An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware
A composite material and polylactic acid technology, which are applied in the field of high temperature resistant polylactic acid composite materials and their preparation, can solve the problem of increasing the interface bonding force between inorganic fillers and organisms, improving the easy cleaning performance of polylactic acid products, and crystallization of polylactic acid composite materials. Slow speed and other problems, to achieve the effects of excellent hydrophilic ability, improved interfacial adhesion, and good hydrolytic stability
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Embodiment 1
[0031] An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware is composed of the following parts by weight of raw materials: 35 parts of modified polylactic acid, 65 parts of plant fibers, 1.5 parts of sodium rosin, 0.3 parts of magnesium aluminum silicate, 25 parts of polyethylene glycol and 3 parts of polyethylene wax, and its preparation method comprises the following steps:
[0032]Add the weighed plant fiber and polyethylene glycol into the high-speed mixer and stir for 5-10min. The stirring speed is set to 320-450r / min, and the temperature is raised to 80-90°C. After mixing sodium rosin and modified polylactic acid, stir for 1-1.5h, after cooling to room temperature, add magnesium aluminum silicate and polyethylene wax in turn, after stirring for 10-15min, add the well-stirred mixture to the twin-screw extruder Melting and blending in the machine, extrusion, drawing and granulation, the easy-to-clean high...
Embodiment 2
[0037] An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware is composed of the following parts by weight of raw materials: 70 parts of modified polylactic acid, 30 parts of plant fibers, 0.8 parts of sodium rosin, 0.1 part of magnesium aluminum silicate, 10 parts of polyethylene glycol, 3 parts of polyethylene wax and 3 parts of N,N,-ethylene bis-stearamide, the preparation method is the same as that in Example 1, specifically referring to Example 1, the difference is polyethylene wax (i.e. lubricant) was replaced with polyethylene wax and N,N,-ethylenebisstearamide.
[0038] The preparation method of above-mentioned modified polylactic acid comprises the following steps:
[0039] Add 100 parts of polylactic acid to an appropriate amount of tetrahydrofuran solution, stir at 50 ° C until dissolved, add 2.4 parts of FC-99 and 0.5 part of TM-200S to the mixed solution under constant temperature conditions, stir ...
Embodiment 3
[0042] An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware is composed of the following raw materials in parts by weight: 45 parts of modified polylactic acid, 55 parts of plant fibers, 1.2 parts of sodium rosin, 0.2 parts of magnesium aluminum silicate, 20 parts of polyethylene glycol and 4 parts of glycerol trihydroxystearate, its preparation method is the same as in Example 1, with specific reference to Example 1, the difference is that polyethylene wax (i.e. lubricant) is replaced with glycerol trihydroxystearate Fatty acid ester.
[0043] The preparation method of above-mentioned modified polylactic acid comprises the following steps:
[0044] Add 100 parts of polylactic acid to an appropriate amount of tetrahydrofuran solution, stir at 50 ° C until dissolved, add 3.0 parts of FC-99 and 0.7 parts of TM-200S to the mixed solution under constant temperature conditions, stir for 2.5-4 hours, and then heat ...
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