Insoluble energetic organic polymer coated micro-nano particles and preparation method thereof

A technology of micro-nano particles and polymers, applied in transportation and packaging, boron/boride, metal processing equipment, etc., can solve the problems of harsh operating conditions, risks in scale-up tests, slow decomposition, etc., and achieve good dispersion effect.

Active Publication Date: 2020-12-15
NORTHWEST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] In summary, the existing technology has the following three problems when coating the surface of micro-nanoparticles with a thin film: first, the operating conditions are harsh, and there are risks in the scale-...

Method used

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  • Insoluble energetic organic polymer coated micro-nano particles and preparation method thereof
  • Insoluble energetic organic polymer coated micro-nano particles and preparation method thereof
  • Insoluble energetic organic polymer coated micro-nano particles and preparation method thereof

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preparation example Construction

[0032] The preparation method of the insoluble energetic organic polymer coated micro-nano particles of the present invention comprises the following steps:

[0033] Step 1, first discuss in two cases: when the micro-nano particles are aluminum powder, add 30mL tetrahydrofuran into a 100mL three-neck flask, add 2g micro-nano aluminum powder; when the micro-nano particles are boron powder, add o-dichlorobenzene and dichlorobenzene Each 25ml of methyl acetamide is added into a 100mL three-necked flask, and 5g of micro-nano boron powder is added; micro-nano in the present invention refers to a particle size of 20 nanometers to 100 microns;

[0034] Use an ice-water bath to cool down the mixed system to 0-5°C, feed argon or nitrogen to prevent the aluminum powder from being oxidized, add the first monomer to the three-necked flask, the mass of the first monomer is 0.1% of the aluminum powder or boron powder ~20%, control the obtained system to 0~25℃;

[0035] The first monomer is...

Embodiment 1

[0044] Add 30ml of anhydrous tetrahydrofuran into a 100mL three-necked flask, add 2.0g of aluminum powder, cool down to 0°C in an ice-water bath, and inject nitrogen to prevent the aluminum powder from being oxidized. Add 184 mg of cyanuric chloride, and control the reaction solution to 20°C.

[0045] Under an ice-water bath environment at 0°C, dissolve 90 mg of ethylenediamine and 387.5 mg of acid-binding agent diisopropylamine in 5 ml of anhydrous tetrahydrofuran, and slowly drop them into the flask, which can dissolve faster than direct addition. React at 0°C for 1 hour under argon atmosphere, then gradually raise to reflux at 70°C, and react for 1 day.

[0046] The reaction solution was lowered to room temperature, and the product was obtained by suction filtration, rinsed with water, ethanol, and acetone successively, and dried in vacuum to obtain micro-nano aluminum particles coated with an insoluble energetic organic polymer.

[0047] from figure 1 It can be seen that...

Embodiment 2

[0049] Add 25ml each of o-dichlorobenzene and dimethylacetamide into a 100mL three-neck flask, add 5g of boron powder, cool down to 5°C in an ice-water bath, and blow in argon to prevent the boron powder from being oxidized. Add 0.42g trialdehyde phloroglucinol, and control the reaction solution to 25°C.

[0050] In an ice-water bath environment at 3°C, slowly add 0.498g of 3,3-diaminobioxadiazole, react at 5°C for 0.5h under an argon atmosphere, then gradually rise to 120°C and react for 1 day;

[0051] After the reaction liquid is cooled to room temperature, the product is obtained by suction filtration, rinsed with water, ethanol, and acetone successively, and vacuum-dried to obtain insoluble energetic organic polymer-coated micro-nano boron particles.

[0052] from Figure 5 A large number of granular micro-nano boron particles can be seen, and there are some sheet-like polymers, and a large number of large pores are evenly distributed in the sheet-shaped polymers, and th...

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Abstract

The invention discloses insoluble energetic organic polymer coated micro-nano particles and a preparation method thereof. The preparation method comprises the following steps: soaking micro-nano aluminum powder or boron powder in a solvent at low temperature, adding a first monomer and a second monomer at 0-25 DEG C, reacting for 0.5-2 hours at 0-5 DEG C in a protective gas atmosphere, reacting at50-120 DEG C to obtain a reaction solution, and carrying out nucleophilic substitution reaction on halogen and the second monomer; carrying out condensation polymerization on the aldehyde group and the second monomer, carrying out catalytic coupling reaction on the amino group and the second monomer, separating the product in the reaction solution, and performing drying to obtain the insoluble energetic organic polymer coated micro-nano particles. The energetic organic polymer coated micro-nano particles are insoluble in water and an organic solvent, so the problems of slow decomposition andpoor stability after soaking are avoided, the dispersity is good, and the problems that the surfaces of micro-nano aluminum and boron particles are easy to oxidize and the temperature required by a combustion reaction is high are solved.

Description

technical field [0001] The invention relates to the technical field of energetic materials, in particular to insoluble energetic organic polymer-coated micro-nano particles and a preparation method thereof. Background technique [0002] As an energetic material, aluminum powder has the characteristics of high energy density and easy ignition. Micro-nano-sized aluminum powder has been widely used in some formulas, showing excellent properties. Boron powder is the preferred additive for high-energy boron-rich fuel-rich solid propellants because of its high mass calorific value and volume calorific value. However, aluminum powder and boron powder will be slowly oxidized by oxygen in the air to form a dense shell of aluminum oxide or boron oxide. When the oxide layer reaches a certain thickness, it will hinder its internal oxidation. However, the oxide layer does not contribute to energy during combustion, and it also makes it difficult to burn aluminum and boron in the inner l...

Claims

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Application Information

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IPC IPC(8): C06B45/32C08G12/02B22F1/00C01B35/02
CPCC06B45/32C01B35/023C08G12/02B22F1/102
Inventor 郭兆琦程彦飞耶金杨娜王煜马海霞
Owner NORTHWEST UNIV
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