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A stainless heat-resistant self-shielded flux-cored wire for magnesium smelting reduction tank

A technology of flux-cored welding wire and reducing tank, which is applied in the welding of reducing tanks for magnesium smelting, and in the field of stainless heat-resistant self-protecting flux-cored welding wire, which can solve the problems of scrapping the reducing tank, high welding current, and high labor intensity of workers. Achieve the effects of improving oxidation resistance and corrosion resistance, reducing the occurrence of welding defects, and improving the quality of welded joints

Active Publication Date: 2017-03-01
BEIJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When submerged arc welding wire is used, the heat input is large, and the slag after welding is easy to form a spinel structure, which sticks to the weld and is not easy to remove, resulting in low welding efficiency and high labor intensity
Due to the large welding current used by submerged arc welding wire, it is only suitable for flat welding and fillet welding positions. Although the connection between the head of the reducing tank and the tank body can be realized, it cannot complete the wall thickness of the small diameter tank and the thin wall of the large diameter tank. Welding of components
For some vertical welding positions and horizontal welding positions, submerged arc welding wire cannot be used, which restricts the application of submerged arc welding materials
[0009] Using the above-mentioned traditional austenitic stainless steel electrodes and submerged arc welding wires, because such welding materials do not match the material of the reduction tank body, the durability of the welded joints and the resistance to sulfidation corrosion are poor, so that the base metal of the reduction tank during use The welding seam has been corroded when it is intact, which leads to the scrapping of the reduction tank
In addition, because the welding joints of the reduction tank are subjected to high pressure, high temperature oxidation and gas erosion, it is easy to cause creep, thermoplastic deformation, cracking, sulfidation corrosion and peeling of the welded joints.
Especially when used in high temperature and sulfur-containing medium, the welding seam between the reduction tank body and the head is easy to peel off from the outside first, forming a dent or air leakage, resulting in a low service life of the reduction tank, even less than three months , has seriously affected the output of magnesium cans and the efficiency of magnesium smelting
[0010] The price of the reduction tank for magnesium smelting is high, and the number of replacements is large. In addition, in the production process, multiple reduction tanks are often working at the same time. If a single reduction tank has welding quality problems and cannot be repaired or replaced in time, it will lead to production stoppage and huge losses. economic loss
The lack of welding materials for high-quality, high-efficiency and automated magnesium-smelting reduction tanks severely restricts the application of magnesium-smelting reduction tanks

Method used

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  • A stainless heat-resistant self-shielded flux-cored wire for magnesium smelting reduction tank
  • A stainless heat-resistant self-shielded flux-cored wire for magnesium smelting reduction tank
  • A stainless heat-resistant self-shielded flux-cored wire for magnesium smelting reduction tank

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Embodiment 1. A SUS304L stainless steel strip of 8×0.25 (8mm in width and 0.25mm in thickness) is selected, and the filling rate is 15%. After drawing and reducing the diameter, a welding wire with a diameter of 1.2 mm is obtained.

[0037] The mass percentage of each alloy composition in the powder core is: the mass percentage of rutile is 8%, the mass percentage of sodium carbonate is 0.8%, the mass percentage of feldspar is 4%, the compound fluoride (20% BaF 2 -8%LiF 2 -10%MgF2-62CaF 2 , the mass percentage that has supplemented in front) is 6%, the mass percentage of chromium is 35%, the mass percentage of nickel is 12%, the mass percentage of manganese is 4%, the mass percentage of molybdenum is 6%, the mass percentage of chromium nitride The percentage is 1%, the mass percentage of aluminum-magnesium alloy is 6%, the mass percentage of mixed rare earth is 6%, and the balance is reduced iron. The welding current used during welding is 130A, and the welding volta...

Embodiment 2

[0038] Embodiment 2. A 10×0.4 (10 mm in width and 0.4 mm in thickness) SUS304L stainless steel strip is selected, and the filling rate is 20%. After drawing and reducing the diameter, a welding wire with a diameter of 1.4mm is obtained.

[0039] The mass percentage of each alloy composition in the powder core is: the mass percentage of rutile is 9%, the mass percentage of sodium carbonate is 0.6%, the mass percentage of feldspar is 8%, the compound fluoride (20% BaF 2 -8%LiF 2 -10%MgF2-62CaF 2 ) is 8% by mass, 36% by mass of chromium, 8% by mass of nickel, 5% by mass of manganese, 4% by mass of molybdenum, and 2% by mass of chromium nitride, The mass percentage of the aluminum-magnesium alloy is 4%, the mass percentage of the mixed rare earth is 5%, and the balance is reduced iron. The welding current used during welding is 160A, and the welding voltage is 26V.

Embodiment 3

[0040] Embodiment 3. 8×0.3 (8 mm in width and 0.3 mm in thickness) SUS304L stainless steel strips are selected, and the filling rate is 22%. After drawing and reducing the diameter, a welding wire with a diameter of 1.2 mm is obtained.

[0041] The mass percentage of each alloy composition in the powder core is: the mass percentage of rutile is 10%, the mass percentage of sodium carbonate is 2.3%, the mass percentage of feldspar is 6%, the compound fluoride (20% BaF 2 -8%LiF 2 -10%MgF2-62CaF 2 ) is 9% by mass, 34% by mass of chromium, 11.7% by mass of nickel, 4% by mass of manganese, 10% by mass of molybdenum, and 3% by mass of chromium nitride, The mass percentage of the aluminum-magnesium alloy is 4%, the mass percentage of the mixed rare earth is 7%, and the balance is reduced iron. The welding current used during welding is 180A, and the welding voltage is 28V.

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Abstract

A stainless heat-proof self-protecting flux-cored wire for a magnesium smelting reduction tank belongs to the technical field of materials processing engineering. A normal stainless steel band 304L or common carbon steel serves as a coating layer, and alloys in a powder core are rutile, sodium carbonate, feldspar, compound fluorides, chromium, nickel, manganese, molybdenum, chromium nitride, aluminium-magnesium alloy, misch metal and iron power. Compared with a conventional stainless steel welding rod, the stainless heat-proof self-protecting flux-cored wire has the advantages that higher welding current can be used; higher welding speed can be realized; the production efficiency is improved; and the labor intensity is lowered; c. Compared with a conventional stainless steel submerged-arc welding solid wire, the stainless heat-proof self-protecting flux-cored wire has the advantages that all-position welding can be realized; the heat input is small; the slag detachability is good; and the manufacturing technique is simpler. A welded joint formed by using the stainless heat-proof self-protecting flux-cored wire provided by the invention has favorable heat resistance, oxidation resistance, vulcanization and corrosion resistance and high-temperature creep resistance compared with welded joints formed by welding the stainless steel welding rod and the stainless steel solid wire.

Description

technical field [0001] The invention belongs to the technical field of material processing engineering, and relates to a stainless heat-resistant self-protecting flux-cored welding wire, which is mainly used for welding reduction tanks for magnesium smelting. [0002] technical background [0003] Magnesium and magnesium alloys are currently the lightest structural materials in industrial applications. They have high specific strength, specific stiffness and good processing performance. In addition, they also have good thermal conductivity and electrical conductivity, damping and shock absorption, and electromagnetic shielding. Good and other characteristics, magnesium alloy is easy to process and shape, more importantly, it is easy to recycle and easy to degrade, so it is a very valuable green structural material. These characteristics of magnesium alloy make it widely used in electronic appliances, aerospace, national defense industry, automobile and other fields. [0004]...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B23K35/368B23K35/365
CPCB23K35/0266B23K35/24B23K35/3601B23K35/3605B23K35/3608B23K35/368B23K35/406
Inventor 栗卓新李国栋
Owner BEIJING UNIV OF TECH
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