Unlock instant, AI-driven research and patent intelligence for your innovation.

An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware

A composite material and polylactic acid technology, which are applied in the field of high temperature resistant polylactic acid composite materials and their preparation, can solve the problem of increasing the interface bonding force between inorganic fillers and organisms, improving the easy cleaning performance of polylactic acid products, and crystallization of polylactic acid composite materials. Slow speed and other problems, to achieve the effects of excellent hydrophilic ability, improved interfacial adhesion, and good hydrolytic stability

Active Publication Date: 2022-07-08
湖南钜亿新材料科技有限公司
View PDF6 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese invention patent CN106221162B discloses a heat-resistant and durable polylactic acid composite material. The shell micropowder is subjected to surface activation treatment, and the sisal fiber is subjected to thermoplastic modification treatment, and then the components are extruded through a twin-screw extruder. out of granulation, the composite material uses natural shell powder and sisal fiber to improve the performance, so that the heat distortion temperature exceeds 100 ° C, and has properties such as hydrolysis resistance and aging resistance, but the compatibility of the components of the polylactic acid composite material is poor , resulting in poor toughness, high brittleness and easy breakage of molded products of modified materials
Chinese invention patent CN107201015B discloses an antibacterial and heat-resistant polylactic acid tableware. In-situ graft surface modification is carried out on inorganic fillers, and melt blending is carried out by one-step method. The grafted crosslinking structure between components of the present invention can significantly increase the inorganic The interfacial binding force between the filler and the organism improves the mechanical properties of the polylactic acid tableware, improves the temperature resistance, and has antibacterial and oxidation resistance, but the crystallization rate of the polylactic acid composite material is slow, the toughness is poor, and There is no greater improvement with the improvement of heat resistance, which will affect the service life, which is not conducive to the widespread promotion in the field of tableware
[0005] To sum up, using some current methods to modify polylactic acid will have problems of low efficiency and durability, and there are no reports and studies on improving the performance of polylactic acid products in terms of easy cleaning. Therefore, as environmental protection With the widespread promotion of tableware, it will become an inevitable trend to develop an easy-to-clean and heat-resistant polylactic acid composite material

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware
  • An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware
  • An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware is composed of the following parts by weight of raw materials: 35 parts of modified polylactic acid, 65 parts of plant fibers, 1.5 parts of sodium rosin, 0.3 parts of magnesium aluminum silicate, 25 parts of polyethylene glycol and 3 parts of polyethylene wax, and its preparation method comprises the following steps:

[0032]Add the weighed plant fiber and polyethylene glycol into the high-speed mixer and stir for 5-10min. The stirring speed is set to 320-450r / min, and the temperature is raised to 80-90°C. After mixing sodium rosin and modified polylactic acid, stir for 1-1.5h, after cooling to room temperature, add magnesium aluminum silicate and polyethylene wax in turn, after stirring for 10-15min, add the well-stirred mixture to the twin-screw extruder Melting and blending in the machine, extrusion, drawing and granulation, the easy-to-clean high...

Embodiment 2

[0037] An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware is composed of the following parts by weight of raw materials: 70 parts of modified polylactic acid, 30 parts of plant fibers, 0.8 parts of sodium rosin, 0.1 part of magnesium aluminum silicate, 10 parts of polyethylene glycol, 3 parts of polyethylene wax and 3 parts of N,N,-ethylene bis-stearamide, the preparation method is the same as that in Example 1, specifically referring to Example 1, the difference is polyethylene wax (i.e. lubricant) was replaced with polyethylene wax and N,N,-ethylenebisstearamide.

[0038] The preparation method of above-mentioned modified polylactic acid comprises the following steps:

[0039] Add 100 parts of polylactic acid to an appropriate amount of tetrahydrofuran solution, stir at 50 ° C until dissolved, add 2.4 parts of FC-99 and 0.5 part of TM-200S to the mixed solution under constant temperature conditions, stir ...

Embodiment 3

[0042] An easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware is composed of the following raw materials in parts by weight: 45 parts of modified polylactic acid, 55 parts of plant fibers, 1.2 parts of sodium rosin, 0.2 parts of magnesium aluminum silicate, 20 parts of polyethylene glycol and 4 parts of glycerol trihydroxystearate, its preparation method is the same as in Example 1, with specific reference to Example 1, the difference is that polyethylene wax (i.e. lubricant) is replaced with glycerol trihydroxystearate Fatty acid ester.

[0043] The preparation method of above-mentioned modified polylactic acid comprises the following steps:

[0044] Add 100 parts of polylactic acid to an appropriate amount of tetrahydrofuran solution, stir at 50 ° C until dissolved, add 3.0 parts of FC-99 and 0.7 parts of TM-200S to the mixed solution under constant temperature conditions, stir for 2.5-4 hours, and then heat ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
lengthaaaaaaaaaa
heat deflection temperatureaaaaaaaaaa
tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention discloses an easy-to-clean and high-temperature-resistant polylactic acid composite material for environment-friendly tableware, and relates to the technical field of polylactic acid composite materials. The easy-to-clean high-temperature-resistant polylactic acid composite material for environmentally friendly tableware disclosed in the present invention is composed of the following raw materials by weight: 35-70 parts of modified polylactic acid, 30-65 parts of plant fibers parts, 0.8-1.5 parts of sodium rosin, 0.1-0.3 parts of magnesium aluminum silicate, 10-25 parts of polyethylene glycol and 3-6 parts of lubricant, the invention also discloses an easy-to-clean and high-temperature-resistant polymer Preparation method of lactic acid composite material. The polylactic acid composite material of the invention is easy to clean, can withstand high temperature, has a heat deformation temperature of over 120° C., and has excellent mechanical properties, high toughness, is not easy to be brittle, and prolongs the service life. The preparation method of the composite material is simple and cost-effective. Low, completely biodegradable, can be widely used in food packaging and environmental protection tableware and other fields.

Description

technical field [0001] The invention belongs to the technical field of polylactic acid composite materials, and in particular relates to an easy-to-clean and high-temperature-resistant polylactic acid composite material for environmentally friendly tableware and a preparation method thereof. Background technique [0002] Today, with the theme of environment and sustainable development, environmentally friendly biodegradable polymer materials are undoubtedly favored by people and become a research hotspot in recent years. However, polylactic acid is considered to be one of the most promising alternatives to traditional plastics. Polylactic acid (PLA) is a biodegradable aliphatic polyester prepared by chemical synthesis with lactic acid formed by fermentation of corn or potato starch as raw material. The energy consumption in the production process is lower than that of petroleum-based polymers such as PP, and it is a polymer material with low environmental load. [0003] PLA...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/04C08L97/02C08L1/02C08L71/02C08K13/02C08K5/098C08K3/34C08K5/435C08K5/00C08J3/24
CPCC08L97/02C08L1/02C08L67/04C08J3/24C08L2201/08C08L2205/035C08L2205/03C08L2205/16C08L2201/06C08J2367/04C08L71/02C08K13/02C08K5/098C08K3/34C08K5/435C08K5/0091Y02W90/10
Inventor 胡育强胡一帆
Owner 湖南钜亿新材料科技有限公司