The invention discloses a six-membered ring structured
fluorine-containing carbonic ester
solvent. The structure of six-membered ring structured
fluorine-containing carbonic ester
solvent is more stable. In addition, as two
fluorocarbon groups can be introduced on the
side chain, the
fluorine content in the molecules is high, and better
flame resistance and low-temperature performance can be obtained. The invention also provides a preparation method of the fluorine-containing carbonic ester
solvent. According to the preparation method, a high-efficiency catalyst is used and the product yield is high. Furthermore, the invention provides an
electrolyte for
lithium ion batteries. The
electrolyte contains the above fluorine-containing carbonic ester solvent and
electrolyte salt, and also comprises a non-
fluoride solvent and / or a fluorine-containing additive. The fluorine-containing carbonic ester solvent can be used to effectively improve homogeneity and
flame resistance of the electrolyte and raise high-temperature stability of batteries. The solvent has lower low-temperature
viscosity such that low-temperature performance of batteries is better. As the
surface tension of the fluorine-containing carbonic ester solvent is low, wetability between the electrolyte and an
electrode material can be improved, and furthermore, electrochemical performance of batteries can be optimized.