Coking waste gas purification system

An exhaust gas purification system and coke oven technology, applied in coke ovens, incinerators, gas treatment and other directions, can solve the problems of high operating costs, large investment in desulfurization and denitrification, and high energy consumption for flue gas heating, and achieve efficient recovery of flue gas waste heat, The effect of reducing environmental pollution and increasing the humidity of flue gas

Active Publication Date: 2018-10-16
武汉钢铁有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing processes such as adsorption, condensation and incineration require large investment and high purification costs;
[0013] (2) The desulfurization and denitrification process of coke oven flue gas activated carbon generally requires the construction of a sulfuric acid system, which requires a large investment, and also requires the construction of an acid wastewater treatment system generated during the acid production process
The tail gas after acid production is mixed into the coke oven flue gas in front of the activated carbon desulfurization and denitrification tower, causing certain corrosion to the flue gas pipeline in the front area of ​​the tower;
[0014] (3) The coke oven flue gas SDA desulfurization process system is frequently blocked, the operation stability is poor, and the desulfurization by-products are solid wastes, which cannot be used as resources and cause secondary pollution to the environment;
[0015] (4) The existing coke oven flue gas carbon-based catalytic desulfurization combined with SCR denitrification process, although the desulfurization by-product is low-concentr

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0076] High temperature electromigration desulfurization-SCR denitrification-Claus furnace:

[0077] Such as figure 1 As shown, this embodiment discloses a coking waste gas purification system that cooperates with high-temperature electromigration desulfurization-SCR denitrification-Claus furnace process, including a coke oven 100, a coke oven horizontal flue 200, and a coke oven flue gas desulfurization and denitrification device 300 , CDQ furnace 400, chemical product storage device 500, hydrogen sulfide treatment device 600, Claus furnace 700, sulfur condenser 800 and tail gas combustion device 900, the coke oven flue gas desulfurization and denitrification device 300 includes electromigration membrane separation of sulfur dioxide device 300a and SCR denitration reactor 300b, and a heat exchanger 300e and a heater 300f are respectively arranged between the gas pipelines connected between the sulfur dioxide electromigration membrane separator 300a and the SCR denitration rea...

Embodiment 2

[0082] Activated carbon adsorption desulfurization and denitrification-Claus furnace:

[0083] Such as figure 2 As shown, this embodiment discloses a coking waste gas purification system based on activated carbon adsorption desulfurization and denitrification process, including coke oven 100, coke oven horizontal flue 200, coke oven flue gas desulfurization and denitrification device 300, CDQ furnace 400, chemical products Storage device 500, hydrogen sulfide treatment device 600, Claus furnace 700, sulfur condenser 800 and tail gas combustion device 900, said coke oven flue gas desulfurization and denitrification device 300 includes 2 , NO X and catalytic reaction NO X Adsorption reaction tower 300c, sulfur dioxide analysis tower 300d, described adsorption reaction tower 300c is provided with second flue gas inlet 300c-1, purified flue gas outlet 300c-2 and is used for carrying out the discharge of material delivery with sulfur dioxide analysis tower 300d port and feed po...

Embodiment 3

[0089] Carbon-based catalytic desulfurization to acid-SCR denitrification:

[0090] like image 3 As shown, this embodiment discloses a coking waste gas purification system for coking with carbon-based catalytic desulfurization to produce acid-SCR denitrification process, including coke oven 100, coke oven horizontal flue 200, coke oven flue gas desulfurization and denitrification device 300, CDQ Furnace 400, chemical product storage device 500 and fluidized bed dryer 1000, the coke oven flue gas desulfurization and denitrification device 300 includes 2 The desulfurization reactor 300g, the SCR denitration reactor 300b for denitration, the heat exchanger 300e and the heater 300f. The desulfurization reactor 300g includes a desulfurization acid production device 300g-1, a dilute acid tank 300g-2, a concentrated acid tank 300g-3 and a dilute acid concentration device 300g-4, and the desulfurization acid production device 300g-1 is equipped with a second 3. Flue gas inlet 300g-...

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Abstract

The invention discloses a coking waste gas purification system, which belongs to the field of energy saving and environment protection of the coking industry. The coking waste gas purification systemcomprises a coking smoke generating and processing system, a dry quenching system and a tank nitrogen sealing system, wherein the coking smoke generating and processing system comprises a coke oven, acoke oven horizontal flue and a coke oven smoke desulfurization and denitrification device; the dry quenching system comprises a dry quenching furnace; the tank nitrogen sealing system comprises a chemical product storage device; the dry quenching furnace is provided with a circulating inert gas outlet and a circulating inert gas inlet; each tank of the tank nitrogen sealing system is respectively provided with a chemical product tank gas inlet used for introducing nitrogen, and a chemical product tank gas outlet used for emitting chemical product tail gas; the circulating inert gas outlet ofthe dry quenching furnace is connected with three gas pipelines, wherein one gas pipeline is connected with the circulating inert gas inlet of the dry quenching furnace for importing circulating inert gas to cool cokes in the dry quenching furnace, another gas pipeline is connected with the chemical product tank gas outlet of the chemical product storage device for importing into spreading tail gas blow gas pipeline of the circulating inert gas, and the final gas pipeline is connected with an in-furnace gas inlet arranged on the coke oven for importing the spreading tail gas dilution coke oven combustion chamber gas of the circulating inert gas. According to the coking waste gas purification system, coking chemical product tail gas can be fully recovered and utilized, and tail gas waste heat can be effectively recovered.

Description

technical field [0001] The invention relates to the treatment of coking waste gas of a coking oven, belongs to the field of energy saving and environmental protection in the coking industry, and in particular relates to a coking waste gas purification system. Background technique [0002] The coking industry is an important part of the metallurgical industry. Its main task is to provide raw materials (fuel) such as coke and coke oven gas for iron and steel enterprises. The production process can be divided into two main production processes: coking and chemical product recovery. The coking process is completed in the coke oven. The coking oven is composed of a carbonization chamber, a combustion chamber, a regenerator, a chute area and a top area, and the base and sub-flue are below the regenerator. [0003] In the coking process, coking coal is loaded into the carbonization chamber of the coke oven by a coal loading car, heated to 950-1050°C under the condition of isolatio...

Claims

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Application Information

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IPC IPC(8): B01D53/86B01D50/00B01D53/50B01D53/56C10B39/02C10B43/00F23K5/00F23G7/06
CPCB01D50/00B01D53/002B01D53/02B01D53/1468B01D53/18B01D53/8609B01D53/8631B01D2253/102B01D2258/0283C10B39/02C10B43/00F23G7/06F23K5/002Y02P20/129
Inventor 吴高明张垒梁尚国王丽娜刘尚超刘璞
Owner 武汉钢铁有限公司
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