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High-flame-retardancy multi-axial carbon fiber warp knitting fabric, preparation method and equipment

A technology of warp knitted fabrics and carbon fibers, which is applied in the direction of flame retardant fibers, carbon fibers, warp knitting, etc., can solve the problems of low content of flame retardants at the end, uneven flame retardancy of parts, and high content of flame retardants at the front end, etc. Achieve the effect of improving flame retardant performance, improving flame retardant grade, and easier combination

Pending Publication Date: 2022-05-13
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since RTM is generally made of relatively dense carbon fiber fabric as a reinforcing material, the inorganic flame retardant additives are often blocked by the fabric when the resin is injected, resulting in a high content of flame retardants at the front end and a low content of flame retardants at the end, which makes the parts resistant to corrosion. non-uniform combustion

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • High-flame-retardancy multi-axial carbon fiber warp knitting fabric, preparation method and equipment

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A highly flame-resistant multi-axial carbon fiber warp-knitted fabric, including multiple carbon fiber layers and flame retardant powder uniformly attached to each carbon fiber layer, the flame retardant powder adheres to the carbon fiber layer and passes through the seam The weaving process is fixed.

[0023] Wherein, the powder is a solid flame retardant powder, including but not limited to halogen-based, organic phosphorus-based, nitrogen-based, silicon-based, antimony-based, aluminum-magnesium-based, inorganic phosphorus-based, boron-based, molybdenum-based, tin-based and their complex systems.

[0024] Further, the complex system includes but not limited to polybrominated diphenyl ether, tribromophenol, brominated bisphenol A, DOPO and its derivatives, melamine and its salts, red phosphorus, polyphosphate, aluminum hydroxide, Magnesium hydroxide, antimony trioxide, antimony pentoxide, zinc borate, molybdenum oxide.

Embodiment 2

[0026] A kind of equipment for preparing aforementioned carbon fiber warp knitted fabric, see figure 1 , the equipment includes an upstream creel 1, multiple sets of yarn supply assemblies, a plurality of spray pipes with the same number as the yarn supply assemblies, the second yarn spreading console 11, a feed tank 15, a feed pump 16, a circulation pump 17, a feed Pipe 18, pressure roller 19, liquid receiving tank 20, infrared drying box 21, infrared exhaust air 22, hot air drying oven 23, hot air drying exhaust air 24, braiding machine head 25 and winding machine 26, said upstream creel 1 and The silk spreading console 11 is arranged upstream of the silk spreading platform (i.e. the smuggling platform), a stirring head is arranged in the feed tank 15, and a circulation pump 17 is arranged on the tank body of the feed tank 15; the bottom of the feed tank 15 passes through The feed pipe 18 is connected with the feed pump 16; the end of the feed pipe 18 is provided with a plur...

Embodiment 3

[0029] A method for preparing a highly flame-resistant multi-axial carbon fiber warp-knitted fabric by using the aforementioned equipment, the method includes the following steps.

[0030] a, preparing the flame retardant powder into an inorganic flame retardant powder suspension;

[0031] b, introducing the inorganic flame retardant powder suspension into the feed tank;

[0032] c. Spray the suspension on the surface of the carbon fiber through the spray pipe after the carbon fiber weft laying;

[0033] d, the carbon fiber moves forward, and after laying the weft, use the pressure roller to remove the excess water and evenly disperse the inorganic flame retardant powder to the carbon fiber layer;

[0034] e, drying, using infrared drying;

[0035] f, sewing;

[0036] g, continue to use hot air to dry the residual moisture;

[0037] h, rewinding.

[0038] Wherein, in step c, according to the fabric structure, the suspension is sprayed between several layers of fabrics from ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a high-flame-retardance multi-axial carbon fiber warp knitting fabric, a preparation method and equipment, the fabric comprises a plurality of carbon fiber layers and flame retardant powder evenly attached to the carbon fiber layers, and the flame retardant powder is attached to the carbon fiber layers and fixed through a stitch bonding process. The flame retardant property of the RTM part is improved by adding a flame retardant additive in the carbon fiber warp knitting process, the additive is a mixture of aluminum hydroxide and magnesium hydroxide as a main component, and in the adding process, the additive is firstly prepared into a suspension containing an aluminate coupling agent, so that the suspension is more easily combined with the carbon fiber, and the flame retardant property of the RTM part is improved. Therefore, the non-uniform flame-retardant effect caused by dispersion in the resin injection process is avoided. The carbon fiber fabric woven by the process can be used for RTM, vacuum infusion and other composite material forming processes, and the flame retardant grade of a final workpiece can be remarkably improved when the carbon fiber fabric is used in cooperation with flame retardant resin.

Description

technical field [0001] The invention belongs to the technical field of flame-retardant composite material manufacturing, and in particular relates to a highly flame-retardant multiaxial carbon fiber warp-knitted fabric, a preparation method and equipment. Background technique [0002] RTM (Resin Transfer Molding) is the fastest-growing composite material molding process. This process has the advantages of excellent product surface quality, high precision, low void ratio, and the ability to form complex components. Wide range of applications. The Japan Reinforced Plastics Association recommends the RTM process and the pultrusion process together as the two most promising composite molding processes in the 21st century. However, the resin matrix used in it has a fatal disadvantage as a polymer organic material, that is, it is flammable and produces a large amount of harmful gas and smoke when burned. Due to the dense population and airtight space in the field of rail transit...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D04B21/00D06M13/165D06M13/156D06M13/285D06M13/364D06M11/69D06M11/72D06M11/45D06M11/44D06M11/47D06M11/48D06M11/82D06M15/55D06M17/00D06B1/02D06B23/20D06B15/00D06B15/09D06M101/40
CPCD04B21/00D06M13/165D06M13/156D06M13/285D06M13/364D06M11/69D06M11/72D06M11/45D06M11/44D06M11/47D06M11/48D06M11/82D06M15/55D06M17/00D06B1/02D06B23/20D06B15/00D06B15/09D06B23/205D06M2200/30D06M2101/40D10B2101/12
Inventor 黄胜德季春晓蔡莺莺张红卫邓文彬
Owner CHINA PETROLEUM & CHEM CORP