Method for treating lignocellulose raw material through steam explosion and producing biogas, cellulose and lignin simultaneously

A lignocellulose and cellulose technology, which is applied in the field of steam explosion treatment of biomass raw materials and steam explosion treatment of lignocellulose raw materials, can solve the problems of difficulty in generating economic benefits, complicated straws, and long gas production cycle, and is suitable for industrial use. management and operation, efficient separation methods, and the effect of shortening the fermentation cycle

Inactive Publication Date: 2011-05-11
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the traditional utilization of lignocellulosic raw materials often only aims to use a single component to produce a single product, and the rest of the components are used at low value or even treated as waste. Pollution. For example, the paper industry only uses cellulose components. The production process aims to obtain high-quality cellulose. During the production process, hemicellulose and lignin are severely damaged, which not only cannot be used for high-value use, but also causes environmental pollution.
The biogas fermentation of lignocellulosic raw materials has received extensive attention, but it is not successful at present, and has suffered serious setbacks in engineering practice. The main problems are as follows: 1. The cellulose, hemicellulose and lignin of raw materials are closely combined , is difficult to be degraded by microorganisms, resulting in long gas production cycle and low efficiency; 2. The raw materials are easy to float on the feed liquid and cannot fully contact with the microorganisms, slowing down the reaction speed. At the same time, the crust of the floating raw materials prevents the biogas from escaping in time; 3. Most of them are fermented in traditional cellar pools, and the fermentation temperature and gas production rate cannot be controlled, resulting in an embarrassing situation where more gas is produced in summer and little or no gas is produced in winter
However, these processes use the whole lignocellulosic raw material as the raw material for biogas fermentation instead of using each component separat...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Cut corn stalks into lengths of 3-10cm, put them into a steam explosion tank for steam explosion treatment, the steam explosion condition is 1.4MPa, and maintain pressure for 5min; After washing with water, use the method of plate and frame separation for solid-liquid separation; the separated liquid with a total sugar concentration of 0.9% is acidified and anaerobically fermented at 35-55°C to produce biogas with a methane content of 65-75% by volume. H 2 S content below 100mg / m 3 The steam-exploded corn stalk solid material obtained by solid-liquid separation was treated with 0.2% sodium hydroxide solution at 105°C for 2 hours, and then separated from cellulose and lignin liquid through a chamber filter press, and the lignin liquid was ultrafiltered The system is purified, and the lignin is precipitated after acid analysis, and finally separated and dried to obtain the finished lignin with a purity of 89%; after the lye extraction, the separated solid is washed with ...

Embodiment 2

[0044] Cut the raw material of wheat straw into a length of 5-13cm, put it into a steam explosion tank for steam explosion treatment, the steam explosion condition is 1.5MPa, and maintain the pressure for 4min; after the steam explosion treatment, the corn straw material is washed with 10 times (W / W) water The solid-liquid separation is carried out by the method of plate and frame separation; the separated liquid with a total sugar concentration of 1.8% is acidified and anaerobically fermented at 35-55°C to produce biogas with a methane content of 65%-75% by volume. h 2 S content below 90mg / m 3 ; The steam-exploded corn stalk solid material obtained by solid-liquid separation was treated with 2% sodium hydroxide solution at 115°C for 2 hours, and then separated from cellulose and lignin liquid through a chamber filter press, and the lignin liquid was ultrafiltered The system is purified, the lignin is precipitated after acid analysis, and finally separated and dried to obtain...

Embodiment 3

[0046] Cut the raw corn stalks into lengths of 5-10 cm, put them into a steam explosion tank for steam explosion treatment, the steam explosion conditions are 1.6MPa, and maintain the pressure for 2 minutes; after the steam explosion treatment, the corn stalks are washed with 15 times (W / W) water The solid-liquid separation is carried out by the method of plate and frame separation; the separated liquid with a total sugar concentration of 2.3% is acidified and anaerobically fermented at 45°C to produce biogas with a methane content of 65%-75% by volume, and the H in the biogas 2 S content below 100mg / m 3 The steam-exploded corn stalk solid material that solid-liquid separation obtains is divided into long fiber and short fiber with the method for mechanical separation, and the weight ratio of long and short fiber is 4: 6, and short fiber uses 0.9% sodium hydroxide solution at 90 ℃ After treatment for 3 hours, the cellulose and lignin liquid are separated by a chamber filter pr...

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PUM

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Abstract

The invention relates to a method for treating lignocellulose raw material through steam explosion and producing biogas, cellulose and lignin simultaneously. The traditional utilization of the lignocellulose raw material only uses a single component and aims to produce a single product, thus the function of each component can not realized and the economic benefit is low. The method in the invention uses the steam explosion technology as a core, wherein hemicellulose, cellulose and lignin are separated from the lignocellulose raw material for high-value use. The method comprises the following steps: performing steam explosion on the lignocellulose raw material; degrading hemicellulose to soluble sugar; extracting soluble sugar with water for biogas fermentation, wherein lignin and cellulose are easy to separate when hemicellulose is removed; extracting high-concentration lignin with low concentration base; and leaving high concentration cellulose when hemicellulose and lignin are removed. The biogas produced by the method has low sulfur content and can be directly used; the extracted lignin can be used to produce resins, adhesives, rubber industry additives and the like; cellulose can be used for papermaking and preparing products such as polyol, carboxymethyl cellulose, cellulose acetate and textile fibre. By adopting the method in the invention, the biomass of lignocellulose can be completely utilized and no pollutant is discharged; and the method is easy for industrialization operation.

Description

technical field [0001] The invention relates to a method for steam explosion treatment of biomass raw materials, in particular to a method for steam explosion treatment of lignocellulosic raw materials, belonging to the field of biochemical engineering. Background technique [0002] Lignocellulosic raw material is a huge renewable resource, mainly composed of hemicellulose, cellulose and lignin, each component has a wide range of uses: hemicellulose is a collection of pentose and hexose, after degradation It can be used by microorganisms to produce various fermentation products, such as biogas, oil, butanol, ethanol, etc., and can also produce furfural, xylo-oligosaccharides and other products; cellulose is a high polymer composed of glucose units, which is degraded into glucose. It can be used as a carbon source for microbial fermentation to produce various fermented products, such as lactic acid, oil, butanol, ethanol, etc. At the same time, cellulose itself is a polymer m...

Claims

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Application Information

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IPC IPC(8): C12P5/02C12P19/04
CPCY02E50/30
Inventor 陈洪章彭小伟
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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