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SEBS thermoplastic elastomer cable insulation material and preparation method thereof

A thermoplastic elastomer, cable insulation technology, used in plastic/resin/wax insulators, organic insulators, etc., can solve the problems of easy scorch, less localized products, complicated process flow, etc., and achieve excellent heat resistance and weather resistance. , the effect of significant economic and social benefits and broad market prospects

Active Publication Date: 2010-09-22
东莞市高能高分子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. Inherent weaknesses in rubber mixing and processing: ① A large amount of reinforcing agents such as carbon black and white carbon black are used in the mixing process, which will cause serious dust pollution; without reinforcing agents, the strength of the mixed rubber will not meet the requirements , or even fail to produce qualified products; ②The rubber mixing equipment system is huge, the production process is complicated, the energy consumption is large, and the noise pollution is serious; ③High temperature (140~180°C) mixing and vulcanization process escapes a large amount of mist and smoke, which affects the operation The physical and mental health of personnel is harmful to the environment; ④ It is difficult to recycle used waste rubber and leftover materials, and they cannot be decomposed naturally, forming a major social hazard; ⑤ It is difficult to realize complete mechanization and automation of the process
[0005] 2. Problems in the production process of rubber cables: ① As a key process, the vulcanization process needs to be carried out through high-temperature and high-pressure media in vulcanization pipes or vulcanization tanks. High safety production requirements; ②The storage time of the mixed rubber is short, it is easy to scorch, and it fluctuates with the temperature change, which is difficult to master; Cable manufacturers are unable to produce
It can be used in the production of various flexible electric wires; however, the current production cost is high, the degree of crosslinking is difficult to control, the leftover materials cannot be recycled, and there are few domestically produced products, and EPDM, one of the main raw materials, mainly relies on imports

Method used

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  • SEBS thermoplastic elastomer cable insulation material and preparation method thereof
  • SEBS thermoplastic elastomer cable insulation material and preparation method thereof

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preparation example Construction

[0052] The invention also discloses the preparation method of the above-mentioned SEBS thermoplastic elastomer cable insulating material, and the process flow chart is as follows: figure 1 described, including the following steps:

[0053] Weighing raw materials: Weigh 100 parts of raw material SEBS resin, 50-150 parts of rubber filler oil, 10-50 parts of graft modified SEBS, 50-80 parts of polypropylene, 15-30 parts of polyolefin elastomer, 100-200 parts of mineral filler parts, lubricants 2~5 parts, anti-aging agent 2~4 parts, copper ion inhibitor 1.8~3 parts.

[0054] Mixing: Make the SEBS resin fully absorb the rubber filler oil, or optionally surface-treated the mineral filler, and then add it to the mixer together with other components and mix well.

[0055] Granulation: kneading with an internal mixer, extruding and granulating with a single-screw extruder with forced feeding, and finally drying and packaging.

[0056] Preferably, in the granulation step, the internal...

Embodiment 1

[0059] Weighing raw materials: weigh 100 parts by weight of high molecular weight SEBS resin, 125 parts by weight of paraffin-based rubber oil, 35 parts by weight of maleic anhydride grafted SEBS, 72 parts by weight of copolymerized polypropylene, 21 parts of EPDM rubber, 150 parts of calcined kaolin parts, 1 part by weight of ethylene bis-stearic acid amide, 1 part by weight of zinc stearate, 1 part by weight of polyethylene wax, tetrakis[beta-3-(3,5-di-tert-butyl-4-hydroxyphenyl) Propionic acid] 1.5 parts by weight of pentaerythritol, 1 part by weight of bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite, 1.2 parts by weight of N-salicylaminophthalimide, N,N' -1.0 part by weight of bis[beta(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl]hydrazide.

[0060] Mixing: Make the SEBS resin completely absorb the paraffin-based rubber oil, then add it together with the maleic anhydride grafted SEBS and other components into the mixer and mix it evenly.

[0061] Granulation: knea...

Embodiment 2

[0065] Weigh the raw materials: Weigh the raw materials according to the predetermined weight parts: 50 parts by weight of high molecular weight SEBS resin, 50 parts by weight of low molecular weight SEBS resin, 150 parts by weight of naphthenic rubber oil, 10 parts by weight of acrylic acid grafted SEBS, homopolymeric polymer 50 parts by weight of propylene, 30 parts by weight of EPDM rubber, 100 parts by weight of silk powder, 100 parts by weight of muscovite powder, 1.5 parts by weight of ethylene bisoleamide, 1.5 parts by weight of calcium stearate, 1 weight part of PE wax parts, 1 part by weight of dimethicone, 1 part by weight of octadecyl β(4-hydroxy-3,5-di-tert-butylphenyl)propionate, 1 part by weight of tris(2,4-di-tert-butylphenyl)idene 1 part by weight of phosphoric acid ester and 1.8 part by weight of N-salicylamidophthalimide.

[0066] Mixing: First make the SEBS resin completely absorb the naphthenic rubber oil, then add it together with the acrylic grafted SEBS ...

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Abstract

The invention discloses an SEBS thermoplastic elastomer cable insulation material which comprises the following components in parts by weight: 100 parts of SEBS resin, 50 to 150 parts of rubber filling oil, 10 to 50 parts of grafting modified SEBS, 50 to 80 parts of polypropylene, 15 to 30 parts of polyolefin elastomer, 100 to 200 parts of mineral filler, 2 to 5 parts of lubricant, 2 to 4 parts of anti-aging agent and 1.8 to 3 parts of copper ion inhibitor. The invention also provides a preparation method of the SEBS thermoplastic elastomer cable insulation material, which comprises the following steps: raw material weighing, mixing and granulation. The SEBS thermoplastic elastomer cable insulation material has excellent electrical insulation performance as well as good mechanical performance and aging resistant performance, is a novel material capable of substituting soft vulcanized rubber, is used for soft cable insulation layer production, realizes the full 'vulcanization-free' of soft cable production, and is characterized by 'safety, environment protection, energy saving' and the like.

Description

technical field [0001] The invention relates to a cable insulating material and a preparation method thereof, in particular to a cable insulating material with SEBS thermoplastic elastomer as a base material and a preparation method thereof. Background technique [0002] Rubber cables are a very important category of wires and cables, mainly including: field wires and cables, industrial wires and cables for detection and mining, flexible rubber cables for mobile, electric welding machine cables, flexible cables for submersible motors, elevator cables, and electric locomotives. Cables, marine cables, rubber insulated control cables, rubber insulated power cables, rubber insulated fixed laying cables, etc. The total annual output value of my country's rubber cable industry is about 15 billion yuan, and more than 250,000 tons of mixed rubber are used, with a value of 4 to 5 billion yuan. [0003] The production of rubber cables faces the following main problems: [0004] 1. I...

Claims

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Application Information

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IPC IPC(8): C08L53/02C08L91/00C08L51/00C08L23/12C08L23/14C08L23/16C08L23/08C08K13/02C08K3/34B29C47/92H01B3/44B29C48/92
CPCB29C48/04B29C48/397B29C48/875B29C48/92B29C2948/92704B29C2948/92895B29C2948/92904
Inventor 肖望东饶长全徐令军林峰
Owner 东莞市高能高分子材料有限公司
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