Single dye type bright acidic copper plating additive and preparation method and application thereof

An acidic copper plating and additive technology, applied in the field of copper plating additives, can solve the problems of insufficient fineness of the high and middle areas of the coating, the influence of the polarization of the plating solution, and increase the production cost, etc., and achieve excellent deep plating ability and good filling and leveling performance of the coating , easy to manage the effect
CN101899687AInactive Publication Date: 2010-12-01济南德锡科技有限公司

Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
济南德锡科技有限公司
Publication Date
2010-12-01
Estimated Expiration
Not applicable · inactive patent

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Abstract

The invention discloses a single dye type bright acidic copper plating additive and a preparation method and application thereof. The additive is prepared from a polymeric phenazine dye, a triphenylmethane dye, a thiazine dye, a surfactant and polysulfide serving as main raw materials; when the additive is applied to copper plating solution for copper plating, the using effect can reach that of a three-dose additive; the entire plated sheet is bright; the additive is simple to manage and the maladjustment of the plating solution additive is not caused; and even if the concentration of the additive is over-high, the plating solution can be continuously used after the plating solution is slightly diluted.
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Description

technical field

[0001] The invention relates to a copper plating additive, in particular to a single-dose dye type bright acidic copper plating additive. Background technique

[0002] Due to the good toughness of the coating, the plating solution has good bright leveling and fast deposition speed. It is used in plastic electroplating, metal copper-nickel-chromium decorative electroplating, metallization electroplating of printing plate holes and electroforming. occupies an important position.

[0003] Research on acidic copper plating additives by major companies around the world began in the 1950s, and foreign research has successfully added sulfur- and nitrogen-containing compounds, such as thiourea and its derivatives, 2-mercaptobenzothiazole, 2-mercaptobenzothiazole Some dyes such as imidazole and basic saffron, thiazapine, triphenylmethane, etc., may have a brighter coating; in the 1960s, some additives such as polyether were added to make the brightness, leveling abil...

Claims

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