The invention discloses a hemostatic material for war wounds as well as a preparation method and an application thereof, which relate to the technical field of biomedical materials, and the hemostaticmaterial is characterized by comprising an electrostatic spinning outer membrane and hydrogel applied to the surface of the electrostatic spinning outer membrane, and the components of the electrostatic spinning outer membrane and the hydrogel are respectively one of PEG-NHS (polyethylene glycol-succinimide ester) or PEG-NH2 (polyethylene glycol amino). The preparation method comprises the following steps: 1) preparing preparation materials; 2) preparing the electrostatic spinning outer membrane; and 3) preparing the hydrogel. The hemostatic material is a hemostatic product applied to trauma,wound, thoracic cavity and abdominal cavity operations or internal organs and vascular bleeding. The hemostatic material has the properties of rapid coagulation hemostasis, moisture retention, bacteriostasis, tissue repair promotion, high mechanical strength, strong wound adhesion and the like, so that an efficient and convenient self-rescue and mutual-rescue material can be provided for war wound wounded persons, the death rate is conveniently reduced, and the war wound treatment level is improved.