The invention discloses a solar energy collection composite micro-energy system and a method for realizing super capacitor charging control, and belongs to the technical field of new energy compounding. The composite micro-energy system is composed of a solar battery, a solar energy collection circuit, a battery protection circuit, a lithium battery, a super capacitor charger, a super capacitor, an output adjusting circuit and a controller. The solar battery, the solar energy collection circuit, the battery protection circuit, the lithium battery and the controller are connected in series to form a loop, and the super capacitor charger is connected with the solar energy collection circuit, the controller and the super capacitor to form the solar collection composite micro-energy system; the super capacitor of the system supplies power to the wireless sensing node through the output adjusting circuit. According to the system, the lithium battery and the super capacitor are adopted for composite energy storage, and large energy storage capacity and high power output can be achieved at the same time, and energy can be provided for the wireless sensing node for a long time. Different load conditions can be adapted, so that the capacity of the lithium battery is slowly attenuated, and the service life is long.