The invention brings forward a tooth whitening instrument system. The system comprises a tooth whitening instrument, the tooth whitening instrument comprises a housing, a cold-light emitting apparatus inside the housing and a tooth mold arranged on the housing, wherein the tooth mold is an elastomer with a concave arc-shaped bent surface, the housing is provided with a charging port, and the charging port can charge the tooth whitening instrument through a mobile phone. According to the invention, the tooth whitening instrument is designed to be a portable apparatus, the housing of the whitening instrument is provided with the charging port matching the data line of the mobile phone, a client is enabled to whiten their teeth at any time at any place, the tooth whitening cost of a user is greatly decreased, consumption of the client using a household type tooth whitening instrument is equivalent to one tenth of the consumption of tooth whitening in a dentistal hospital once, the concave arc-shaped tooth mold matches the form of a tooth mandibular arch completely, a light source is enabled to maintain an optimal irradiation angle and an optimal distance with teeth, and application is facilitated.