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Multilayer condom containing modified polyurethane raw material and preparation method of multilayer condom

A technology of polyurethane and condoms, which is applied in the direction of male contraceptives, etc., can solve the problems of unresolved natural rubber sensitization, low tolerance of oil-based lubricants, life-threatening problems, etc., and achieve excellent adhesion Adhesion performance, improvement of surface performance and water resistance, effect of improving surface performance

Active Publication Date: 2020-04-28
眉山尤博瑞新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, natural rubber latex contains many non-rubber components such as allergic water-soluble protein and other biopolymers. If the water-soluble protein in the latex exceeds a certain content, the user's skin will have allergic reactions such as erythema and itching. Many people with severe allergies There may even be life-threatening convulsions, tremors, etc.
Since the 1980s, natural rubber latex medical and sanitary products have caused frequent human allergy incidents. In the United States, it is estimated that about 17 million people are allergic to natural latex. The allergenicity of natural rubber has been warned. Later, scientists tried to reduce the allergenicity of natural rubber through various methods, but the effect has been minimal. So far, the allergenicity of natural rubber has not been well resolved. solve
On the other hand, condoms made of natural rubber also have the following disadvantages: odor, low tolerance to oil-based lubricants, and rapid loss of strength
[0010] At present, the modification of various condom film materials is still being studied, but there is still no condom that can have many advantages of the above three condoms. Can the method of modification improve the quality of condom rubber? In addition to the tensile strength of the film, it can also significantly improve its elongation at break, and can well ensure the mechanical properties and performance of the condom. Solving the defects of the existing three condom materials has become an urgent technical problem to be solved.

Method used

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  • Multilayer condom containing modified polyurethane raw material and preparation method of multilayer condom
  • Multilayer condom containing modified polyurethane raw material and preparation method of multilayer condom
  • Multilayer condom containing modified polyurethane raw material and preparation method of multilayer condom

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Synthesis of modified polyurethane chain extender:

[0048] Amino protection of lysine by tert-butoxycarbonyl group and reaction with N-N-hydroxysuccinimide in dichloromethane solvent with coupling agent EDC-HCl at room temperature for 5 h to obtain intermediate product 1, and the obtained intermediate product One reacts with dopamine hydrochloride with methanol as a solvent at normal temperature for 10 hours to obtain intermediate product two, and reacts intermediate product two with hydrochloric acid / ethyl acetate for 2 hours at normal temperature to remove the amino protecting group to obtain a modified polyurethane chain extender, the reaction formula as follows:

[0049]

[0050] The mass spectrometry data of test gained modified polyurethane chain extender is as figure 1 As shown, the H NMR spectrum is as figure 2 shown.

Embodiment 2

[0052] Synthesis of modified polyurethane:

[0053](1) React with isophorone diisocyanate, polytetrahydrofuran ether diol and hydrophilic chain extender 2,2-dimethylolpropionic acid (DMPA) according to the molar ratio of 3:2:1 to prepare modified polyurethane , denoted as PU-LDA00, its molecular weight is measured as M n =93215.

[0054] (2) React with isophorone diisocyanate, polytetrahydrofuran ether glycol, and mixed chain extender at a molar ratio of 3:2:1, wherein the mixed chain extender follows: ①Modified polyurethane chain extender and hydrophilic extender Chain agent DMPA molar ratio = 0.3:0.7; ② modified polyurethane chain extender and hydrophilic chain extender DMPA molar ratio = 0.5:0.5; prepared modified polyurethane, respectively marked as PU-LDA30, PU-LDA50, measured its The molecular weights are ①M n =108864; ②M n =112350.

[0055] The modified polyurethane emulsion obtained above was cast into a film to obtain a film with a thickness of 0.1mm, and the wat...

Embodiment 3

[0064] The synthesis of the multilayer condom containing modified polyurethane raw material, its preparation method comprises the following steps:

[0065] (1) Preparation of inner film:

[0066] In terms of solid mass percentage, it is polymerized and emulsified from the following components: 19.2% diisocyanate, 68.9% polymer diol, 6.4% polysiloxane diol, 1.67% fluorine-containing chain extender, and chain extender I1. 13%, hydrophilic chain extender 2.7%; Wherein, diisocyanate is isophorone diisocyanate (IPDI); Polymer diol is polybutylene adipate diol (PBA molecular weight 2000); Siloxane diol is dimethyl siloxane with active end group, the end group of siloxane is connected with the active terminal hydroxyl group through ether carbon chain, and its molecular weight is 2500; the fluorine-containing chain extender is a side chain fluorine-containing carbon chain Segment of dihydric alcohol, the fluorocarbon chain of the side chain is a non-perfluorocarbon chain of 5 carbons...

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Abstract

The invention provides a multilayer condom containing a modified polyurethane raw material and a preparation method of the multilayer condom. The preparation method of the condom comprises the following steps: (1) preparation of an inner-layer adhesive film: reacting polyisocyanate with a chain extender to obtain a fluorine-containing and silicon-containing polyurethane emulsion, and then forminga film to prepare the inner-layer adhesive film; (2) preparation of an intermediate layer adhesive film: blending polyisoprene rubber and a modified polyurethane emulsion to prepare the intermediate layer adhesive film; (3) preparation of an outer adhesive film: preparing rosin modified resin latex from maleated rosin through emulsion polymerization, and then blending the rosin modified resin latex with modified polyurethane emulsion and polyisoprene rubber emulsion to form a film; and (4) hemming, demolding and forming to obtain a finished product. The multilayer condom has the advantages ofno special smell, no anaphylactic reaction, high tensile strength, high elongation at break, good toughness, high resilience, good bacteriostasis effect on a plurality of common bacteria, efficient barrier performance on small molecules, good processing and production, and good application prospect.

Description

technical field [0001] The invention belongs to the technical field of contraceptive tools, and in particular relates to a multilayer condom containing modified polyurethane raw materials and a preparation method thereof. Background technique [0002] Condoms prevent conception in a non-drug form and are the most commonly used contraceptive tool in the world. According to incomplete statistics, the consumption of condoms in China is nearly 12 billion per year. At present, condoms are not only a tool for family planning, but also one of the most effective methods to prevent the spread of sexually transmitted diseases. With the rapid spread of AIDS and other sexually transmitted diseases, the situation of AIDS prevention and treatment is becoming increasingly severe, and the quality of condom products is also increasing. Gaining importance. [0003] The main raw material for the manufacture of condoms is natural rubber latex, which has always occupied a dominant position in t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/10C08G18/12C08G18/40C08G18/42C08G18/44C08G18/48C08G18/61C08G18/34C08G18/32C08F220/06C08F222/26A61F6/04
CPCA61F6/04C08F220/06C08G18/10C08G18/12C08G18/4009C08G18/4238C08G18/44C08G18/4854C08G18/61C08G18/6651C08G18/6692C08G18/348C08G18/3825C08G18/3206C08G18/3812C08G18/3857C08F222/26C08G18/3228
Inventor 叶恒刘灯旺艾婷婷张丽娜
Owner 眉山尤博瑞新材料有限公司
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