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Biomimetic silicification enhanced catalysts, methods of making and using the same

A biomimetic silicification-enhanced catalyst and its preparation method are disclosed. The preparation method includes the following steps: S1: Urea, iron salt, and copper salt are added to a first solvent to obtain a mixed solution; S2: The mixed solution undergoes a hydrothermal reflux reaction to obtain particle units; S3: The particle units undergo a silicification reaction with ammonia and a silica precursor to obtain a catalyst. The catalyst prepared by this method can not only reduce its band gap by copper doping to utilize visible light as a reaction light source and reduce reaction conditions, but also inhibit the aggregation of catalyst particles by utilizing the mesoporous silica layer on the surface, expose more reaction sites, and limit the heat loss of the internal particle units, thereby increasing the reaction temperature. This can effectively improve the organic matter treatment effect of the catalyst. It adsorbs and degrades dyes in wastewater through two modes: electrostatic attraction and catalytic decomposition of hydrogen peroxide to generate strong oxidizing free radicals.
Owner:SICHUAN UNIV