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Quasi-molecule laser electrochemical microstructure manufacturing method and equipment

A technology of excimer laser and manufacturing method, which can be used in photoplate-making process exposure devices, optics, optomechanical equipment, etc., and can solve the problems of low power, long laser wavelength, and limited application range.

Inactive Publication Date: 2006-06-14
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the lasers used in the existing laser-induced electrochemical micromachining process have longer wavelengths (such as 1.06 microns or 442 nanometers) and low power (such as 4.5 milliwatts), and it is difficult for the machinable feature size to reach the submicron scale. And the scope of application is still very limited
For example, the patented technology of the University of California in the United States is only applicable to the etching of III-nitride (such as gallium nitride) thin films, and it is powerless to submicron processing of other materials

Method used

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  • Quasi-molecule laser electrochemical microstructure manufacturing method and equipment
  • Quasi-molecule laser electrochemical microstructure manufacturing method and equipment
  • Quasi-molecule laser electrochemical microstructure manufacturing method and equipment

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Embodiment 1: the processing of metal microhole array

[0029] First, a layer of copper conductive layer is formed on the glass surface by chemical deposition, then, photoresist is coated on the copper conductive layer, and then the pattern is transferred to the photoresist by photolithography technology, and then it is dried. Etch and remove the photoresist, and then install the glass plate with copper conductive layer constituting the microprobe array at the cathode position in the laser electrochemical reaction chamber, so that the copper layer faces down, and connect with the cathode in it The post is connected, and the metal copper substrate to be processed is placed at the anode position, and connected to the anode terminal through the flat electrode. The distance between the electrodes is 0.2mm, the electrolyte is 5% NaCl solution, the liquid surface submerges the workpiece by 1mm, the power supply voltage is 12V, the wavelength of the excimer laser is 248nm, the...

Embodiment 2

[0030] Embodiment 2: the processing of metal microhole array

[0031] The fabrication and installation of the microprobe array are the same as the above example. The electrode spacing is 2mm, the electrolyte is 30% NaCl solution, the liquid surface submerges the workpiece by 2.5mm, the power supply voltage is 3V, the wavelength of the excimer laser is 248nm, the pulse energy is 100mJ, and the pulse number is 1000. After 1 minute, a microhole array with a pitch of 15 microns and a diameter of 5 microns is etched on the metal copper substrate with a thickness of about 0.5 mm.

Embodiment 3

[0032] Embodiment 3: the processing of metal microhole array

[0033] The fabrication and installation of the microprobe array are the same as the above example. The electrode spacing is 2mm, the electrolyte is 10% NaCl solution, the liquid surface submerges the workpiece by 2.5mm, the power supply voltage is 6V, the wavelength of the excimer laser is 248nm, the pulse energy is 250mJ, and the pulse number is 500. After 1 minute, a microhole array with a pitch of 50 microns and a diameter of 50 microns is etched on the stainless steel substrate with a thickness of about 0.5 mm.

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Abstract

The present invention belongs to the field of micro-manufacturing. Aiming at the shortcomings of traditional methods, excimer laser, integrated circuit plate-making lithography, electrochemistry and scanning probe microscopic technology are fused into a new processing method. The steps are: (1) first prepare a microscopic probe Needle array; (2) Fix the substrate between the plate electrode and the microprobe array, generate negative pressure, and inject protective gas; (3) Apply voltage between the electrodes after injecting the electrolyte solution, and at the same time pass through the excimer laser The electrochemical reaction is controlled to complete the machining process. The corresponding device is equipped with an electrochemical reaction chamber on the workbench of the laser microprocessing machine, which includes a laser pneumatic window, a protective gas inlet, a vacuum pump interface, an electrolyte solution inlet, a microprobe array, a flat electrode, an auxiliary electrochemical reaction gas inlet, and a waste outlet. . The invention can obtain a microstructure with an aspect ratio of 5-50 and a characteristic size of 1-50 microns on metal and semiconductor substrates, and has wide applications in the fields of environmental protection, textiles, papermaking, energy, information and national defense.

Description

technical field [0001] The invention belongs to the field of micro-manufacturing in manufacturing technology, and relates to integrated circuit plate-making photolithography, excimer laser processing and electrochemical processing techniques. Background technique [0002] The current micro-manufacturing method generally adopts a photolithography process to apply glue on a substrate to form a microstructure pattern, and then uses a chemical micromachining process or a laser-induced chemical micromachining process to fabricate a three-dimensional microstructure. However, since the longitudinal etching depth and lateral etching width of the microstructure formed by the chemical micromachining process are basically equal (the aspect ratio is 1), it is difficult to produce a microstructure with a large vertical depth and a small lateral width, and unnecessary "The Lateral Corrosion Problem". Laser-induced chemical micromachining can reduce harmful lateral corrosion effects and i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03F7/20G03F7/00
Inventor 史铁林陈志凌熊良才柳海鹏周月豪马龙
Owner HUAZHONG UNIV OF SCI & TECH
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