifier, titanate coupling agent 0.5 parts each, activator choose stearic acid 1 part, rare earth antibacterial agent choose rare earth metal lanthanum and hydroxyl 1 part of rare earth metal complex formed by quinoline and Schiff base, 0.5 parts of antioxidant 1010, 1.5 parts of zinc stearate as processing aid, 40 parts of polylactic acid and polyethylene glycol for biodegradable materials Alcohol 5 parts. Wherein, the antioxidant can be selected from hindered phenolic antioxidants and phosphorous acid antioxidants and mixed with one or more. Choose from antioxidants such as Oxygen 1010, Antioxidant 1076 and Antioxidant 245.
[0031] (1) Grinding and grading heavy calcium carbonate with a jet mill to obtain unmodified ultrafine heavy calcium carbonate powder with a particle size distribution range of D50<3 μm, D95<8 μm, and D100<10 μm;
[0032] (2) drying the unmodified ...
Embodiment 2
[0039] Select 35 parts of superfine heavy calcium carbonate, 0.5 parts of phosphate coupling agent as surface modifier, 2 parts of epoxy soybean oil as activator, and 2 parts of rare earth antibacterial agent as rare earth metal yttrium, picolinic acid and o-phenanthroline 0.5 part of rare earth metal complex, 2 parts of calcium stearate as processing aid, 50 parts of polylactic acid and 8 parts of polycaprolactone as biodegradable material, and 2 parts of tributyl citrate as compatibilizer.
[0040] (1) Grinding and grading heavy calcium carbonate with a jet mill to obtain unmodified ultrafine heavy calcium carbonate powder with a particle size distribution range of D50<3 μm, D95<8 μm, and D100<10 μm;
[0041] (2) drying the unmodified superfine ground calcium carbonate powder to a moisture content of ≤0.3%, and placing 35 parts of the dried unmodified superfine ground calcium carbonate powder in a high-speed mixer;
[0042] (3) Add 0.5 parts of phosphate coupling agent, mix ...
Embodiment 3
[0048]Select 40 parts of superfine heavy calcium carbonate, 3 parts of borate coupling agent as surface modifier, 0.5 part of monoglyceride stearate as activator, rare earth antibacterial agent as rare earth metal yttrium and o-phenanthroline, nitric acid 0.5 parts of rare earth metal complexes formed by root ions, 0.5 parts of antioxidant 1076 (commonly available antioxidants in the market include antioxidant 168, antioxidant 1010, antioxidant 1076 and antioxidant 245), 3 parts of calcium stearate were selected as processing aids, 42 parts of polylactic acid and 8 parts of polybutylene succinate were selected as biodegradable materials, and 2.5 parts of tributyl phosphite were selected as compatibilizer.
[0049] (1) Grinding and grading heavy calcium carbonate with a jet mill to obtain unmodified ultrafine heavy calcium carbonate powder with a particle size distribution range of D50<3 μm, D95<8 μm, and D100<10 μm;
[0050] (2) Dry the unmodified superfine ground calcium carb...
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