Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Synergistic scale-inhibiting heavy metal remover as well as preparation method and application thereof

A technology for removing agents and heavy metals, applied in descaling and water softening, chemical instruments and methods, gaseous discharge wastewater treatment, etc., can solve problems such as environmental hazards, strong water solubility, ecological environment damage, etc. The effect of mass production and low process requirements

Pending Publication Date: 2021-12-21
北京可林维尔化工有限公司
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the boiler has improved production efficiency, the flue gas discharged during the use of the boiler contains a large amount of sulfur dioxide and dust, which has caused great damage to the ecological environment. By installing a desulfurization device at the tail of the flue gas and adding an alkaline desulfurizer Remove the above pollutants
The treatment of boiler flue gas is a hot topic nowadays. Although the boiler flue gas treatment system is put into operation, metal ions and other dust in the flue gas, especially calcium and magnesium ions, will be in the boiler flue gas wet desulfurization treatment system. The fouling problem in the pipes, trays, tower walls and nozzles in the desulfurization system is becoming more and more serious. The flue gas treatment system often needs to stop running in one or two months. The fouling in the treatment system brings huge costs and losses
In addition, the flue gas dust contains a large amount of heavy metals, which are highly soluble in water and cause great harm to the environment after sewage discharge.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Synergistic scale-inhibiting heavy metal remover as well as preparation method and application thereof
  • Synergistic scale-inhibiting heavy metal remover as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0054] The present invention also provides a preparation method of the remover, comprising the following steps:

[0055] (1) the composite chelating agent is mixed with the first part of water to obtain the mixed system A;

[0056] (2) Mix the synergist with the remaining water to obtain the mixed system B;

[0057] (3) mixing the mixed system A and the mixed system B to obtain the system C;

[0058] (4) Mix the system C and the dispersant to obtain the synergistic scale and anti-heavy metal remover.

[0059] In the present invention, the mass of the first part of water in the step (1) is preferably 40-60% of the water mass, more preferably 45-55%, more preferably 48-52%.

[0060] In the present invention, the mixing temperature in the step (1) is preferably 30-50°C, more preferably 35-45°C, more preferably 38-42°C; the mixing method is preferably stirring, and the stirring The rotating speed is preferably 150-200rpm, more preferably 160-190rpm, more preferably 170-180rpm; th...

Embodiment 1

[0068] Take by weighing 23 parts of polyaspartic acid / furfuryl amine graft copolymers, 18 parts of aminotrimethylene phosphoric acid, 17 parts of ethylene glycol bis(2-aminoethyl ether) tetraacetic acid, 10 parts of carboxymethyl cellulose, 8 parts of polydopamine and 8 parts of ammonium polyphosphate obtain complex chelating agent.

[0069] Take by weighing 10 parts of sodium thiosulfate, 10 parts of sodium dimethyldithiocarbamate, 5 parts of sodium diethyldithiocarbamate, 6 parts of trisodium thiocyanate and 10 parts of ammonium chloride to obtain a synergist .

[0070] Weigh 12 parts of polymaleic acid, 6 parts of acrylic acid / itaconic acid copolymer and 5 parts of acrylic acid / hydroxypropyl acrylate / sodium ethylene sulfonate to obtain a dispersant.

[0071] Control the mass ratio of complex chelating agent, synergist, dispersant and water to 12:22:8:25.

[0072] Prepare the remover by the following steps: mix the complex chelating agent with 50% water, control the temper...

Embodiment 2

[0078] Take by weighing 20 parts of polyaspartic acid / furfuryl amine graft copolymers, 16 parts of aminotrimethylene phosphoric acid, 18 parts of ethylene glycol bis(2-aminoethyl ether) tetraacetic acid, 9 parts of carboxymethyl cellulose, 6 parts of polydopamine and 7.5 parts of ammonium polyphosphate obtain complex chelating agent.

[0079] Take by weighing 12 parts of sodium thiosulfate, 5 parts of sodium dimethyldithiocarbamate, 8 parts of sodium diethyldithiocarbamate, 6 parts of trisodium thiocyanate and 7 parts of ammonium chloride to obtain a synergist .

[0080] Weigh 10 parts of polymaleic acid, 8 parts of acrylic acid / itaconic acid copolymer and 7 parts of acrylic acid / hydroxypropyl acrylate / sodium ethylene sulfonate to obtain a dispersant.

[0081] Control the mass ratio of complex chelating agent, synergist, dispersant and water to 11:23:9:30.

[0082] Prepare the remover by the following steps: mix the complex chelating agent with 40% water, control the tempera...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention belongs to the technical field of scale inhibition of metal salt compounds. The invention provides a synergistic scale-inhibiting heavy metal remover, the mass ratio of a composite chelating agent to a synergist to a dispersant to water is (10-15): (20-25): (5-10): (20-30), in the synergistic scale-inhibiting heavy metal remover, calcium, magnesium, chromium, cadmium, lead, nickel, copper and mercury in slurry after flue gas desulfurization are chelated through the chelation of the composite chelating agent, and metal compounds are prevented from being deposited on a desulfurization slurry circulating pipeline and a nozzle to influence the desulfurization effect; the synergist improves the capacity of the chelating agent, and meanwhile, the synergist and the chelating agent jointly act to remove metal ions, so that the content of the metal ions is reduced; and the dispersant has a dispersing effect, the whole system is not easy to settle, and the dispersant can be combined with metal ions to prevent generation of scale samples. The heavy metals in the slurry are chelated into insoluble substances, and then the heavy metals deposited in the solid are removed together after the slurry is dehydrated, so that the pollution to the environment is prevented.

Description

technical field [0001] The invention relates to the technical field of scale inhibition of metal salt compounds, in particular to a synergistic scale inhibition heavy metal remover and its preparation method and application. Background technique [0002] Boilers are common production equipment in production and life, and are often used in thermal power plants, smelting, petroleum, chemical, pharmaceutical and other enterprises. Although the boiler has improved production efficiency, the flue gas discharged during the use of the boiler contains a large amount of sulfur dioxide and dust, which has caused great damage to the ecological environment. By installing a desulfurization device at the tail of the flue gas and adding an alkaline desulfurizer Remove the above pollutants. The treatment of boiler flue gas is a hot topic nowadays. Although the boiler flue gas treatment system is put into operation, metal ions and other dust in the flue gas, especially calcium and magnesium...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C02F5/14C02F103/18
CPCC02F5/145C02F2101/22C02F2101/20C02F2103/18
Inventor 王学博王方园
Owner 北京可林维尔化工有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products