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321results about How to "Stable internal structure" patented technology

LiNi0.6-xCo0.2Mn0.2AlxO2-yFy positive electrode material for lithium ion cell and preparation method thereof

The invention belongs to the field of lithium ion cell and specifically relates to a LiNi0.6-xCo0.2Mn0.2AlxO2-yFy positive electrode material for the lithium ion cell and a preparation method thereof. X is more than 0 and y is less than or equal to 0.05. The positive electrode material is used for overcoming the defect of poor electrochemical performance of the Ni-Co lithium manganate ternary positive electrode material. According to the invention, a minute quantity of aluminum and fluorine are doped, so that the positive electrode material for the lithium ion cell has higher specific discharge capacity and excellent cycle performance; under a room temperature environment, when the voltage scope is 2.7-4.3V and the constant current charge-discharge multiplying power is 0.5C, the specific discharge capacity of the material at the first time can reach 187.9mAh g<-1>, and after circulation for 20 times, the specific discharge capacity still can reach 192.1mAh g1 and the capacity retention ratio reaches up to 102.2%; when the voltage scope is increased to 2.7-4.5V and the constant current charge-discharge multiplying power is 0.5C, the initial specific discharge capacity of the material can reach 225.8mAh g<-1>, and after circulation for 20 times, the specific discharge capacity still can reach 190.2mAh g<-1> and the capacity retention ratio reaches up to 84.2%. The preparation technique of the material is simple and controllable, the product purity is high, the chemical uniformity is high, the crystal quality is high, the product grain is small and the size distribution is uniform.
Owner:UNIV OF ELECTRONIC SCI & TECH OF CHINA

Al/La co-doped high-nickel ternary precursor with core-shell structure and preparation method thereof, and positive electrode material

The invention relates to the field of lithium ion battery materials, and provides an Al/La co-doped high-nickel ternary precursor with a core-shell structure and a preparation method thereof, and a positive electrode material prepared from the precursor. The preparation method mainly comprises the following three steps: step 1, synthesizing an Al-doped high-nickel ternary precursor with rod-like primary particles under the condition of a low pH value; 2, increasing the pH value on the basis of the step 1, growing a La-doped high-nickel ternary precursor shell with needle-shaped primary particles by taking the Al-doped high-nickel ternary precursor as an inner core so as to synthesize an Al/La co-doped high-nickel ternary precursor with a core-shell structure; and 3, mixing the Al/La co-doped high-nickel ternary precursor with the core-shell structure and a lithium salt, and carrying out high-temperature calcination in an oxygen atmosphere to obtain the Al/La co-doped ternary positive electrode material with the core-shell structure. Due to the unique co-doped core-shell structure, the stability of an internal structure is effectively enhanced, the generation of mixed phases such ascation mixing and rock salt structures is inhibited, the breakage of grain boundaries is reduced, the average oxidation state of manganese ions is improved, the Jahn-Teller effect is effectively inhibited, the rapid attenuation of the capacity in a cycle process is reduced, the cycle stability of the material is remarkably improved, and the cycle life of the material is remarkably prolonged. Theproduct synthesized by adopting a coprecipitation method is uniform in component, good in sphericity, good in reproducibility, easy in condition control, low in preparation cost, high in economic value and wide in application prospect.
Owner:ZHUJI PAWA NEW ENERGY

High-potential lithium ion battery NCM ternary anode material and manufacturing method thereof

The invention belongs to the lithium ion battery field and relates to a lithium ion battery anode material and a manufacturing method thereof. The invention especially relates to a high-potential lithium ion battery NCM ternary anode material and the manufacturing method thereof, which is used for overcoming a defect of poor electrochemical cycle performance of existing lithium ion battery anode material layered high-nickel lithium-nickel-cobalt manganate NCM811 and derivatives. A molecular expression of the anode material is Li (Ni0. 8Co0. 1Mn0. 1) 1-x-ySixO2 @ (Li2SiO3) y, wherein x+y is greater than 0 and is less than or equal to 0.2, and y is much less than x. Li2SiO3 coating modification formed by combining high-valence state Si < 4 + > gradient doping for inhibiting generation of micro-cracks in a circulation process and a surface is adopted. The lithium ion battery anode material has a relatively high specific discharge capacity and excellent cycling stability and a high-rate charge-discharge cycling requirement can be satisfied. Bulk phase doping is performed by adopting a traditional solid phase method, operation is simple, industrial production is easy, a prepared productis high in purity, high in chemical uniformity, high in crystallization quality, fine in product particle, and uniform in distribution, and electrochemical performance is excellent and manufacturingcost is low.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA

Aluminum and fluorine dual-modified lithium ion battery cathode material and preparation method thereof

The invention belongs to the field of lithium ion batteries, and provides a lithium ion battery cathode material Li(Ni0.8Co0.1Mn0.1)1-xAlxO2-yFy@LiAlO2 and a preparation method thereof, wherein x is more than 0, and y is less than or equal to 0.05, and the defects of LiNi0.8Mn0.1Co0.1O2 has poor electrochemical cycle performance and poor safety performance are overcome. Aluminum and fluorine are co-doped in a matrix material, and the trivalent aluminum element not only can stabilize the structure of the material, but also can prevent Ni<2+> from substituting Li<+>, so that the mixing of lithium / nickel cations is reduced, and fluorine can inhibit side reaction between the material and electrolyte; at the same time, the surface of a parent material Li(Ni0.8Co0.1Mn0.1)1-xAlxO2-yFy is coated with an extremely thin lithium fast ion conductor lithium metaaluminate which can enhance the lithium ion transport and reduce the surface alkalinity; the lithium ion battery cathode material can havehigher discharge specific capacity while improving cycling stability, and has a more stable structure compared with LiNi0.8Co0.1Mn0.1O2, the safety and processing performance of the material are improved, and especially at large magnification and high voltage, the safety performance is greatly improved.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA

Nickel-cobalt-manganese ternary precursor, positive electrode material and preparation method

The invention belongs to the technical field of lithium ion battery materials, and discloses a zirconium-magnesium doping and zirconium coating double-modified nickel-cobalt-manganese ternary precursor and a preparation method thereof. According to the preparation method, Zr and Mg are introduced into the ternary precursor for doping, Zr is introduced for coating at the later stage of reaction, a complexing control crystallization coprecipitation method is adopted, and the zirconium-magnesium doping and zirconium coating dual-modified nickel-cobalt-manganese ternary precursor is prepared by controlling parameters such as the pH value, the ammonia concentration and the reaction temperature of a reaction system. According to the invention, Zr, Mg doping and Zr coating are introduced into the ternary precursor, the positive electrode material inheriting the performance is stable in cycle performance, good in capacity retention rate and excellent in rate performance, meanwhile, the single crystal material has the characteristics of compact internal structure and no crack, the volume effect and crack generation can be effectively inhibited in the fast charging process, and the development requirements of the electric vehicle industry can be met.
Owner:ZHUJI PAWA NEW ENERGY

High-capacity long-cycle single-crystal ternary positive electrode material and preparation method thereof

ActiveCN111370700ANo reduction in specific capacityStabilized particle surfaceSecondary cellsPositive electrodesPhysical chemistrySingle crystal
The invention provides a high-capacity long-cycle single-crystal ternary positive electrode material and a preparation method thereof. The chemical formula of the single crystal ternary positive electrode material is LiNi < x > Co < y > Mn < 1-x-y > MaO < 2 >, wherein x is more than or equal to 0.5 and less than or equal to 1, y is more than 0 and less than or equal to 0.5, x + y is more than 0 and less than 1, a is more than 0 and less than or equal to 0.005, and M is a cation modified element which comprises a Ti element and can also comprise one or more of Al, Mg, Zr, Nb and Y elements. According to the preparation method of the high-capacity long-cycle single-crystal ternary positive electrode material provided by the invention, the material of which the modified elements have concentration gradients which are progressively increased from the core to the surface can be prepared. Under a high charging cut-off voltage, the modified elements are preferentially oxidized compared with transition metal elements, so that the internal structures of the particles are stabilized, the content of the core modified elements is low, the specific capacity of the material is not reduced, meanwhile, the content of the modified elements on the surface of the material is relatively high, the particle surface of the material is relatively stable, and the cycle performance of the material is integrally improved.
Owner:NINGXIA SINOCHEM LITHIUM BATTERY MATERIAL CO LTD
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