A kind of high-strength environmental protection wood board adhesive and preparation method thereof
An adhesive and high-strength technology, applied in the direction of polymer adhesive additives, non-polymer adhesive additives, adhesive types, etc., can solve problems such as low VOC content, human health hazards, air pollution, etc. Achieve the effects of less side reactions, increased hard segment content, and simple operation
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Embodiment 1
[0025] A high-strength environment-friendly wood board adhesive is prepared from the following raw materials by weight: 40 parts of hexamethylene diisocyanate, 10 parts of hydroxyl terminated ethylene oxide-tetrahydrofuran copolyether, 7.5 parts of modified polyimide, 75 parts of fluorinated polyether glycol, 1.3 parts of dibutyltin dilaurate, 0.4 part of boron trifluoride triethanolamine complex, β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid 0.2 part of n-octadecyl alcohol ester and 0.2 part of antioxidant.
[0026] The modified polyimide is prepared by the following steps:
[0027] (1) Mix 49 parts of N,N-dimethylacetamide and 6.5 parts of 3,3',4,4'-biphenyltetracarboxylic dianhydride, stir under nitrogen for 8 minutes, and then add 1.5 parts of 2, 4,6-triaminopyrimidine was stirred for 36 hours;
[0028] (2) The obtained solution was heated to 155° C., and xylene and water were added to azeotrope to remove the generated water. After cooling, the solution was washed ...
Embodiment 2
[0034] A high-strength environment-friendly wood board adhesive is prepared from the following raw materials in parts by weight: 30 parts of 4,4'-diphenylmethane diisocyanate, 5 parts of hydroxyl-terminated ethylene oxide-tetrahydrofuran copolyether, modified polyamide 5 parts of imine, 60 parts of fluorine-containing polyether glycol, 0.5 part of dibutyltin dilaurate, 0.2 part of boron trifluoride triethanolamine complex, β-(3,5-di-tert-butyl-4-hydroxyl 0.1 part of isooctyl phenyl) propionate and 0.1 part of antioxidant.
[0035] The modified polyimide is prepared by the following steps:
[0036] (1) Mix 47 parts of N,N-dimethylacetamide and 6 parts of 3,3',4,4'-biphenyltetracarboxylic dianhydride, stir under nitrogen for 5 minutes, and then add 1 part of 2, 4,6-triaminopyrimidine was stirred for 24 hours;
[0037] (2) heating the obtained solution to 150°C, adding xylene and water azeotropically to remove the water produced, after cooling, washing the solution with ethanol...
Embodiment 3
[0043] A high-strength environmentally friendly wood board adhesive is prepared from the following raw materials in parts by weight: 50 parts of toluene diisocyanate, 15 parts of hydroxyl terminated ethylene oxide-tetrahydrofuran copolyether, 10 parts of modified polyimide, fluorine-containing polyether 90 parts of ether glycol, 2 parts of dibutyltin dilaurate, 0.5 part of boron trifluoride triethanolamine complex, tetrakis[beta-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] 0.3 part of pentaerythritol ester and 0.3 part of antioxidant.
[0044] The modified polyimide is prepared by the following steps:
[0045] (1) Mix 51 parts of N,N-dimethylacetamide and 7 parts of 3,3',4,4'-biphenyltetracarboxylic dianhydride, stir under nitrogen for 10 minutes, and then add 2 parts of 2, 4,6-triaminopyrimidine was stirred for 48 hours;
[0046] (2) heating the obtained solution to 160° C., adding xylene and water azeotropically to remove the generated water, after cooling, washing the...
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