Method and system for co-processing waste incineration fly ash and zinc-containing dust mud of steel plant

A waste incineration fly ash and co-processing technology, applied in the direction of furnace, furnace type, rotary drum furnace, etc., can solve the problems of increasing the final processing capacity, low strength of solidified body, failure to achieve volume reduction and resource utilization, and achieve solidification Good effect, good resource utilization effect, good vitrified structure and hydration activity effect

Active Publication Date: 2021-03-05
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Disadvantages: The addition of curing agent just increases the final treatment capacity and takes up a lot of land; secondly, the strength of the cured body is low, the long-term stability of heavy metals is poor, and the purpose of volume reduction and resource utilization cannot be achieved at the same time
Advantages: simple treatment process, low investment in equipment; Disadvantages: wastewater with high concentration of inorganic salts will be produced, which needs further treatment; secondly, the price of chemical stabilizers is high, and the treatment of heavy metals is not thorough
Disadvantages: high energy consumption
The main purpose of this technology is to utilize the valuable components in fly ash, such as CaO, Fe 2 o 3 , MgO, Al 2 o 3 However, the alkali metals, heavy metals and chlorides in the fly ash will enter the blast furnace with the sinter, which will have a significant adverse effect on the smooth production of the blast furnace and the life of the lining

Method used

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  • Method and system for co-processing waste incineration fly ash and zinc-containing dust mud of steel plant
  • Method and system for co-processing waste incineration fly ash and zinc-containing dust mud of steel plant
  • Method and system for co-processing waste incineration fly ash and zinc-containing dust mud of steel plant

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058]Premix the fly ash and blast furnace zinc-containing ash / mud at a ratio of 1:9, add 2% binder, 1.5% lime, and 8-10% water according to the mass ratio for mixing, and then briquetting on the roller forming machine. Then natural conservation for 72h. Afterwards, it is continuously fed into the rotary kiln for pre-reduction, and the obtained hot charge is discharged into the smelting reduction furnace by a screw conveyor. Mix coke, semi-coke, and crushed coke foam in proportion and add them to the silo, and feed them into the smelting reduction furnace from the top of the furnace through the material tank in batches. Hot air at 1250°C with an oxygen concentration of 30% is blasted into the hearth tuyeres of the smelting reduction furnace, and pulverized coal is sprayed into the tuyeres. The crude gas at about 830°C discharged from the smelting reduction furnace is separated from the carbon-containing coarse dust by the hot cyclone dust collector, and then enters the rotary...

Embodiment 2

[0060] Premix fly ash and zinc-containing dust (blast furnace ash and converter ash in a ratio of 1:2) in a ratio of 1.5:8.5. According to the mass ratio, the amount of carbon is 3%, binder 2.5%, lime 1.5%, moisture Controlled at 8-10%, the working procedure is the same as above. Among them, the blast temperature of the smelting reduction furnace is 1220°C, the oxygen concentration is 35%, and the blast humidity is 9g / m 3 , the amount of coal injection is 180kg / t. The gas temperature at the inlet of the rotary kiln is 810°C.

Embodiment 3

[0062] Premix fly ash and zinc-containing dust sludge (blast furnace ash, converter ash and electric furnace ash three kinds of zinc-containing dust in a ratio of 1:1:1) in a ratio of 2:8, with a carbon content of 7% according to the mass ratio, and bond Addition of agent is 3%, lime 1.5%, and operation process is the same as above. Among them, the blast temperature of the smelting reduction furnace is 1200°C, the oxygen concentration is 35%, and the blast humidity is 12g / m 3 , the amount of coal injection is 170kg / t. The gas temperature at the inlet of the rotary kiln is 800°C.

[0063] The above-mentioned 3 examples, after detection and analysis, as shown in Table 2 to Table 6 below, the concentration of dioxin in bag dust removal ash, clean gas, and water washing mud is far lower than the environmental protection discharge standard value; the Cl ion content of water slag is all <0.06% , The leaching concentrations of various heavy metals in water slag, bag dust and washed...

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Abstract

The invention discloses a method and a system for co-processing waste incineration fly ash and zinc-containing dust mud of a steel mill. The method comprises the following steps: 1, adding 1.5% of lime and pulverized coal into the fly ash and the dust mud according to the slagging alkalinity of 1.1-1.3, the total carbon content of 2-8% and the binder ratio of 2-5% for proportioning, wherein the fly ash accounts for 5-20% of the dust mud; 2, adding water into the mixture, extruding into blocks or pelletizing, and curing until the strength meets the requirement; 3, adding the agglomerates or pellets into a rotary kiln, and introducing high-temperature coal gas to pre-reduce the agglomerates or pellets in the kiln; 4, continuously adding the pre-reduced agglomerates or pellets into a smeltingreduction furnace, and meanwhile distributing main fuel such as nut coke within the range of the material surface radius of the smelting reduction furnace; blowing hot air with the oxygen concentration of 35% from a tuyere of a reduction furnace, and spraying pulverized coal through the tuyere; and carrying out further indirect reduction, softening melting and FeO-C final reduction on the pre-reduced pellets in a coke bed in the reduction furnace to generate molten iron and furnace slag. According to the main purpose, the fly ash is cooperatively treated and utilized by combining the advantages of a metallurgical furnace for treating zinc-containing dust according to the chemical components of the fly ash.

Description

technical field [0001] The invention belongs to the technical field of environmental protection, and in particular relates to a method and a system for co-processing and utilizing waste incineration fly ash and steel plant zinc-containing solid waste. Background technique [0002] Waste incineration is the process of converting waste into heat energy, waste gas and residue through thermal decomposition, combustion and other reactions. During the incineration process of garbage, flue gas will be produced, and fly ash is the dust removal ash produced by dust removal and purification of flue gas, including bag filter fly ash and flue gas purification absorption tower fly ash. Waste incineration fly ash is classified as double hazardous waste because it is rich in heavy metals such as Pb, Cr, Cd, Zn, Hg, Cu, Ni, As, and highly toxic organic compounds dioxins and furans (PCDD / DFs). In addition, fly ash also contains more than 20% of Ca, Na, and K chlorides. Because the main com...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/243C21B13/14C21B13/08
CPCC22B1/243C22B1/2406C21B13/14C21B13/08C21B13/0006C21B13/0066C21B13/0073
Inventor 徐万仁毛晓明陈小龙许海法康健王玉明
Owner BAOSHAN IRON & STEEL CO LTD
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