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Waterborne glass nano-paint containing composite metal nanometer nuclear particles and preparation

A composite metal and nano-core technology, applied in the field of coatings, can solve the problems of single function, complex preparation process and insufficient performance.

Inactive Publication Date: 2018-07-06
深圳威耐纳米新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the visible light transmittance of the coating prepared by this technology is too low, even less than 60%.
[0017] Although many preparation methods of vanadium dioxide and doped vanadium dioxide coatings have been reported, such as chemical vapor deposition, reactive evaporation, magnetron sputtering, laser pulse deposition, sol-gel method, hydrothermal Synthesis method, vacuum reduction method, spray pyrolysis method, etc., but these methods have expensive raw materials, complicated preparation process, resulting in high preparation cost, and vanadium dioxide powder presents mixed valence state and low purity, which leads to its large-scale industrial application. there is a distance
[0018] Therefore, although there are various heat-insulating and light-transmitting coating composition materials in the prior art, their performance is still not perfect, and the too single function also restricts the application range of the material.

Method used

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  • Waterborne glass nano-paint containing composite metal nanometer nuclear particles and preparation
  • Waterborne glass nano-paint containing composite metal nanometer nuclear particles and preparation
  • Waterborne glass nano-paint containing composite metal nanometer nuclear particles and preparation

Examples

Experimental program
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Effect test

preparation example 1A

[0082] Preparation Example 1A: Preparation of molybdenum-doped vanadium dioxide nanopowder material coated with nano-titanium dioxide in component A-nano-titanium dioxide

[0083] (1) Step 1, prepare modified nano vanadium dioxide particles doped with molybdenum:

[0084] Add KH560, vanadium dioxide particles and molybdenum particles to propanol solvent, wherein the amount of vanadium dioxide particles added is 150g / L, the amount of molybdenum particles added is 30g / L, and the mass fraction of coupling agent KH560 is 2% After mixing evenly, use the high-energy ball mill ball mill with a ball-to-material ratio of 30:1, set the ball mill speed at 800 rpm for 8 hours, filter and separate, wash, and dry to obtain molybdenum-doped modified nanometer powder with a uniform particle size. Vanadium oxide particles with a median particle size of 60nm;

[0085] (2) Step 2, nano-titanium dioxide coating:

[0086]The above-mentioned modified vanadium dioxide nanoparticles doped with moly...

preparation example 1B

[0087] Preparation Example 1B: Preparation of Component A-nano-titanium dioxide-coated tungsten-doped vanadium dioxide nanopowder material in composite metal nano-core particles

[0088] (1) Step 1, prepare modified nano vanadium dioxide particles doped with tungsten:

[0089] Add KH560, vanadium dioxide particles and tungsten particles to butanol solvent, wherein the amount of vanadium dioxide particles added is 160g / L, the amount of tungsten particles added is 40g / L, and the mass fraction of coupling agent KH560 is 1.5% After mixing evenly, use a high-energy ball mill with a ball-to-material ratio of 30:1 for ball milling, set the ball milling speed at 800 rpm for 8 hours, filter and separate, wash, and dry to obtain the modified nanometer powder doped with tungsten with uniform particle size. Vanadium oxide particles with a median particle size of 55nm;

[0090] (2) Step 2, nano-titanium dioxide coating:

[0091] The above-mentioned modified vanadium dioxide nanoparticles...

preparation example 2

[0092] Preparation example 2: Preparation of component B-tungsten / fluorine co-doped vanadium dioxide nanopowder in composite metal nano-core particles

[0093] Take 1.0 moles of vanadium pentoxide V 2 o 5 As the raw material, oxalic acid is used as the reducing agent, sodium tungstate dihydrate is selected as the tungsten dopant, ammonium fluoride is selected as the fluorine dopant (the molar amounts of tungsten and fluorine elements are 0.1 moles respectively), and urea with a concentration of 1.5M As a precipitating agent, add 1200ml of distilled water and react for 72 hours in a 190-degree hydrothermal reactor to obtain blue-black silk powder precipitation. After washing, nano-grinding, and drying, calcinate in a tubular resistance furnace at 800°C under the protection of a nitrogen atmosphere. Annealed for 5 hours to obtain a tungsten / fluorine co-doped vanadium dioxide powder, wherein the tungsten / fluorine is 5% of the molar weight of the vanadium dioxide. The average pa...

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Abstract

The invention relates to waterborne glass nano-paint containing composite nanometer nuclear particles and preparation. The paint is prepared from composite metal nanometer nuclear particles, nano-silicon dioxide modified by fluorinated alkyl silane, nano-silicon dioxide coated by nano-titania, organic silicon molecules modified by acrylic ester, modified nano-titania, waterborne polyurethane resin / polysiloxane resin composite resin, an additionally adsorbed adjuvant and other auxiliary ingredients. By certain modification and combination of composite nanometer nuclear particle ingredients andother ingredients, the performance of the paint is expanded, by mutual synergy between the ingredients, the coating material shows excellent properties, has excellent effects of high light transmitting performance, heat insulation performance, ultraviolet isolation / absorption performance, high adhesiveness, anti-aging stability, water dredging, dust prevention and self cleaning, and further has anintelligent energy-saving effect specific to environmental temperature.

Description

technical field [0001] The invention relates to a nano-coating material, more specifically to a water-based high-transparency coating material with a composite inorganic nano-nuclear particle structure for heat insulation of transparent glass and a preparation method thereof, belonging to the field of coatings. The material can be used as a coating on glass surfaces such as architectural glass and automotive glass. Background technique [0002] Coating materials are solid continuous film materials coated on the surface of objects, which can be divided into many types such as wear-resistant type, anti-oxidation type, heat-insulating type, and light-transmitting type. Currently, due to the widespread use of glass in daily life, various coatings suitable for glass have been extensively studied. [0003] In building glass, on the one hand, as architectural lighting, it is expected to efficiently transmit visible light while reducing energy loss caused by thermal effects of indo...

Claims

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Application Information

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IPC IPC(8): C09D175/04C09D183/04C09D5/16C09D5/33C09D7/62C03C17/00
CPCC03C17/009C08K2003/2241C08K2201/011C09D5/004C09D5/1612C09D5/1687C09D175/04C08L83/04C08K13/06C08K9/06C08K3/22C08K9/10C08K3/36Y02P20/10
Inventor 沈龙陈名璨
Owner 深圳威耐纳米新材料科技有限公司
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